Interwoven Porous Pristine Cobalt‐Based Metal‐Organic Framework as an Efficient Photocatalyst for CO2 Reduction DOI

Zhujuan Ren,

Shuaishuai Wang,

Mengyu Zhu

et al.

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract As a desired utilization of the conversion CO 2 into valuable carbon fuel production under solar energy, it remains challenging due to lack efficient catalysts. Herein, 3D interpenetrating metal‐organic framework [Co(Tipa)(HCOO) (H O)]·H O (Co‐Tipa) with 1D open channel is solvothermally synthesized using semi‐flexible ligand (Tipa = tri‐(4‐(1 H ‐imidazol‐1‐yl)‐phenyl)amine). The tridentate bridge ligand‐oriented periodicity Co‐Tipa MOF combined ruthenium‐based photosensitizers mild reaction conditions form an nonhomogeneous co‐catalyst for photocatalytic reduction (CO RR). crystalline MOFs catalyst, rate, selectivity, and quantum yield visible light irradiation offer outstanding performance synergistic advantages structural feature, metal center, organic ligand. stability reusability in system are profited from robust entangled framework. mechanism how enhance RR assisted illustration through density functional theory (DFT) calculations. By leveraging unique properties MOFs, this study offers innovative approaches development more effective s catalysts that can selectively chemicals fuels.

Language: Английский

Recent progress of NH2-MIL-125(Ti)-based photocatalytic system in energy production and environmental purification DOI
Chengzhang Zhu,

Qihang Tian,

Shipeng Wan

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154689 - 154689

Published: Aug. 14, 2024

Language: Английский

Citations

9
Robust Noble Metal-Free Photoconversion of CO2 to CO with a Molecule/MOF Hybrid Catalyst for Straightforward Two-Chamber Organic Carbonylation DOI

Yuru Zhu,

Yilin Xue,

Zhen Wang

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3546 - 3557

Published: Feb. 12, 2025

Language: Английский

Citations

1
Metal–Organic Frameworks: Synthesis Methods and Multifunctional Applications DOI
Jaykishon Swain,

Anulipsa Priyadarshini,

Swati Panda

et al.

Energy Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 27, 2025

Metal–organic frameworks (MOFs) have emerged as a transformative class of materials in science and chemistry due to their exceptional porosity structural tunability. Composed metal ions or clusters intricately coordinated with organic ligands, MOFs form highly ordered 3D networks well‐defined pores channels. These unique characteristics enable precise customization pore size, shape, functionality through the selection appropriate unlocking diverse applications across multiple fields. This review provides comprehensive exploration MOFs, focusing on synthesis, properties, versatility. Key areas discussion include MOFs’ potential for catalytic activity, gas storage, sensing, drug delivery. Of particular importance is role environmental remediation, energy biomedical applications, demonstrating adaptability modern challenges. However, significant barriers such scalability, long‐term stability, economic viability must be addressed widespread adoption. By detailing state‐of‐the‐art advancements, this highlights unparalleled ability achieve precision efficiency targeted offering valuable insights emerging researchers. The findings underscore pivotal addressing contemporary scientific industrial challenges, paving way innovative solutions energy, environment, health.

Language: Английский

Citations

0
Recent advances in Ni-based electrocatalysts for low-energy hydrogen production via alternative pathways to water electrolysis DOI Open Access

Myungjoon Kim,

Sehyun Joung,

S.-G. Lee

et al.

Energy Materials, Journal Year: 2025, Volume and Issue: 5(8)

Published: May 6, 2025

Energy-efficient water electrolysis is one of the most promising techniques for generating green hydrogen as a carbon-free energy source. As half-reaction splitting, oxygen evolution reaction kinetically sluggish, leading to large thermodynamic potential gaps compared reaction. In terms cost-effective generation, mitigating this overpotential challenging obstacle, but it remains hurdle overcome. It necessary advance energy-saving production by substituting with an thermodynamically favorable anodic Additionally, depending on specific small molecules used oxidation reaction, possible reduce environmentally harmful substances and produce value-added chemicals. Nickel-based electrocatalysts have received growing attention their application in electrochemical reactions due affordability, versatility structural tuning, ability function active sites bond formation cleavage. The purpose paper probe how morphology, structure, composition these catalysts affect electrocatalyst performance molecule oxidation. Explaining relationships can accelerate development sustainable identifying design principles high-performance nickel-based electrocatalysts.

Language: Английский

Citations

0
Organic and Metal–Organic Polymer-Based Catalysts—Enfant Terrible Companions or Good Assistants? DOI Creative Commons
Milan Králik, Peter Koóš, Martin Markovič

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(19), P. 4623 - 4623

Published: Sept. 29, 2024

This overview provides insights into organic and metal–organic polymer (OMOP) catalysts aimed at processes carried out in the liquid phase. Various types of polymers are discussed, including vinyl (various functional poly(styrene-co-divinylbenzene) perfluorinated functionalized hydrocarbons, e.g., Nafion), condensation (polyesters, -amides, -anilines, -imides), additional (polyurethanes, polyureas, polybenzimidazoles, polyporphyrins), prepared from organometal monomers. Covalent frameworks (COFs), (MOFs), their composites represent a significant class OMOP catalysts. Following this, preparation, characterization, application dispersed metal discussed. Key catalytic such as alkylation—used large-scale applications like production alkyl-tert-butyl ether bisphenol A—as well reduction, oxidation, other reactions, highlighted. The versatile properties COFs MOFs, well-defined nanometer-scale pores, large surface areas, excellent chemisorption capabilities, make them highly promising for chemical, electrochemical, photocatalytic applications. Particular emphasis is placed on potential CO2 treatment. However, notable drawback COF- MOF-based relatively low stability both alkaline acidic environments, high cost. A special part devoted to deactivation disposal used/deactivated catalysts, emphasizing importance separating heavy metals conclusion guidance selecting developing OMOP-based

Language: Английский

Citations

2
Data‐Driven Innovation in Metal‐Organic Frameworks Photocatalysis: Bridging Gaps for CO2 Capture and Conversion with FAIR Principles DOI Creative Commons
Claudia Bizzarri, Manuel Tsotsalas

Advanced Energy and Sustainability Research, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Metal‐organic frameworks (MOFs) have emerged as key materials for carbon capture and conversion, particularly in photocatalytic CO 2 reduction. However, inconsistent reporting of essential parameters the literature hinders informed decisions about material selection optimization. This perspective highlights need a user‐friendly, centralized database supported by automated data extraction using natural language processing tools to streamline comparisons MOF materials. By consolidating crucial from scientific literature, such promotes efficient decision‐making utilization. Emphasizing significance open‐source initiatives principles FAIR data—ensuring are Findable, Accessible, Interoperable, Reusable—a collaborative approach management sharing is advocated for. Making database‐accessible worldwide enhances quality reliability, fostering innovation progress conversion Additionally, databases valuable creating artificial intelligence assist researchers discovery synthesis conversion.

Language: Английский

Citations

0
Interwoven Porous Pristine Cobalt‐Based Metal‐Organic Framework as an Efficient Photocatalyst for CO2 Reduction DOI

Zhujuan Ren,

Shuaishuai Wang,

Mengyu Zhu

et al.

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract As a desired utilization of the conversion CO 2 into valuable carbon fuel production under solar energy, it remains challenging due to lack efficient catalysts. Herein, 3D interpenetrating metal‐organic framework [Co(Tipa)(HCOO) (H O)]·H O (Co‐Tipa) with 1D open channel is solvothermally synthesized using semi‐flexible ligand (Tipa = tri‐(4‐(1 H ‐imidazol‐1‐yl)‐phenyl)amine). The tridentate bridge ligand‐oriented periodicity Co‐Tipa MOF combined ruthenium‐based photosensitizers mild reaction conditions form an nonhomogeneous co‐catalyst for photocatalytic reduction (CO RR). crystalline MOFs catalyst, rate, selectivity, and quantum yield visible light irradiation offer outstanding performance synergistic advantages structural feature, metal center, organic ligand. stability reusability in system are profited from robust entangled framework. mechanism how enhance RR assisted illustration through density functional theory (DFT) calculations. By leveraging unique properties MOFs, this study offers innovative approaches development more effective s catalysts that can selectively chemicals fuels.

Language: Английский

Citations

0