Journal of the American Chemical Society, Год журнала: 2024, Номер unknown

Опубликована: Дек. 1, 2024

Metal-organic cages and capsules exhibit space-specific functions based on their discrete hollow structures. To acquire enzyme-like asymmetric or intricate structures, they have been modified by desymmetrization with two more different ligands. There is a need to establish new strategies that can desymmetrize structures in simple way using only one type of ligand, which from the mixed-ligand approach. In this study, strategy was developed form interconvertible stereoisomers unsymmetric macrocyclic ligand benzimidazole[3]arene. Single-crystal X-ray diffraction analysis revealed isomers assembled silver tetrafluoroborate afforded conformationally heteroleptic Ag

Язык: Английский