Along
with
the
progresses
of
material
syntheses,
importance
structural
regulation
is
realized
to
rationally
improve
efficiencies
and
specificities
in
target
functions.
Small
science
necessary
for
advanced
systems.
A
novel
concept,
nanoarchitectonics,
combine
nanotechnology
other
scientific
disciplines
synthesize
a
functional
system
contributions
small
objects,
nano‐units,
recently
proposed.
Based
on
facts
knowledge
nanoscale
objects
explored
by
nanotechnology,
systems
are
constructed
using
nano‐units
aid
research
fields,
such
as
organic
chemistry,
supramolecular
materials
science,
biology.
The
introduction
nanoarchitectonics
essences
construction
can
produce
unusual
systems,
brain‐like
information
processing
based
atomic‐level
reactions,
diffusions,
aggregations.
Probe‐tip‐mediated
reactions
also
possible
precise
site
selectivity.
coupling
equilibrium
self‐assemblies
non‐equilibrium
fabrication
processes
results
variously
structured
hierarchical
structures
even
from
simple
0D
fullerenes.
Especially,
interfacial
directly
bridge
nanoscopic
functions
macroscopic
actions,
including
facile
contact
nanostructures
living
cells.
This
review
article
overviews
origin
future,
atoms
materials,
big
technology.
Chemical Reviews,
Год журнала:
2022,
Номер
122(6), С. 6459 - 6513
Опубликована: Фев. 3, 2022
The
Langmuir–Blodgett
(LB)
technique,
through
which
monolayers
are
transferred
from
the
air/water
interface
onto
a
solid
substrate,
was
first
method
to
allow
for
controlled
assembly
of
organic
molecules.
With
its
almost
100
year
history,
it
has
been
inspiration
most
methods
functionalize
surfaces
and
produce
nanocoatings,
in
addition
serving
explore
concepts
molecular
electronics
nanoarchitectonics.
This
paper
provides
an
overview
history
Langmuir
LB
films,
including
potential
use
devices
discussion
on
why
films
seldom
considered
practical
applications
today.
Emphasis
is
then
given
two
areas
where
these
offer
unique
opportunities,
namely,
mimicking
cell
membrane
models
exploiting
nanoarchitectonics
sensors,
investigate
recognitions,
assemble
machines.
promising
topics
short-
long-term
prospects
technique
also
highlighted.
Nanoscale Horizons,
Год журнала:
2021,
Номер
6(5), С. 364 - 378
Опубликована: Янв. 1, 2021
The
nanoarchitectonics
concept
has
the
ability
to
bridge
nanoscale
science
and
visual
size
materials.
final
goal
of
approaches
is
creation
living-creature-like
functional
material
systems
from
simple
objects.
Coordination Chemistry Reviews,
Год журнала:
2023,
Номер
481, С. 215043 - 215043
Опубликована: Фев. 13, 2023
As
the
structure
and
properties
of
anisotropic
metal–organic
frameworks
(MOFs)
vary
with
certain
directions
in
space,
controlling
orientation
these
MOFs
allows
full
advantage
to
be
taken
their
properties.
Not
surprisingly,
preparation
oriented
MOFs,
has
drawn
great
attention
past
decade.
In
this
review,
we
systematically
summarized
strategies
utilized
for
growth
highlighting
possibilities
each
synthetic
approach
as
well
challenges
they
have
overcome.
Herein,
also
explored
MOF-on-MOF
hybrids.
Finally,
presented
advantages
MOF
crystals
over
randomly
counterparts
different
applications,
including
adsorptions,
separations,
catalysis,
sensing,
energy
storage,
etc.
We
hope
review
shows
tremendous
helps
reader
better
comprehend
synthesis,
properties,
applications.
Angewandte Chemie International Edition,
Год журнала:
2020,
Номер
59(36), С. 15424 - 15446
Опубликована: Март 14, 2020
Abstract
Incorporation
of
non‐equilibrium
actions
in
the
sequence
self‐assembly
processes
would
be
an
effective
means
to
establish
bio‐like
high
functionality
hierarchical
assemblies.
As
a
novel
methodology
beyond
self‐assembly,
nanoarchitectonics,
which
has
as
its
aim
fabrication
functional
materials
systems
from
nanoscopic
units
through
methodological
fusion
nanotechnology
with
other
scientific
disciplines
including
organic
synthesis,
supramolecular
chemistry,
microfabrication,
and
bio‐process,
been
applied
this
strategy.
The
application
factors
conventional
is
discussed
on
basis
examples
directed
assembly,
Langmuir–Blodgett
layer‐by‐layer
assembly.
In
particular,
structures
using
bio‐active
components
such
proteins
or
by
combination
bio‐components
two‐dimensional
nanomaterials,
are
described.
Methodologies
described
review
article
highlight
possible
approaches
nanoarchitectonics
concept
for
creation
higher
functionalities
structural
organization.
Physical Chemistry Chemical Physics,
Год журнала:
2021,
Номер
24(7), С. 4097 - 4115
Опубликована: Дек. 2, 2021
While
the
layer-by-layer
(LbL)
assembly
method
has
already
reached
a
certain
maturity,
there
is
still
plenty
of
room
for
expanding
its
usefulness
fabrication
nanoarchitectonics-based
materials
and
devices.
Bulletin of the Chemical Society of Japan,
Год журнала:
2023,
Номер
97(1)
Опубликована: Дек. 1, 2023
Abstract
Nanotechnology
has
revealed
the
science
of
nanoscale.
The
global
challenge
that
will
follow
is
to
build
functional
materials
with
knowledge
nanoscale
phenomena.
This
task
carried
out
by
nanoarchitectonics
as
a
postnanotechnology
concept.
goal
material
systems
architecting
atoms,
molecules,
and
nanomaterials
building
blocks.
Fundamentally,
all
are
made
atoms
molecules.
Therefore,
nanoarchitectonics,
which
architects
from
can
be
universal
way
create
materials.
It
may
said
method
for
everything
in
science.
From
basic
units,
living
cells,
complex
systems,
components
nanoarchitectonics.
paper
presents
recent
examples
research
at
various
size
levels,
atomic
cellular
level,
specifically,
(i)
atomistic
(ii)
molecular
(iii)
supramolecular
(iv)
inorganic
(v)
biomolecular
(vi)
cell-mimic
(vii)
cell-based
possibility
science,
an
integrative
then
explored.
Bulletin of the Chemical Society of Japan,
Год журнала:
2022,
Номер
95(5), С. 774 - 795
Опубликована: Март 22, 2022
Abstract
Promoted
understanding
of
nanostructures
and
their
functions
significantly
rely
on
rapid
progress
nanotechnology
within
a
few
decades.
It
would
be
fruitful
way
to
consider
materials
science
through
regulation
nanostructure
regulations
the
basis
nanotechnological
accomplishments.
As
post-nanotechnology
concept,
new
concept
nanoarchitectonics
has
recently
emerged
as
methodology
produce
functional
from
nanoscale
units.
In
this
review
article,
we
discuss
recent
advances
related
approaches
atom-scales
living
cell
sizes.
The
multiscale
are
exemplified
discussed
including
atom
molecules
nanoarchitectonics,
supramolecular
at
cell-scale.
Next,
supracell-level
is
organization
designed
surfaces,
sheets
layered
three-dimensional
biofilms
bioinks,
challenges
for
cells
liquid
interface.
All
formed
with
fundamental
units,
atoms,
molecules,
nanomaterials,
therefore,
basic
units
can
hypothetically
applied
any
kind
material.
Therefore,
could
method
everything
in
an
analogy
theory
physics.
Chemical Communications,
Год журнала:
2024,
Номер
60(16), С. 2152 - 2167
Опубликована: Янв. 1, 2024
In
nanoarchitectonics
approaches,
rational
physical
and
chemical
communications
will
lead
to
the
development
of
more
advanced
functional
materials.
Layer-by-layer
assembly
can
be
a
powerful
tool
for
this
purpose,
as
exemplified
in
feature
paper.
