Manganese(I) Catalyzed CO2 Reduction Processes in Homogenous Phase DOI Creative Commons
Sylwia Kostera, Luca Gonsalvi

ChemCatChem, Год журнала: 2023, Номер 16(7)

Опубликована: Дек. 8, 2023

Abstract The catalytic activation of carbon dioxide (CO 2 ) can be a promising tool for the use this abundant, non‐flammable and non‐toxic gas as feedstock C1 chemical synthesis, in particular bulk products such formic acid (HCOOH) methanol (CH 3 OH). key successful, widespread CO is design application efficient, thermally robust cheap catalysts. In last decade, earth‐abundant transition metal complexes, those 3d metals, has shown results. review article, comprehensive summary main systems described literature homogeneous Mn(I)‐catalyzed reduction processes (hydrogenation, hydroboration hydrosilylation) will described, with attention to effect stabilizing ligands, reaction conditions need additives, together mechanistic details often obtained by combination experimental data DFT calculations.

Язык: Английский

Base Metal Catalyst for Indirect Hydrogenation of CO2 DOI Creative Commons
Jagrit Grover, Suman Maji, Chitrala Teja

и другие.

ACS Organic & Inorganic Au, Год журнала: 2023, Номер 3(5), С. 299 - 304

Опубликована: Июль 24, 2023

We herein report a novel Mn-SNS-based catalyst, which is capable of performing indirect hydrogenation CO2 to methanol via formylation. In this domain hydrogenation, pincer ligands have shown clear predominance. Our catalyst based on the SNS-type tridentate ligand, quite stable and cheap as compared type ligands. The can also be recycled effectively after formylation reaction without any significant change in efficiency. Various amines including both primary secondary worked well under protocol provide desired formylated product good yields. formed reduced further at higher pressures hydrogen. As whole, we developed that involves proceeds amines.

Язык: Английский

Процитировано

2
Density functional theory study of CO2 reduction to CH3OH on the surfaces of metal (Cu, Ni, and Mn)-doped carbon nanotubes DOI
Xuefeng Xu, Yan Hao,

Decai Dai

и другие.

Journal of Physics and Chemistry of Solids, Год журнала: 2021, Номер 162, С. 110537 - 110537

Опубликована: Дек. 14, 2021

Язык: Английский

Процитировано

5
Liquid-phase hydrogenation of carbon monoxide to methanol using a recyclable manganese-based catalytic system DOI Creative Commons

Sebastian Stahl,

Niklas Wessel, Andreas J. Vorholt

и другие.

Green Chemistry, Год журнала: 2024, Номер 26(13), С. 7799 - 7805

Опубликована: Янв. 1, 2024

A simple and recyclable homogeneous catalytic system for the hydrogenation of carbon monoxide to methanol was established.

Язык: Английский

Процитировано

0
A robust low coordinate Co(II) catalyst for efficient conversion of CO2 into methanol under mild conditions DOI

Vasudha Sharma,

Amaleswari Rasamsetty, Chinmoy Das

и другие.

Chemical Engineering Journal, Год журнала: 2023, Номер 474, С. 145714 - 145714

Опубликована: Авг. 28, 2023

Язык: Английский

Процитировано

1
Manganese(I) Catalyzed CO2 Reduction Processes in Homogenous Phase DOI Creative Commons
Sylwia Kostera, Luca Gonsalvi

ChemCatChem, Год журнала: 2023, Номер 16(7)

Опубликована: Дек. 8, 2023

Abstract The catalytic activation of carbon dioxide (CO 2 ) can be a promising tool for the use this abundant, non‐flammable and non‐toxic gas as feedstock C1 chemical synthesis, in particular bulk products such formic acid (HCOOH) methanol (CH 3 OH). key successful, widespread CO is design application efficient, thermally robust cheap catalysts. In last decade, earth‐abundant transition metal complexes, those 3d metals, has shown results. review article, comprehensive summary main systems described literature homogeneous Mn(I)‐catalyzed reduction processes (hydrogenation, hydroboration hydrosilylation) will described, with attention to effect stabilizing ligands, reaction conditions need additives, together mechanistic details often obtained by combination experimental data DFT calculations.

Язык: Английский

Процитировано

1