Recent progress of NH2-MIL-125(Ti)-based photocatalytic system in energy production and environmental purification
Chemical Engineering Journal,
Год журнала:
2024,
Номер
497, С. 154689 - 154689
Опубликована: Авг. 14, 2024
Язык: Английский
Robust Noble Metal-Free Photoconversion of CO2 to CO with a Molecule/MOF Hybrid Catalyst for Straightforward Two-Chamber Organic Carbonylation
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 3546 - 3557
Опубликована: Фев. 12, 2025
Язык: Английский
Metal–Organic Frameworks: Synthesis Methods and Multifunctional Applications
Energy Technology,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 27, 2025
Metal–organic
frameworks
(MOFs)
have
emerged
as
a
transformative
class
of
materials
in
science
and
chemistry
due
to
their
exceptional
porosity
structural
tunability.
Composed
metal
ions
or
clusters
intricately
coordinated
with
organic
ligands,
MOFs
form
highly
ordered
3D
networks
well‐defined
pores
channels.
These
unique
characteristics
enable
precise
customization
pore
size,
shape,
functionality
through
the
selection
appropriate
unlocking
diverse
applications
across
multiple
fields.
This
review
provides
comprehensive
exploration
MOFs,
focusing
on
synthesis,
properties,
versatility.
Key
areas
discussion
include
MOFs’
potential
for
catalytic
activity,
gas
storage,
sensing,
drug
delivery.
Of
particular
importance
is
role
environmental
remediation,
energy
biomedical
applications,
demonstrating
adaptability
modern
challenges.
However,
significant
barriers
such
scalability,
long‐term
stability,
economic
viability
must
be
addressed
widespread
adoption.
By
detailing
state‐of‐the‐art
advancements,
this
highlights
unparalleled
ability
achieve
precision
efficiency
targeted
offering
valuable
insights
emerging
researchers.
The
findings
underscore
pivotal
addressing
contemporary
scientific
industrial
challenges,
paving
way
innovative
solutions
energy,
environment,
health.
Язык: Английский
Recent advances in Ni-based electrocatalysts for low-energy hydrogen production via alternative pathways to water electrolysis
Myungjoon Kim,
Sehyun Joung,
S.-G. Lee
и другие.
Energy Materials,
Год журнала:
2025,
Номер
5(8)
Опубликована: Май 6, 2025
Energy-efficient
water
electrolysis
is
one
of
the
most
promising
techniques
for
generating
green
hydrogen
as
a
carbon-free
energy
source.
As
half-reaction
splitting,
oxygen
evolution
reaction
kinetically
sluggish,
leading
to
large
thermodynamic
potential
gaps
compared
reaction.
In
terms
cost-effective
generation,
mitigating
this
overpotential
challenging
obstacle,
but
it
remains
hurdle
overcome.
It
necessary
advance
energy-saving
production
by
substituting
with
an
thermodynamically
favorable
anodic
Additionally,
depending
on
specific
small
molecules
used
oxidation
reaction,
possible
reduce
environmentally
harmful
substances
and
produce
value-added
chemicals.
Nickel-based
electrocatalysts
have
received
growing
attention
their
application
in
electrochemical
reactions
due
affordability,
versatility
structural
tuning,
ability
function
active
sites
bond
formation
cleavage.
The
purpose
paper
probe
how
morphology,
structure,
composition
these
catalysts
affect
electrocatalyst
performance
molecule
oxidation.
Explaining
relationships
can
accelerate
development
sustainable
identifying
design
principles
high-performance
nickel-based
electrocatalysts.
Язык: Английский
Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants?
Molecules,
Год журнала:
2024,
Номер
29(19), С. 4623 - 4623
Опубликована: Сен. 29, 2024
This
overview
provides
insights
into
organic
and
metal–organic
polymer
(OMOP)
catalysts
aimed
at
processes
carried
out
in
the
liquid
phase.
Various
types
of
polymers
are
discussed,
including
vinyl
(various
functional
poly(styrene-co-divinylbenzene)
perfluorinated
functionalized
hydrocarbons,
e.g.,
Nafion),
condensation
(polyesters,
-amides,
-anilines,
-imides),
additional
(polyurethanes,
polyureas,
polybenzimidazoles,
polyporphyrins),
prepared
from
organometal
monomers.
Covalent
frameworks
(COFs),
(MOFs),
their
composites
represent
a
significant
class
OMOP
catalysts.
Following
this,
preparation,
characterization,
application
dispersed
metal
discussed.
Key
catalytic
such
as
alkylation—used
large-scale
applications
like
production
alkyl-tert-butyl
ether
bisphenol
A—as
well
reduction,
oxidation,
other
reactions,
highlighted.
The
versatile
properties
COFs
MOFs,
well-defined
nanometer-scale
pores,
large
surface
areas,
excellent
chemisorption
capabilities,
make
them
highly
promising
for
chemical,
electrochemical,
photocatalytic
applications.
Particular
emphasis
is
placed
on
potential
CO2
treatment.
However,
notable
drawback
COF-
MOF-based
relatively
low
stability
both
alkaline
acidic
environments,
high
cost.
A
special
part
devoted
to
deactivation
disposal
used/deactivated
catalysts,
emphasizing
importance
separating
heavy
metals
conclusion
guidance
selecting
developing
OMOP-based
Язык: Английский
Data‐Driven Innovation in Metal‐Organic Frameworks Photocatalysis: Bridging Gaps for CO2 Capture and Conversion with FAIR Principles
Advanced Energy and Sustainability Research,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 30, 2024
Metal‐organic
frameworks
(MOFs)
have
emerged
as
key
materials
for
carbon
capture
and
conversion,
particularly
in
photocatalytic
CO
2
reduction.
However,
inconsistent
reporting
of
essential
parameters
the
literature
hinders
informed
decisions
about
material
selection
optimization.
This
perspective
highlights
need
a
user‐friendly,
centralized
database
supported
by
automated
data
extraction
using
natural
language
processing
tools
to
streamline
comparisons
MOF
materials.
By
consolidating
crucial
from
scientific
literature,
such
promotes
efficient
decision‐making
utilization.
Emphasizing
significance
open‐source
initiatives
principles
FAIR
data—ensuring
are
Findable,
Accessible,
Interoperable,
Reusable—a
collaborative
approach
management
sharing
is
advocated
for.
Making
database‐accessible
worldwide
enhances
quality
reliability,
fostering
innovation
progress
conversion
Additionally,
databases
valuable
creating
artificial
intelligence
assist
researchers
discovery
synthesis
conversion.
Язык: Английский
Interwoven Porous Pristine Cobalt‐Based Metal‐Organic Framework as an Efficient Photocatalyst for CO2 Reduction
Small Methods,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 27, 2024
Abstract
As
a
desired
utilization
of
the
conversion
CO
2
into
valuable
carbon
fuel
production
under
solar
energy,
it
remains
challenging
due
to
lack
efficient
catalysts.
Herein,
3D
interpenetrating
metal‐organic
framework
[Co(Tipa)(HCOO)
(H
O)]·H
O
(Co‐Tipa)
with
1D
open
channel
is
solvothermally
synthesized
using
semi‐flexible
ligand
(Tipa
=
tri‐(4‐(1
H
‐imidazol‐1‐yl)‐phenyl)amine).
The
tridentate
bridge
ligand‐oriented
periodicity
Co‐Tipa
MOF
combined
ruthenium‐based
photosensitizers
mild
reaction
conditions
form
an
nonhomogeneous
co‐catalyst
for
photocatalytic
reduction
(CO
RR).
crystalline
MOFs
catalyst,
rate,
selectivity,
and
quantum
yield
visible
light
irradiation
offer
outstanding
performance
synergistic
advantages
structural
feature,
metal
center,
organic
ligand.
stability
reusability
in
system
are
profited
from
robust
entangled
framework.
mechanism
how
enhance
RR
assisted
illustration
through
density
functional
theory
(DFT)
calculations.
By
leveraging
unique
properties
MOFs,
this
study
offers
innovative
approaches
development
more
effective
s
catalysts
that
can
selectively
chemicals
fuels.
Язык: Английский