Manganese(I) Catalyzed CO2 Reduction Processes in Homogenous Phase DOI Creative Commons
Sylwia Kostera, Luca Gonsalvi

ChemCatChem, Journal Year: 2023, Volume and Issue: 16(7)

Published: Dec. 8, 2023

Abstract The catalytic activation of carbon dioxide (CO 2 ) can be a promising tool for the use this abundant, non‐flammable and non‐toxic gas as feedstock C1 chemical synthesis, in particular bulk products such formic acid (HCOOH) methanol (CH 3 OH). key successful, widespread CO is design application efficient, thermally robust cheap catalysts. In last decade, earth‐abundant transition metal complexes, those 3d metals, has shown results. review article, comprehensive summary main systems described literature homogeneous Mn(I)‐catalyzed reduction processes (hydrogenation, hydroboration hydrosilylation) will described, with attention to effect stabilizing ligands, reaction conditions need additives, together mechanistic details often obtained by combination experimental data DFT calculations.

Language: Английский

Base Metal Catalyst for Indirect Hydrogenation of CO2 DOI Creative Commons
Jagrit Grover, Suman Maji, Chitrala Teja

et al.

ACS Organic & Inorganic Au, Journal Year: 2023, Volume and Issue: 3(5), P. 299 - 304

Published: July 24, 2023

We herein report a novel Mn-SNS-based catalyst, which is capable of performing indirect hydrogenation CO2 to methanol via formylation. In this domain hydrogenation, pincer ligands have shown clear predominance. Our catalyst based on the SNS-type tridentate ligand, quite stable and cheap as compared type ligands. The can also be recycled effectively after formylation reaction without any significant change in efficiency. Various amines including both primary secondary worked well under protocol provide desired formylated product good yields. formed reduced further at higher pressures hydrogen. As whole, we developed that involves proceeds amines.

Language: Английский

Citations

2
Density functional theory study of CO2 reduction to CH3OH on the surfaces of metal (Cu, Ni, and Mn)-doped carbon nanotubes DOI
Xuefeng Xu, Yan Hao,

Decai Dai

et al.

Journal of Physics and Chemistry of Solids, Journal Year: 2021, Volume and Issue: 162, P. 110537 - 110537

Published: Dec. 14, 2021

Language: Английский

Citations

5
Liquid-phase hydrogenation of carbon monoxide to methanol using a recyclable manganese-based catalytic system DOI Creative Commons

Sebastian Stahl,

Niklas Wessel, Andreas J. Vorholt

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(13), P. 7799 - 7805

Published: Jan. 1, 2024

A simple and recyclable homogeneous catalytic system for the hydrogenation of carbon monoxide to methanol was established.

Language: Английский

Citations

0
A robust low coordinate Co(II) catalyst for efficient conversion of CO2 into methanol under mild conditions DOI

Vasudha Sharma,

Amaleswari Rasamsetty, Chinmoy Das

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 474, P. 145714 - 145714

Published: Aug. 28, 2023

Language: Английский

Citations

1
Manganese(I) Catalyzed CO2 Reduction Processes in Homogenous Phase DOI Creative Commons
Sylwia Kostera, Luca Gonsalvi

ChemCatChem, Journal Year: 2023, Volume and Issue: 16(7)

Published: Dec. 8, 2023

Abstract The catalytic activation of carbon dioxide (CO 2 ) can be a promising tool for the use this abundant, non‐flammable and non‐toxic gas as feedstock C1 chemical synthesis, in particular bulk products such formic acid (HCOOH) methanol (CH 3 OH). key successful, widespread CO is design application efficient, thermally robust cheap catalysts. In last decade, earth‐abundant transition metal complexes, those 3d metals, has shown results. review article, comprehensive summary main systems described literature homogeneous Mn(I)‐catalyzed reduction processes (hydrogenation, hydroboration hydrosilylation) will described, with attention to effect stabilizing ligands, reaction conditions need additives, together mechanistic details often obtained by combination experimental data DFT calculations.

Language: Английский

Citations

1