Green Chemistry, Год журнала: 2024, Номер 27(3), С. 660 - 669
Опубликована: Дек. 17, 2024
We demonstrate a macromolecular electrolyte engineering strategy to break the Zn 2+ solvation sheath using porphyrin-based additive, which can facilitate formation of Zn-porphyrin complex and achieve superior electrochemical performance.
Язык: Английский
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(16)
Опубликована: Фев. 19, 2024
Bipolar organics fuse the merits of n/p-type redox reactions for better Zn-organic batteries (ZOBs), but face capacity plafond due to low density active units and single-electron reactions. Here we report multielectron redox-bipolar tetranitroporphyrin (TNP) with quadruple two-electron-accepting n-type nitro motifs dual-electron-donating p-type amine moieties towards high-capacity-voltage ZOBs. TNP cathode initiates high-kinetics, hybrid anion-cation 10e
Язык: Английский
Процитировано
37
Advanced Science, Год журнала: 2024, Номер 11(19)
Опубликована: Март 13, 2024
Abstract Zinc‐organic batteries (ZOBs) are receiving widespread attention as up‐and‐coming energy‐storage systems due to their sustainability, operational safety and low cost. Charge carrier is one of the critical factors affecting redox kinetics electrochemical performances ZOBs. Compared with conventional large‐sized sluggish Zn 2+ storage, non‐metallic charge carriers small hydrated size light weight show accelerated interfacial dehydration fast reaction kinetics, enabling superior metrics for Thus, it valuable ongoing works build better ZOBs ion storage. In this review, versatile cationic (H + , NH 4 ) anionic (Cl − OH CF 3 SO 2− first categorized a brief comparison respective physicochemical properties chemical interactions redox‐active organic materials. Furthermore, work highlights implementation effectiveness ions in ZOBs, giving insights into impact types on (capacity, rate capability, operation voltage, cycle life) cathodes. Finally, challenges perspectives non‐metal‐ion‐based outlined guild future development next‐generation energy communities.
Язык: Английский
Процитировано
30
Nano-Micro Letters, Год журнала: 2024, Номер 16(1)
Опубликована: Май 14, 2024
Aqueous zinc-ion batteries (AZIBs) are one of the most compelling alternatives lithium-ion due to their inherent safety and economics viability. In response growing demand for green sustainable energy storage solutions, organic electrodes with scalability from inexpensive starting materials potential biodegradation after use have become a prominent choice AZIBs. Despite gratifying progresses molecules electrochemical performance in AZIBs, research is still infancy hampered by certain issues underlying complex electrochemistry. Strategies designing electrode AZIBs high specific capacity long cycling life discussed detail this review. Specifically, we put emphasis on unique electrochemistry different redox-active structures provide in-depth understanding working mechanisms. addition, highlight importance molecular size/dimension regarding profound impact performances. Finally, challenges perspectives developing point view future We hope valuable evaluation our context give inspiration rational design high-performance
Язык: Английский
Процитировано
30
Advanced Materials, Год журнала: 2024, Номер 36(35)
Опубликована: Июнь 25, 2024
Solid-state batteries (SSBs) have garnered significant attention in the critical field of sustainable energy storage due to their potential benefits safety, density, and cycle life. The large-scale, cost-effective production SSBs necessitates development high-performance solid-state electrolytes. However, manufacturing relies heavily on advancement suitable Composite polymer electrolytes (CPEs), which combine advantages ordered microporous materials (OMMs) electrolytes, meet requirements for high ionic conductivity/transference number, stability with respect electrodes, compatibility established processes, cost-effectiveness, making them particularly well-suited mass SSBs. This review delineates how structural ordering dictates fundamental physicochemical properties OMMs, including ion transport, thermal transfer, mechanical stability. applications prominent OMMs are critically examined, such as metal-organic frameworks, covalent organic zeolites, CPEs, highlighting facilitates fulfillment property requirements. Finally, an outlook is provided, exploring CPEs can be enhanced through dimensional design importance uncovering underlying "feature-function" mechanisms various CPE types underscored.
Язык: Английский
Процитировано
20
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Фев. 14, 2025
Abstract Lithium‐ion batteries (LIBs), known for their high energy density and long cycle life, have become indispensable in everyday applications. Unfortunately, the increasing demand LIBs raises concerns about sustainability of lithium resources. Non‐lithium metal‐ion therefore garnered significant attention due to abundant resources potential cost advantages. Yet, widespread adoption is hindered by limited availability high‐performance cathode materials. Organic electrode materials (OEMs) emerged as promising candidates, owing structural diversity tunability, allowing them accommodate large cations. Despite potential, most OEMs suffer from unsatisfactory cyclability, poor rate performance, low density. This review summarizes recent advancements improving electrochemical performance OEMs, focusing on molecular engineering approaches mitigate dissolution, enhance conductivity The charge storage mechanism current challenges associated with are first discussed. Various strategies designed address these then explored, including linkage improve stability electronic Finally, insights provided future development next‐generation battery technologies beyond LIBs.
Язык: Английский
Процитировано
3
Advanced Functional Materials, Год журнала: 2024, Номер 34(46)
Опубликована: Июль 17, 2024
Abstract VO 2 is considered as one of the most likely cathode materials to be commercialized for large‐scale application in AZIBs and at forefront aqueous batteries, but its lower electrical conductivity, slower Zn 2+ mobility, well voltage degradation structural collapse due vanadium solubilization have limited further development. Herein, a Co‐substitution engineering strategy proposed, which introducing heteroatom Co doping substitution oxygen vacancy stabilize structure promote ionic/electronic leading an enhanced ion storage behavior. The Co‐substituted (Co 0.03 V 0.97 O 2‐x , denote v ‐CoVO) reported this paper, inhibits dissolution AZIBs, even acetionitrile system. DFT calculations show that ‐CoVO has more stable faster electronic/ionic conductivity. Consequently, ‐CoVO||ZnOTF||Zn battery (aqueous) can deliver remarkable capacity 475 mAh g −1 0.2 A with 99.1% retention after 200 cycles, still maintains excellent cycling stability ‐CoVO||ZnTFSI||Zn (acetionitrile electrolyte) 0.1 . In addition, compared charge transfer resistance iffusion coefficient are significantly enhanced. This work broadens scope research high performance ZIBs.
Язык: Английский
Процитировано
15
Chemical Engineering Journal, Год журнала: 2024, Номер 487, С. 150527 - 150527
Опубликована: Март 19, 2024
Язык: Английский
Процитировано
13
Electrochemical Energy Reviews, Год журнала: 2025, Номер 8(1)
Опубликована: Фев. 17, 2025
Язык: Английский
Процитировано
2
Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 12, 2024
Redox-active covalent organic frameworks (COFs) are promising candidates for sodium-ion batteries (SIBs). However, the construction of redox-bipolar COFs with anions and cations co-storage feature SIBs is rarely reported. Herein, COF constructed from aniline-fused quinonoid units (TPAD-COF) developed as cathode material in first time. The unique integration conductive aniline skeletons quinone redox centers endows TPAD-COF high ionic/electrical conductivity, abundant redox-active sites, fascinating bipolar features. Consequently, elaborately tailored exhibits higher specific capacity (186.4 mAh g
Язык: Английский
Процитировано
9
Angewandte Chemie International Edition, Год журнала: 2025, Номер unknown
Опубликована: Янв. 4, 2025
Abstract The crosstalk of transition metal ions between the oxide cathode and Zn anode restricts practical applications aqueous zinc‐ion batteries (ZIBs). Herein, we propose a decoupled electrolyte (DCE) consisting nonaqueous‐phase (N‐phase) anolyte an aqueous‐phase (A‐phase) catholyte to prevent Mn 2+ , thus extending lifespan MnO 2 ‐based ZIBs. Experimental measurements theoretical modelling verify that trimethyl phosphate (TMP) not only synergistically works with NH 4 Cl in N‐phase enable fast conduction while blocking diffusion toward anode, but also modifies solvation structure suppress dendrite formation corrosion on anode. Meanwhile, A‐phase effectively accelerates reaction kinetics. as‐developed Zn|DCE|MnO cell delivers 80.13 % capacity retention after 900 cycles at 0.5 A g −1 . This approach is applicable for other cathode‐based ZIBs, thereby opening new avenue developing ultrastable
Язык: Английский
Процитировано
1