Amphiphilic Cationic Carbon Dots for Efficient Delivery of Light‐Dependent Herbicide
Advanced Science,
Год журнала:
2024,
Номер
11(39)
Опубликована: Авг. 21, 2024
Abstract
The
inefficient
delivery
of
herbicides
causes
unpleasant
side
effects
on
the
ecological
environment.
Protoporphyrinogen
oxidase
(PPO)‐inhibiting
rely
presence
external
light
to
exert
activities
and
thus
their
performance
in
field
is
extremely
susceptible
Here,
taking
acifluorfen
(ACI)
as
a
model
PPO‐inhibiting
herbicide
enhance
efficacy
by
boosting
utilization
rate
sunlight,
amphiphilic
cationic
CDs
(CPC‐CDs)
from
cetylpyridinium
chloride
(CPC)
precursor,
first
prepared
supplementary
source
generator,
subsequently
co‐assembled
with
ACI
through
non‐covalent
bond
interactions
obtain
stable
fluorescent
nanoparticles
(ACI@CPC‐CDs).
ACI@CPC‐CDs
fascinating
physicochemical
properties
can
penetrate
leaves
weeds
stomata
undergo
long‐distance
transport
cell
intervals.
Under
low
intensity,
CPC‐CDs
be
applied
internal
promote
formation
more
singlet
oxygen
damage
leaf
membrane,
consequently
improving
herbicidal
activity
ACI.
Moreover,
safety
evaluation
demonstrates
no
risk
non‐target
organisms
Therefore,
this
work
offers
promising
strategy
for
efficient
light‐dependent
opens
new
insights
into
application
development
sustainable
agriculture.
Язык: Английский
Sustainable pest management using plant secondary metabolites regulated azadirachtin nano-assemblies
Nature Communications,
Год журнала:
2025,
Номер
16(1)
Опубликована: Фев. 18, 2025
Biopesticides
have
emerged
as
a
global
trend
to
minimize
the
risks
associated
with
synthetic
agrochemicals.
However,
their
stability
and
efficacies
remain
challenges
for
widespread
application.
Herein,
co-assembled
nanoparticles
(AT
NPs
or
AP
NPs)
based
on
azadirachtin
(AZA)
tannic
acid
(TA)
phenylalanine
(PA)
are
constructed
in
aqueous
solution
through
self-assembly
technology.
The
small
particle
size,
low
PDI,
high
ζ-potential,
related
other
physicochemical
characteristics
of
can
improve
wettability,
adhesiveness,
rain
erosion
resistance,
photostability
compared
commercial
AZA
formulation.
Importantly,
co-assemblies
bidirectional
pH-responsive
disassembly
acidic
alkaline
solutions,
allow
them
respond
microenvironmental
stimuli
targets
enable
controlled
release
AZA.
nanosystems
demonstrated
remarkable
vitro
vivo
insecticidal
activities
against
Ostrinia
furnacalis
Aphis
gossypii.
This
study
illustrates
distinctive
perspective
developing
eco-friendly
nanosystems,
highlighting
water-based
treatment
method
biopesticides
improved
properties
utilization
efficiency.
delivery
limits
Here,
is
plant
secondary
metabolites
efficient
drug
delivery,
demonstrating
pest
management,
activation
defensive
capacity,
while
increasing
production
yield
crops.
Язык: Английский
Prodrug self-assemblies based on acifluorfen and glucose for improving the effective utilization and reducing the risks to environment
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 161382 - 161382
Опубликована: Март 1, 2025
Язык: Английский
Green Carbon Dots/CaCO3/Abamectin Colloidal Pesticide Formulation for Safer and More Effective Pest Management
ACS Nano,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 21, 2024
An
ideal
green
leaf-deposited
pesticide
formulation
should
offer
advantages
such
as
good
water
dispersibility,
strong
foliar
affinity,
sustained
or
controlled
release
of
active
ingredients,
photostability
and
rain-fastness,
minimal
nontarget
toxicity,
use
nontoxic
organic
solvents,
degradable
adjuvants.
In
line
with
this
objective,
we
present
preparation
a
colloidal
using
optimized
lysine-derived
carbon
dots
(LysCDs)-modified
CaCO3
(LysCDs/CaCO3)
particles
the
carrier
abamectin
(Abm)
ingredient.
The
loading
capacity
in
(LysCDs/CaCO3/Abm)
is
1.7
to
2.1
times
higher
than
that
its
counterpart
(CaCO3/Abm)
prepared
without
LysCDs,
which
attributed
increased
specific
surface
area
pore
volume
LysCDs/CaCO3
particles.
Due
acid-induced
degradation
CaCO3,
for
LysCDs/CaCO3/Abm
accelerated
under
weakly
acidic
conditions,
accompanied
by
Ca2+
ions
fluorescence
changes
LysCDs.
incorporation
LysCDs
enhances
adhesiveness
pesticide,
resulting
highest
degree
retention
when
exposed
ultraviolet
(UV)
light
rainfall,
compared
free-form
CaCO3/Abm.
This
results
best
performance
pest
control
on
Plutella
xylostella
both
indoor
outdoor
tests.
Nontarget
biocompatibility
evaluations
show
exhibits
lower
acute
toxicity
zebrafish
earthworms
abamectin.
addition,
favored
residue
adjuvant
material
after
release,
converted
into
harmless
ions,
CO2,
Therefore,
work
designs
safer
more
effective
deliver
residue,
realizing
trajectory
basically
"circular
green".
Язык: Английский