Dalton Transactions,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
A
recurring
secondary
building
unit
is
observed
in
Ca-MOFs
prepared
deep
eutectic
solvents
based
on
1
:
2
combinations
of
choline
chloride
and
urea
derivatives.
Molecules,
Journal Year:
2025,
Volume and Issue:
30(8), P. 1713 - 1713
Published: April 11, 2025
Seven
hydrophobic
deep
eutectic
solvents
(hDESs)
were
characterised
to
evaluate
their
potential
applicability
in
different
industries
and
environmental
impact.
Standard
physicochemical
properties
determined,
yielding
polarity
density
values
that
slightly
higher
for
thymol-based
hDESs
than
menthol-based
ones,
whereas
viscosity,
the
trend
was
opposite.
Regarding
biologically
relevant
activities,
antioxidative
capacity
antimicrobial
activity
of
determined.
Thymol-based
are
more
potent
as
antioxidants,
especially
one
with
coumarin
a
hydrogen
bond
acceptor,
which
had
highest
Oxygen
Radical
Absorbance
Capacity
(ORAC)
value.
Antimicrobial
assessed
on
four
bacterial
strains
yeast
strain.
Calculated
minimal
inhibitory
concentrations
(MICs)
showed
all
possess
this
activity,
even
antimycotic
effect
against
C.
albicans
observed.
Furthermore,
ensure
safety
these
human
use,
vitro
cytocompatibility
tested
three
cell
lines
(HaCaT,
CaCo-2,
HeLa),
no
cytotoxic
observed
up
1000
mg
L-1.
Finally,
impact
by
phytotoxicity
test
assay
wheat
determined
selected
hDESs,
found
be
toxic,
effects
plant
defence
mechanisms
induced
stress.
Overall,
terpene-based
demonstrate
alternative
various
industries,
including
food
production,
cosmetics,
pharmaceuticals,
variants
exhibiting
slight
advantage
relation
parameters
evaluated
study.
