The Past and the Future of Langmuir and Langmuir–Blodgett Films

Chemical Reviews, Год журнала: 2022, Номер 122(6), С. 6459 - 6513

Опубликована: Фев. 3, 2022

The Langmuir–Blodgett (LB) technique, through which monolayers are transferred from the air/water interface onto a solid substrate, was first method to allow for controlled assembly of organic molecules. With its almost 100 year history, it has been inspiration most methods functionalize surfaces and produce nanocoatings, in addition serving explore concepts molecular electronics nanoarchitectonics. This paper provides an overview history Langmuir LB films, including potential use devices discussion on why films seldom considered practical applications today. Emphasis is then given two areas where these offer unique opportunities, namely, mimicking cell membrane models exploiting nanoarchitectonics sensors, investigate recognitions, assemble machines. promising topics short- long-term prospects technique also highlighted.

Язык: Английский

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Nanoarchitectonics: what's coming next after nanotechnology?

Nanoscale Horizons, Год журнала: 2021, Номер 6(5), С. 364 - 378

Опубликована: Янв. 1, 2021

The nanoarchitectonics concept has the ability to bridge nanoscale science and visual size materials. final goal of approaches is creation living-creature-like functional material systems from simple objects.

Язык: Английский

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Visually resolving the direct Z-scheme heterojunction in CdS@ZnIn2S4 hollow cubes for photocatalytic evolution of H2 and H2O2 from pure water

Applied Catalysis B Environment and Energy, Год журнала: 2021, Номер 293, С. 120213 - 120213

Опубликована: Апрель 7, 2021

Язык: Английский

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The Emergence and Evolution of Borophene

Advanced Science, Год журнала: 2021, Номер 8(12)

Опубликована: Май 2, 2021

Neighboring carbon and sandwiched between non-metals metals in the periodic table of elements, boron is one most chemically physically versatile can be manipulated to form dimensionally low planar structures (borophene) with intriguing properties. Herein, theoretical research experimental developments synthesis borophene, as well its excellent properties application many fields, are reviewed. The decade-long effort toward understanding size-dependent clusters theory-directed including bottom-up approaches based on different foundations, up-down exfoliation modes, key factors influencing synthetic effects, comprehensively summarized. Owing chemical, electronic, mechanical, thermal properties, borophene has shown great promise supercapacitor, battery, hydrogen-storage, biomedical applications. Furthermore, nanoplatforms used various applications, such bioimaging, drug delivery, photonic therapy, highlighted. Finally, progress, challenges, perspectives for future development large-scale production other prospective applications discussed.

Язык: Английский

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Don’t Forget Langmuir–Blodgett Films 2020: Interfacial Nanoarchitectonics with Molecules, Materials, and Living Objects

Langmuir, Год журнала: 2020, Номер 36(26), С. 7158 - 7180

Опубликована: Июнь 5, 2020

Designing interfacial structures with nanoscale (or molecular) components is one of the important tasks in nanoarchitectonics concept. In particular, Langmuir–Blodgett (LB) method can become a promising and powerful strategy nanoarchitectonics. From this viewpoint, status LB films 2020 will be discussed feature article. After section on basics technique, various recent research examples are introduced according to classifications (i) growing research, (ii) emerging (iii) future research. materials other than traditional lipids typical amphiphiles used as film techniques. Two-dimensional materials, supramolecular such metal organic frameworks, biomaterials DNA origami pieces capable working functional assemblies. Possible areas methods would cover demands, including energy, environmental, biomedical applications wide range materials. addition, forefront molecular manipulation cell fate control conducted LB-related science. The technique well-develop methodology for ca. 100 year history. However, there plenty room at interfaces, shown described It hoped that continuous development science technology make an unforgettable methodology.

Язык: Английский

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Recent Developments on Molten Salt Synthesis of Inorganic Nanomaterials: A Review

The Journal of Physical Chemistry C, Год журнала: 2021, Номер 125(12), С. 6508 - 6533

Опубликована: Фев. 23, 2021

A wide range of inorganic nanomaterials with many fascinating properties and application potentials in widespread fields may be synthesized by wet chemical synthetic routes. To achieve scientific commercial viability uniformity scalability, it is necessary to develop efficient cost-effective, preferably sustainable, methods. The molten salt synthesis (MSS) method one such bottom-up technique fabricate a variety tunable size, morphology, surface characteristics. It also environmentally friendly, simple operate, easy scale, generalizable, etc. This review gives critical overview on this emerging rapidly developing for making defect free well-defined texture, surface, morphology at relatively low formation temperature. We have discussed its different aspects, including the role salts, choice electrochemical some advanced modifications conventional MSS technique, their implications. show most recent development nanomaterials, only encompasses studies reported over last six years (2015–2020). summarized technologically important families as metal oxides, fluorides, nitrides, silicides, chalcogenides, oxohalides, borides, carbides. Finally, few perspectives are highlighted. expected that will further attract scientists explore size- shape-tunable nanomaterials.

Язык: Английский

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Material Evolution with Nanotechnology, Nanoarchitectonics, and Materials Informatics: What will be the Next Paradigm Shift in Nanoporous Materials?

Advanced Materials, Год журнала: 2021, Номер 34(7)

Опубликована: Окт. 13, 2021

Abstract Materials science and chemistry have played a central significant role in advancing society. With the shift toward sustainable living, it is anticipated that development of functional materials will continue to be vital for sustaining life on our planet. In recent decades, rapid progress has been made owing advances experimental, analytical, computational methods, thereby producing several novel useful materials. However, most problems material are highly complex. Here, best strategy via implementation three key concepts discussed: nanotechnology as game changer, nanoarchitectonics an integrator, informatics super‐accelerator. Discussions from conceptual viewpoints example developments, chiefly focused nanoporous materials, presented. It coupling these strategies together open advanced routes swift design exploratory search truly solving real‐world problems. These result evolution

Язык: Английский

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There is still plenty of room for layer-by-layer assembly for constructing nanoarchitectonics-based materials and devices

Physical Chemistry Chemical Physics, Год журнала: 2021, Номер 24(7), С. 4097 - 4115

Опубликована: Дек. 2, 2021

While the layer-by-layer (LbL) assembly method has already reached a certain maturity, there is still plenty of room for expanding its usefulness fabrication nanoarchitectonics-based materials and devices.

Язык: Английский

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Nanoarchitectonics: the method for everything in materials science

Bulletin of the Chemical Society of Japan, Год журнала: 2023, Номер 97(1)

Опубликована: Дек. 1, 2023

Abstract Nanotechnology has revealed the science of nanoscale. The global challenge that will follow is to build functional materials with knowledge nanoscale phenomena. This task carried out by nanoarchitectonics as a postnanotechnology concept. goal material systems architecting atoms, molecules, and nanomaterials building blocks. Fundamentally, all are made atoms molecules. Therefore, nanoarchitectonics, which architects from can be universal way create materials. It may said method for everything in science. From basic units, living cells, complex systems, components nanoarchitectonics. paper presents recent examples research at various size levels, atomic cellular level, specifically, (i) atomistic (ii) molecular (iii) supramolecular (iv) inorganic (v) biomolecular (vi) cell-mimic (vii) cell-based possibility science, an integrative then explored.

Язык: Английский

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Materials Nanoarchitectonics from Atom to Living Cell: A Method for Everything

Bulletin of the Chemical Society of Japan, Год журнала: 2022, Номер 95(5), С. 774 - 795

Опубликована: Март 22, 2022

Abstract Promoted understanding of nanostructures and their functions significantly rely on rapid progress nanotechnology within a few decades. It would be fruitful way to consider materials science through regulation nanostructure regulations the basis nanotechnological accomplishments. As post-nanotechnology concept, new concept nanoarchitectonics has recently emerged as methodology produce functional from nanoscale units. In this review article, we discuss recent advances related approaches atom-scales living cell sizes. The multiscale are exemplified discussed including atom molecules nanoarchitectonics, supramolecular at cell-scale. Next, supracell-level is organization designed surfaces, sheets layered three-dimensional biofilms bioinks, challenges for cells liquid interface. All formed with fundamental units, atoms, molecules, nanomaterials, therefore, basic units can hypothetically applied any kind material. Therefore, could method everything in an analogy theory physics.

Язык: Английский

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