Molecules,
Год журнала:
2022,
Номер
27(1), С. 262 - 262
Опубликована: Янв. 1, 2022
In
this
short
review,
we
highlight
the
advancements
in
field
of
palladium-catalyzed
carbon
dioxide
utilization
for
synthesis
high
value
added
organic
molecules.
The
review
is
structured
on
basis
kind
substrate
undergoing
Pd-catalyzed
carboxylation
process.
Accordingly,
after
introductory
section,
main
sections
will
illustrate
olefinic
substrates,
acetylenic
and
other
substrates
(aryl
halides
triflates).
Applied Organometallic Chemistry,
Год журнала:
2022,
Номер
36(8)
Опубликована: Май 24, 2022
Abstract
Carbon
dioxide
(CO
2
)
is
one
of
the
culprit
causes
global
climatic
changes.
Furthermore,
efficient
separation
CO
from
other
gaseous
mixtures
using
zeolitic
imidazolate
framework
(ZIF)‐based
materials
vital
for
several
processes
such
as
flue
gas
separation,
sweetening,
and
natural
processing.
ZIF‐based
are
emerging
adsorbents
catalysts
removal
via
adsorption
conversion
into
valuable
chemicals.
with
high‐adsorption/conversion
efficiencies
tunable
properties
can
be
achieved
by
judicious
synthesis
fabrication
methods.
We
reviewed
catalysis
(e.g.,
cycloaddition,
carboxylation,
hydrogenation,
N
‐formylation,
electrocatalysis,
photocatalysis).
In
addition,
recent
development
methods
membrane
technologies
ways
to
improve
performance
ZIF
membranes
were
highlighted.
The
prospective
point
view
promote
industrial
applications
commercialization
was
briefly
discussed.
Once
challenges
low
reproducibility
solved,
scalability
cost‐effectiveness
should
not
become
issues.
ACS Omega,
Год журнала:
2023,
Номер
8(35), С. 31600 - 31619
Опубликована: Авг. 15, 2023
Catalysts
played
a
crucial
role
in
advancing
modern
human
civilization,
from
ancient
times
to
the
industrial
revolution.
Due
high
cost
and
limited
availability
of
traditional
catalysts,
there
is
need
develop
cost-effective,
high-activity,
nonprecious
metal-based
electrocatalysts.
Metal-organic
frameworks
(MOFs)
have
emerged
as
an
ideal
candidate
for
heterogeneous
catalysis
due
their
physicochemical
properties,
hybrid
inorganic/organic
structures,
uncoordinated
metal
sites,
accessible
organic
sections.
MOFs
are
nanoporous
crystalline
materials
that
can
be
used
catalysts
facilitate
polymerization
reactions.
Their
chemical
structural
diversity
make
them
effective
various
reactions
compared
catalysts.
been
applied
gas
storage
separation,
ion-exchange,
drug
delivery,
luminescence,
sensing,
nanofilters,
water
purification,
catalysis.
The
review
focuses
on
MOF-enabled
value-added
compound
production,
including
alcohol
oxidation,
olefin
oligomerization,
offer
tunable
porosity,
spatial
density,
single-crystal
XRD
control
over
catalyst
properties.
In
this
review,
were
focused
CO2
fixation,
reduction,
photoelectrochemical
splitting.
Overall,
great
potential
versatile
diverse
applications
future.
RSC Advances,
Год журнала:
2025,
Номер
15(8), С. 5977 - 5988
Опубликована: Янв. 1, 2025
Synthesis
and
characterization
of
a
heterogeneous
catalyst
based
on
silica
supported
Zn(
ii
)–hydrazone
complex
its
activity
in
the
chemical
CO
2
fixation
reaction
have
been
reported.
Materials Advances,
Год журнала:
2022,
Номер
3(22), С. 8063 - 8080
Опубликована: Янв. 1, 2022
The
review
provides
a
concise
report
on
various
types
of
COFs,
current
trends,
their
application
in
CO
2
reduction
via
photochemical,
electrochemical
and
photo
coupled
pathways.
Organic & Biomolecular Chemistry,
Год журнала:
2022,
Номер
20(8), С. 1707 - 1722
Опубликована: Янв. 1, 2022
This
study
emphasizes
the
utility
of
a
Zn(
ii
)-functionalized
COF
in
developing
heterogeneous
recyclable
catalytic
system
for
generation
cyclic
carbonates
(up
to
99%
yield)
and
carbamates
94%
under
sustainable
conditions.
Cerium
(IV)-based
metal-organic
frameworks
(MOFs)
are
highly
desirable
due
to
their
unique
potential
in
fields
such
as
redox
catalysis
and
photocatalysis.
However,
the
high
reduction
of
CeIV
species
solution,
it
is
still
a
great
challenge
synthesize
-MOFs
with
novel
structures,
which
extremely
dominated
by
hexanuclear
Ce-O
cluster
inorganic
building
units
(IBUs).
Herein,
IBU
chain
containing
-MOF,
CSUST-3
(CSUST:
Changsha
University
Science
Technology),
was
successfully
prepared
using
kinetic
stabilization
study
UiO-66(Ce)-NDC
(H2
NDC=2,6-naphthalenedicarboxylic
acid).
Furthermore,
owing
superior
activity,
Lewis
acidity
semiconductor-like
behavior
Ce4+
,
activated
demonstrated
be
an
excellent
catalyst
for
CO2
chemical
fixation.
One-pot
synthesis
styrene
carbonate
from
achieved
under
mild
conditions
(1
atm
80
°C,
solvent
free).
Moreover,
shown
remarkable
co-catalyst-free
photocatalyst
overall
water
splitting
(OWS),
rendering
59
μmol
g-1
h-1
H2
22
O2
simulated
sunlight
irradiation
(Na2
S-Na2
SO3
sacrificial
agent).
Materials Advances,
Год журнала:
2022,
Номер
3(7), С. 3165 - 3173
Опубликована: Янв. 1, 2022
We
have
designed
a
nano-sheet-like
porous
organic
polymer
(POP)
constructed
via
schematic
hydrothermal
process
and
characterized
it
using
PXRD,
N
2
adsorption–desorption
studies,
UV-vis,
XPS
microscopic
analyses
(TEM
FESEM).
