MOF@graphene nanocomposites for energy and environment applications

Composites Communications, Год журнала: 2023, Номер 45, С. 101783 - 101783

Опубликована: Ноя. 30, 2023

Язык: Английский

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Structural engineering of atomic catalysts for electrocatalysis

Chemical Science, Год журнала: 2024, Номер 15(14), С. 5082 - 5112

Опубликована: Янв. 1, 2024

This review systematically introduces how to regulate the electronic structure and geometric configuration of atomic catalysts achieve high-efficiency electrocatalysis performances by analyzing detailed electrocatalytic applications mechanisms.

Язык: Английский

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Nanoscale Engineering of P‐Block Metal‐Based Catalysts Toward Industrial‐Scale Electrochemical Reduction of CO₂

Advanced Energy Materials, Год журнала: 2023, Номер 13(34)

Опубликована: Июль 27, 2023

Abstract The efficient conversion of CO 2 to value‐added products represents one the most attractive solutions mitigate climate change and tackle associated environmental issues. In particular, electrochemical reduction fuels chemicals has garnered tremendous interest over last decades. Among all from reduction, formic acid is considered economically vital products. P‐block metals (especially Bi, Sn, In, Pb) have been extensively investigated recognized as catalytic materials for electroreduction formate. Despite remarkable progress, future implementation this technology at industrial‐scale hinges on ability solve remaining roadblocks. review, current research status, challenges, prospects p‐block metal‐based catalysts primarily formate are comprehensively reviewed. rational design nanostructure engineering these metal optimization their performances discussed in detail. Subsequently, recent progress development state‐of‐the‐art operando characterization techniques together with advanced cells uncover intrinsic catalysis mechanism discussed. Lastly, a perspective directions including tackling critical challenges realize its early industrial presented.

Язык: Английский

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N and OH-Immobilized Cu₃ Clusters In Situ Reconstructed from Single-Metal Sites for Efficient CO₂ Electromethanation in Bicontinuous Mesochannels

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(2), С. 1423 - 1434

Опубликована: Янв. 3, 2024

Cu-based catalysts hold promise for electrifying CO2 to produce methane, an extensively used fuel. However, the activity and selectivity remain insufficient due lack of catalyst design principles steer complex reduction pathways. Herein, we develop a concept carbon-supported Cu by regulating active sites' atomic-scale structures engineering carbon support's mesoscale architecture. This aims provide favorable local reaction microenvironment selective pathway methane. In situ X-ray absorption Raman spectroscopy analyses reveal dynamic reconstruction nitrogen hydroxyl-immobilized Cu3 (N,OH-Cu3) clusters derived from atomically dispersed Cu–N3 sites under realistic conditions. The N,OH-Cu3 possess moderate *CO adsorption affinity low barrier hydrogenation, enabling intrinsically CO2-to-CH4 compared C–C coupling with high energy barrier. Importantly, block copolymer-derived fiber support interconnected mesopores is constructed. unique long-range mesochannels offer H2O-deficient prolong transport path CO intermediate, which could suppress hydrogen evolution favor deep toward methane formation. Thus, newly developed consisting in constructed embedded into bicontinuous achieved unprecedented Faradaic efficiency 74.2% at industry-level current density 300 mA cm–2. work explores effective concepts steering desirable pathways interfacial catalytic systems via modulating site atomic level pore architectures supports on create microenvironments.

Язык: Английский

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Furoic acid-doped-over-oxidized poly (3, 4-ethylenedioxythiophene)-based electrochemical sensor for selective, sensitive and concurrent quantification of paracetamol, codeine phosphate and caffeine in pharmaceutical formulation

Journal of materials research/Pratt's guide to venture capital sources, Год журнала: 2025, Номер unknown

Опубликована: Янв. 17, 2025

Язык: Английский

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A molecular view of single-atom catalysis toward carbon dioxide conversion

Chemical Science, Год журнала: 2024, Номер 15(13), С. 4631 - 4708

Опубликована: Янв. 1, 2024

We present critical advances in single-atom catalysis toward CO 2 transformation and address crucial issues about SACs from a molecular point of view.

Язык: Английский

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Atomically Dispersed Metal Catalysts for the Conversion of CO₂ into High‐Value C₂₊ Chemicals

Advanced Materials, Год журнала: 2024, Номер 36(37)

Опубликована: Май 19, 2024

Abstract The conversion of carbon dioxide (CO 2 ) into value‐added chemicals with two or more carbons (C 2+ is a promising strategy that cannot only mitigate anthropogenic CO emissions but also reduce the excessive dependence on fossil feedstocks. In recent years, atomically dispersed metal catalysts (ADCs), including single‐atom (SACs), dual‐atom (DACs), and single‐cluster (SCCs), emerged as attractive candidates for fixation reactions due to their unique properties, such maximum utilization active sites, tunable electronic structure, efficient elucidation catalytic mechanism, etc. This review provides an overview significant progress in synthesis characterization ADCs utilized photocatalytic, electrocatalytic, thermocatalytic toward high‐value C compounds. To provide insights designing chemical originating from , key factors influence activity selectivity are highlighted. Finally, relevant challenges opportunities discussed inspire new ideas generation ‐based products over ADCs.

Язык: Английский

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CoS2-CoSe2 hybrid nanoparticles grown on carbon nanofibers as electrode for supercapacitor and hydrogen evolution reaction

Journal of Alloys and Compounds, Год журнала: 2024, Номер 990, С. 174366 - 174366

Опубликована: Апрель 7, 2024

Язык: Английский

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Metal‐Organic Frameworks‐Based Copper Catalysts for CO₂ Electroreduction Toward Multicarbon Products

Exploration, Год журнала: 2025, Номер unknown

Опубликована: Фев. 12, 2025

ABSTRACT Copper (Cu) is the most promising catalyst for electrochemical CO 2 ‐to‐C 2+ conversion, whereas performance remains below practical thresholds due to high energy barrier of C−C coupling and lack effective approaches steer reaction pathway. Recent advances show that metal‐organic frameworks (MOF) could be a platform as support, pre‐catalyst, co‐catalyst modify electronic structure local environment Cu catalysts promoting reduction by virtue their great tunability over compositions pore architectures. In this review, we discussed general design principles, catalytic mechanisms, achievements MOF‐based catalysts, aiming boost refinement steering pathway C products. The fundamentals challenges are first introduced. Then, summarized conceptions from three aspects: engineering properties Cu, regulating environment, managing site exposure mass transport. Further, latest progress products namely Cu‐based MOF, MOF‐derived Cu@MOF hybrid discussed. Finally, future research opportunities strategies suggested innovate rational advanced electrifying transformation.

Язык: Английский

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Nature‐Inspired Electrocatalysts for CO₂ Reduction to C₂₊ Products

Advanced Energy Materials, Год журнала: 2023, Номер 13(48)

Опубликована: Ноя. 9, 2023

Abstract The electrocatalytic reduction reaction of carbon dioxide (CO 2 RR) has gained significant attention as a promising approach to mitigate emissions and generate valuable chemicals fuels. However, the practical application CO RR been hindered by lack efficient selective electrocatalysts, particularly produce multi‐carbon (C 2+ ) products. Nature serves an ideal source inspiration for development biological organisms can efficiently catalyze same possess robust structures that are inherently scaling. In this review, recent advances in nature‐inspired design electrocatalysts C products summarized categorized based on their source, including coordination sphere metalloenzymes cascade reactions within enzyme, well local environment. importance understanding fundamental mechanisms different contexts between nature technological process is highlighted, with aim improve

Язык: Английский

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