Light-activated hypervalent iodine agents enable diverse aliphatic C–H functionalization

Nature Chemistry, Год журнала: 2025, Номер 17(3), С. 365 - 372

Опубликована: Фев. 24, 2025

Язык: Английский

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Recent Advances in Hydrogen Atom Transfer Induced Selective C(sp³)—H Functionalization of Alkanes

Chinese Journal of Organic Chemistry, Год журнала: 2025, Номер 45(2), С. 477 - 477

Опубликована: Янв. 1, 2025

Язык: Английский

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A Light-Activated Hypervalent Iodine Agent Enables Diverse Aliphatic C–H Functionalization

Опубликована: Май 30, 2024

The functionalization of aliphatic C–H bonds is a crucial step in the synthesis and transformation complex molecules relevant to medicinal, agricultural, materials chemistry. As such, there significant interest development general synthetic platforms that will enable efficient diversification bonds. Here, we report new hypervalent iodine reagent releases potent hydrogen atom abstractor for activation under mild photochemical conditions. Using this reagent, demonstrate selective (N-phenyltetrazole)thiolation broad scope substrates. utility thiolated products showcased through various derivatizations. Simply by altering radical trapping agent, our method can be used directly transform into diverse functionalities, including C–S, C–Cl, C–Br, C–I, C–O, C–N, C–C

Язык: Английский

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Modulating π-bridge in donor-π-acceptor covalent organic frameworks for low-energy-light-driven photocatalytic reaction

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 683, С. 612 - 621

Опубликована: Дек. 26, 2024

Язык: Английский

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