Para-azaquinodimethane-based quinoidal copolymers: Significant enhancement of electrochemical performances and stability with conformational planarity DOI

Nguyen T. Tran,

Bharath Dyaga,

Godeline Mireille Nzouadi

и другие.

Synthetic Metals, Год журнала: 2024, Номер 310, С. 117781 - 117781

Опубликована: Ноя. 13, 2024

Язык: Английский

Recent developments in polymer semiconductors with excellent electron transport performances DOI
Yunchao Zhang, Weifeng Zhang, Zhihui Chen

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review describes the design considerations, bonding modes between monomers, structural modification strategies, and applications of polymer semiconductors with excellent electron transport performances.

Язык: Английский

Процитировано

2
Charge Polarity Modulation and Efficient Electron Transport in Quinoid–Donor–Acceptor Polymers by Acceptor Engineering for High-Performance Transistors DOI

Hao Chen,

Runze Xie,

Junwang Tang

и другие.

Macromolecules, Год журнала: 2025, Номер unknown

Опубликована: Янв. 8, 2025

Fine-tuning the charge polarity and enhancing electron transport in conjugated polymers are critical for developing high-performance organic field-effect transistors (OFETs). Quinoidal polymers, characterized by planar backbones deep-lying lowest unoccupied molecular orbital (LUMO) energy levels, offer distinct advantages over their aromatic counterparts but face challenges achieving reliable mobilities exceeding 1 cm2 V–1 s–1. Herein, we synthesized a set of novel quinoid–donor–acceptor (Q-D-A) with various acceptor units. Increasing strength narrowed band gap, lowered LUMO shifted from unipolar p-type to ambipolar ultimately dominant n-type behavior. The electron-to-hole mobility ratio increased 0 40 behavior observed Q-D-A polymer first time. Consequently, strongest acceptor-based exhibited backbone, small effective mass, high crystallinity, low disorder, resulting 1.20 s–1 decent operational stability. This is record-high value quinoidal transport. Our findings viable strategy tuning improving providing insights into structure–property relationships essential advancing electronics.

Язык: Английский

Процитировано

1
A Three‐in‐One Hybrid Strategy for High‐Performance Semiconducting Polymers Processed from Anisole DOI Creative Commons
Cheng Liu,

Huanhuan Liang,

Runze Xie

и другие.

Advanced Science, Год журнала: 2024, Номер 11(25)

Опубликована: Апрель 22, 2024

Abstract The development of semiconducting polymers with good processability in green solvents and competitive electrical performance is essential for realizing sustainable large‐scale manufacturing commercialization organic electronics. A major obstacle the processability‐performance dichotomy that dictated by lack ideal building blocks balanced polarity, solubility, electronic structures, molecular conformation. Herein, through integration donor, quinoid acceptor units, an unprecedented block, namely TQBT, introduced constructing a serial conjugated polymers. distinct non‐symmetric structure high dipole moment, imparts enhanced solubility anisole—a solvent—to polymer TQBT‐T. Furthermore, PTQBT‐T possess highly rigid planar backbone owing to nearly coplanar geometry quinoidal nature resulting strong aggregation solution localized aggregates film. Remarkably, films spuncast from anisole exhibit hole mobility 2.30 cm 2 V ‐1 s , which record solvent‐processable via spin‐coating, together commendable operational storage stability. hybrid block emerges as pioneering electroactive unit, shedding light on future design strategies high‐performance compatible processing marking significant stride towards ecofriendly

Язык: Английский

Процитировано

8
Exceptional Second Near-Infrared Window Organic Photothermal Material for High-Temperature Applications Activated by a 1064 nm Laser DOI

Huaxin Yang,

Weifang Wang, Ping Deng

и другие.

ACS Materials Letters, Год журнала: 2025, Номер unknown, С. 1060 - 1069

Опубликована: Фев. 17, 2025

Язык: Английский

Процитировано

0
Efficient near-room-temperature synthesis of thiophene-vinyl-flanked diketopyrrolopyrrole dye-based mesopolymers for high-performance organic field-effect transistors DOI
Jinyang Chen,

Wenkang Shi,

Ruifang Meng

и другие.

Dyes and Pigments, Год журнала: 2025, Номер unknown, С. 112782 - 112782

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Precisely Regulating Interchain Aggregation and Film Crystallinity of Quinoidal Terpolymers for High-Performance Eco-friendly Transistors DOI

Runze Xie,

Quanfeng Zhou,

Pengyu Guan

и другие.

Macromolecules, Год журнала: 2025, Номер unknown

Опубликована: Март 25, 2025

Язык: Английский

Процитировано

0
The Impact of Green Solvent Processing on Electroactive Poly(N-(6-N-carbazolylhexyl) acrylamide) and Poly(6-N-carbazolylhexyl acrylate) DOI
Divyesh R. Patel,

Qingpei Wan,

Barry C. Thompson

и другие.

ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown

Опубликована: Июнь 1, 2025

Язык: Английский

Процитировано

0
Para-azaquinodimethane-based quinoidal copolymers: Significant enhancement of electrochemical performances and stability with conformational planarity DOI

Nguyen T. Tran,

Bharath Dyaga,

Godeline Mireille Nzouadi

и другие.

Synthetic Metals, Год журнала: 2024, Номер 310, С. 117781 - 117781

Опубликована: Ноя. 13, 2024

Язык: Английский

Процитировано

2