Intricate Low-Symmetry Ag6L4 Capsules Formed by Anion-Templated Self-Assembly of the Stereoisomers of an Unsymmetric Ligand DOI
Shohei Tashiro,

Yoshihiko Yamada,

Lea Antonia Kringe

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Metal-organic cages and capsules exhibit space-specific functions based on their discrete hollow structures. To acquire enzyme-like asymmetric or intricate structures, they have been modified by desymmetrization with two more different ligands. There is a need to establish new strategies that can desymmetrize structures in simple way using only one type of ligand, which from the mixed-ligand approach. In this study, strategy was developed form interconvertible stereoisomers unsymmetric macrocyclic ligand benzimidazole[3]arene. Single-crystal X-ray diffraction analysis revealed isomers assembled silver tetrafluoroborate afforded conformationally heteroleptic Ag

Language: Английский

Synthesis, characterization and biological activity of binuclear palladium(II) complexes DOI Creative Commons
Debakanta Tripathy, Soumya Lipsa Rath, Niladri Bihari Debata

et al.

Results in Chemistry, Journal Year: 2025, Volume and Issue: 15, P. 102310 - 102310

Published: April 28, 2025

Language: Английский

Citations

0
Intricate Low-Symmetry Ag6L4 Capsules Formed by Anion-Templated Self-Assembly of the Stereoisomers of an Unsymmetric Ligand DOI
Shohei Tashiro,

Yoshihiko Yamada,

Lea Antonia Kringe

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Metal-organic cages and capsules exhibit space-specific functions based on their discrete hollow structures. To acquire enzyme-like asymmetric or intricate structures, they have been modified by desymmetrization with two more different ligands. There is a need to establish new strategies that can desymmetrize structures in simple way using only one type of ligand, which from the mixed-ligand approach. In this study, strategy was developed form interconvertible stereoisomers unsymmetric macrocyclic ligand benzimidazole[3]arene. Single-crystal X-ray diffraction analysis revealed isomers assembled silver tetrafluoroborate afforded conformationally heteroleptic Ag

Language: Английский

Citations

1