Ru-Catalyzed One-Pot Synthesis of Heterocyclic Backbones
Catalysts,
Год журнала:
2023,
Номер
13(1), С. 87 - 87
Опубликована: Янв. 1, 2023
Ruthenium
complexes
are
remarkable
catalysts
for
the
C–H
activation
approaches
and
organic
transformations.
Combining
a
Ru-catalyst
with
oxidants
other
additives
in
one-pot
process
is
considered
sustainable
approach
due
to
reduction
reaction
steps
minimal
usage
of
solvents
during
synthesis,
work-up,
isolation
chemicals,
purification
products.
This
review
highlights
ruthenium-catalyzed
transformations
manner
achieve
heterocyclic
backbones,
including
indoles,
benzofurans,
indazoles,
pyrans,
pyrimidines,
quinolines,
isoquinolines.
Язык: Английский
Ru(ii)-catalyzed oxidative coupling of sulfoxonium ylides with amines: efficient synthesis of α-ketoamides and indolo[2,1-a]isoquinolines
Sumi Changmai,
Tribeni Gogoi,
Jyotshna Phukon
и другие.
Organic & Biomolecular Chemistry,
Год журнала:
2023,
Номер
21(15), С. 3235 - 3244
Опубликована: Янв. 1, 2023
The
first
use
of
sulfoxonium
ylides
for
the
synthesis
α-ketoamides
is
described
via
a
Ru(II)-catalyzed
amidation
reaction
with
amines.
same
2-phenylindoles
provided
indolo[2,1-a]isoquinolines
instead
α-ketoamides.
Язык: Английский
Rhodium(iii)-catalyzed C–H alkylation of arylhydrophthalazinediones with α-Cl ketones as sp3-carbon alkylated agents
Organic & Biomolecular Chemistry,
Год журнала:
2023,
Номер
21(10), С. 2096 - 2100
Опубликована: Янв. 1, 2023
A
C–H
alkylation
of
arylhydrophthalazinediones
catalyzed
by
[Cp*RhCl
2
]
is
developed
using
α-Cl
ketones
as
sp
3
-carbon
alkylated
agents.
Язык: Английский
Heterocycles from Sulfur Ylides
Topics in heterocyclic chemistry,
Год журнала:
2023,
Номер
unknown, С. 63 - 105
Опубликована: Янв. 1, 2023
Язык: Английский
Rh(III)-catalyzed [4 + 1] annulation of 1-arylindazolones with alkynyl cyclobutanols: access to indazolo[1,2-a]indazolones
Organic & Biomolecular Chemistry,
Год журнала:
2024,
Номер
22(32), С. 6500 - 6505
Опубликована: Янв. 1, 2024
A
convenient
and
efficient
synthesis
of
structurally
diverse
indazolo[1,2-
a
]indazolones
via
Rh(
iii
)-catalyzed
[4
+
1]
annulation
1-arylindazolones
with
alkynyl
cyclobutanols
has
been
achieved
by
combining
C–H
C–C
bond
cleavage.
Язык: Английский