Angewandte Chemie, Год журнала: 2022, Номер 134(52)
Опубликована: Дек. 7, 2022
Язык: Английский
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 7, 2025
Abstract Solid acid catalysts (SACs) have attracted significant attention for their role in enhancing the carbon capture desorption process, primarily due to active sites. By employing a synergistic strategy involving anchoring and structural design, both catalytic activity durability of catalyst throughout process are optimized. The TiO 2 shell layer Mn CoO 4 @TiO /SO 2− (MC@TiO /S) effectively inhibits leaching species into solution, thereby enabling sustained high over ten cycles absorption–desorption testing. protonated groups (SO ) facilitates novel pathway proton transfer solution via proton‐coupled electron (PCET) effect, significantly reducing activation energy this step reaction kinetics. Consequently, CO regeneration capacity rate increase by 103% 111%, respectively, while consumption during decreases ≈44%. Additionally, environmental performance is evaluated using life cycle assessment (LCA), highlighting its sustainable potential future scale‐up applications. This study presents viable metal oxide solid materials facilitate efficient low‐energy solvent processes.
Язык: Английский
Процитировано
0
Elsevier eBooks, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0
Tetrahedron, Год журнала: 2023, Номер 143, С. 133474 - 133474
Опубликована: Июль 11, 2023
Язык: Английский
Процитировано
6
Chemical Science, Год журнала: 2024, Номер 15(24), С. 9120 - 9126
Опубликована: Янв. 1, 2024
A new chiral UiO-type MOF with scandium tris(dodecyl sulfate) showed superior catalytic performance to the usual micellar catalysis in presence of proteins, demonstrating ability prevent active Lewis acid sites from mortiferous deactivation.
Язык: Английский
Процитировано
2
Beilstein Journal of Organic Chemistry, Год журнала: 2024, Номер 20, С. 2225 - 2233
Опубликована: Сен. 3, 2024
An eco-friendly selective hydrolysis of chain α-oxo ketene N , S -acetals in water for the switchable synthesis β-keto thioesters and amides is reported. In refluxing water, reactions presence 1.0 equiv dodecylbenzenesulfonic acid effectively afforded excellent yield, while were successfully obtained yield when carried out 3.0 NaOH. The green approach to avoids use harmful organic solvents, thiols thiolacetates as well amines, which could result serious environmental safety issues.
Язык: Английский
Процитировано
1
ChemistryOpen, Год журнала: 2024, Номер unknown
Опубликована: Сен. 24, 2024
Abstract An open‐chain iron pyridine‐NHC framework is expanded utilizing a benzimidazole moiety to deepen the understanding of impact electronic variations on NHC epoxidation catalysts, especially regarding stability. The thereby newly obtained iron(II) complex characterized and employed in olefin epoxidation. It remarkably temperature tolerant achieves TOF ca. 10 000 h −1 TON 700 at 60 °C presence Lewis acid Sc(OTf) 3 , displaying equal stability, but lower activity than unmodified (pre‐)catalyst. In addition, synthetic approach towards another ligand containing 2‐imidazoline units described formylation as well hydrolysis hamper its successful synthesis.
Язык: Английский
Процитировано
1
Chemistry - A European Journal, Год журнала: 2023, Номер 29(29)
Опубликована: Март 11, 2023
A straightforward synthesis approach to chiral 1-aryl-2-aminoethanols via the one-pot asymmetric hydrogenation catalyzed by Ir catalyst was developed. This tandem process involves in situ generation of α-amino ketones nucleophilic substitution α-bromoketones with amines and Ir-catalyzed ketone intermediates provide diverse enantiomerically enriched β-amino alcohols. The excellent yields enantioselectivities (up 96 % yield up >99 ee) a wide substrate scope this strategy were obtained.
Язык: Английский
Процитировано
2
Green Chemistry, Год журнала: 2022, Номер 25(2), С. 720 - 727
Опубликована: Дек. 16, 2022
The direct synthesis of β-NH 2 alcohols via flexible ammonolysis epoxides is still a challenging and unresolved problem.
Язык: Английский
Процитировано
3
Chemistry, Год журнала: 2024, Номер 6(1), С. 98 - 152
Опубликована: Янв. 11, 2024
This review collects the recent developments in field of enantioselective scandium-catalyzed transformations published since beginning 2016, illustrating power chiral scandium catalysts to promote all types reactions.
Язык: Английский
Процитировано
0
Journal of the American Chemical Society, Год журнала: 2024, Номер 146(33), С. 22918 - 22922
Опубликована: Авг. 6, 2024
Chiral Lewis acid catalysts are widely used in organic synthesis due to their diverse applications. However, high acidity makes them susceptible deactivation by basic reagents and water. Here, we present a novel strategy for mitigating this using small molecules. By incorporating weakly coordinating anions into the secondary coordination sphere of metal center, designed highly reusable chiral complex. This complex exhibits excellent thermal stability allows use electron-poor nucleophiles reactions. Spectroscopic titration studies confirmed robustness optimized work provides valuable insights overcoming limitations acids environments, expanding potential chemical synthesis.
Язык: Английский
Процитировано
0