Renewable N-doped microporous carbons from walnut shells for CO₂ capture and conversion

Sustainable Energy & Fuels, Год журнала: 2021, Номер 5(18), С. 4701 - 4709

Опубликована: Янв. 1, 2021

The development of advanced porous carbon-based materials is a burgeoning field, especially for CO 2 capture and utilization.

Язык: Английский

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Chemical Fixation of Carbon Dioxide by Heterogeneous Porous Catalysts

ChemNanoMat, Год журнала: 2021, Номер 7(6), С. 580 - 591

Опубликована: Апрель 9, 2021

Abstract As the ultimate carbon emission of combustion process, dioxide (CO 2 ) is a serious environmental hazard in increasing global climate temperature through greenhouse effect. Porous heterogeneous catalysts have drawn huge interest for capture and past decades; significant developments can be observed their fabrication implementation CO conversion. In this context, emerging development major porous such as MOFs, COFs, metal oxides etc. conversion are discussed. Their physiochemical properties influence on efficiency enlightened. The review provides concise report various types catalysts, current trends, application reduction fixation synthesis fuels other important fine chemicals future research directions deployment Carbon

Язык: Английский

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Rational design of Cu(I)-anchored porous covalent triazine framework (CTF) for simultaneous capture and conversion of CO2 at ambient conditions

Journal of CO2 Utilization, Год журнала: 2022, Номер 63, С. 102132 - 102132

Опубликована: Июль 22, 2022

Язык: Английский

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Silver Metal–Organic Framework Derived N-Doped Carbon Nanofibers for CO₂ Conversion into β-Oxopropylcarbamates

Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Янв. 24, 2024

Developing efficient heterogeneous catalysts for chemical fixation of CO2 to produce high-value-added chemicals under mild conditions is highly desired but still challenging. Herein, we first reported an approach prepare a novel catalyst (Ag@NCNFs), featuring Ag nanoparticles (NPs) embedded within porous nitrogen-doped carbon nanofibers (NCNFs), via growing metal–organic framework on one-dimensional electrospun followed by pyrolysis. Benefiting from the abundant nitrogen species and structure, NPs well dispersed in obtained Ag@NCNFs. Catalytic studies indicated that Ag@NCNFs exhibited excellent catalytic activity three-component coupling reaction CO2, secondary amines, propargylic alcohols generate β-oxopropylcarbamates with turnover number (TON) 16.2, it can be recycled reused at least 5 times without obvious decline activity. The mechanism was clearly clarified FTIR, NMR, 13C isotope labeling, control experiments, density functional theory calculations. results suggest 1,8-diazabicyclo[5.4.0]undec-7-ene synergistically activate alcohol react then generated α-alkylidene cyclic carbonate invaded amine β-oxopropylcarbamate. Importantly, best our knowledge, this experimental theoretical investigation reaction.

Язык: Английский

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A highly efficient and reusable amorphous Pd(ii)/crystal Pd(0)-grafted porous polymer framework for catalytic CO₂ cycloaddition

New Journal of Chemistry, Год журнала: 2024, Номер 48(22), С. 10010 - 10018

Опубликована: Янв. 1, 2024

Herein, we have developed an elegant strategy to heterogenize a homogeneously active Pd-based catalyst via decoration on porous polymer framework for the cycloaddition of CO 2 and epoxides cyclic carbonates under mild solvent-free conditions.

Язык: Английский

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