Potential of deep eutectic solvents as green and sustainable solvents for the recovery of carboxylic acids from aqueous solution: a review DOI

S. V. Suresh Babu,

Sushil Kumar

Journal of Chemical Technology & Biotechnology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 28, 2025

Abstract This paper presents an in‐depth exploration of the potential deep eutectic solvents (DESs) as green and sustainable in reactive extraction process for recovery carboxylic acids from fermentation broth/aqueous waste stream. It delves into eco‐friendly nature cost‐effectiveness DESs, highlighting their high solvation capabilities aligning with practices. The various hydrophobic DESs/NADESs, examining suitability replacements conventional along preparation, are explored. study emphasizes appropriate selection hydrogen bond donors (HBDs) acceptors (HBAs) DES formulations to enhance efficiency. role physical properties DESs such viscosity, density, surface tension ionic conductivity, which impact mass transfer efficiency discussed. In this review, effect parameters type DES/carboxylic acid, initial acid concentration, pH, aqueous phase ratio, temperature, stirring speed on possible mechanism extracted out. With recent studies using efficient excellent reusability multiple cycles is also concludes recommendations future prospects, emphasizing need optimize compositions intensified technologies scale up practical recovery. © 2025 Society Chemical Industry (SCI).

Язык: Английский

A blessing and a curse: impact of urea derivatives on the secondary building unit of Ca-MOFs prepared in deep eutectic solvents DOI Creative Commons
Michaël Teixeira, Benoît Louis, Stéphane A. Baudron

и другие.

Dalton Transactions, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A recurring secondary building unit is observed in Ca-MOFs prepared deep eutectic solvents based on 1 : 2 combinations of choline chloride and urea derivatives.

Язык: Английский

Процитировано

0

Emerging frontiers in poly (ionic liquids) and poly (deep eutectic solvents) DOI
Yasamin Bide, Ashraf Sadat Shahvelayati,

Elahe Mousavi kherad

и другие.

Journal of Molecular Liquids, Год журнала: 2025, Номер unknown, С. 127171 - 127171

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Pioneering polysaccharide extraction with deep eutectic solvents: A review on impacts to extraction yield, physicochemical properties and bioactivities DOI
Muhammad Hasnun Md Yusoff, Muhammad Hakimin Shafie

International Journal of Biological Macromolecules, Год журнала: 2025, Номер 306, С. 141469 - 141469

Опубликована: Фев. 25, 2025

Язык: Английский

Процитировано

0

Physicochemical and Biological Properties of Menthol and Thymol-Based Natural Deep Eutectic Solvents DOI Creative Commons
Martina Bagović,

Martina Železnjak,

Ksenija Markov

и другие.

Molecules, Год журнала: 2025, Номер 30(8), С. 1713 - 1713

Опубликована: Апрель 11, 2025

Seven hydrophobic deep eutectic solvents (hDESs) were characterised to evaluate their potential applicability in different industries and environmental impact. Standard physicochemical properties determined, yielding polarity density values that slightly higher for thymol-based hDESs than menthol-based ones, whereas viscosity, the trend was opposite. Regarding biologically relevant activities, antioxidative capacity antimicrobial activity of determined. Thymol-based are more potent as antioxidants, especially one with coumarin a hydrogen bond acceptor, which had highest Oxygen Radical Absorbance Capacity (ORAC) value. Antimicrobial assessed on four bacterial strains yeast strain. Calculated minimal inhibitory concentrations (MICs) showed all possess this activity, even antimycotic effect against C. albicans observed. Furthermore, ensure safety these human use, vitro cytocompatibility tested three cell lines (HaCaT, CaCo-2, HeLa), no cytotoxic observed up 1000 mg L-1. Finally, impact by phytotoxicity test assay wheat determined selected hDESs, found be toxic, effects plant defence mechanisms induced stress. Overall, terpene-based demonstrate alternative various industries, including food production, cosmetics, pharmaceuticals, variants exhibiting slight advantage relation parameters evaluated study.

Язык: Английский

Процитировано

0

Potential of deep eutectic solvents as green and sustainable solvents for the recovery of carboxylic acids from aqueous solution: a review DOI

S. V. Suresh Babu,

Sushil Kumar

Journal of Chemical Technology & Biotechnology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 28, 2025

Abstract This paper presents an in‐depth exploration of the potential deep eutectic solvents (DESs) as green and sustainable in reactive extraction process for recovery carboxylic acids from fermentation broth/aqueous waste stream. It delves into eco‐friendly nature cost‐effectiveness DESs, highlighting their high solvation capabilities aligning with practices. The various hydrophobic DESs/NADESs, examining suitability replacements conventional along preparation, are explored. study emphasizes appropriate selection hydrogen bond donors (HBDs) acceptors (HBAs) DES formulations to enhance efficiency. role physical properties DESs such viscosity, density, surface tension ionic conductivity, which impact mass transfer efficiency discussed. In this review, effect parameters type DES/carboxylic acid, initial acid concentration, pH, aqueous phase ratio, temperature, stirring speed on possible mechanism extracted out. With recent studies using efficient excellent reusability multiple cycles is also concludes recommendations future prospects, emphasizing need optimize compositions intensified technologies scale up practical recovery. © 2025 Society Chemical Industry (SCI).

Язык: Английский

Процитировано

0