Shape‐Selective Zeolites for Tandem CO2 Hydrogenation‐Carbonylation Reactions DOI Open Access
Hendrik Van Dessel, Sam Van Minnebruggen,

Jasper Dedapper

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 8, 2024

Abstract The valorization of carbon dioxide as a C1 building block in C−C bond forming reactions is critical link on the road to carbon‐circular chemistry. Activation this inert molecule through reduction with H 2 monoxide reverse water‐gas shift (RWGS) reaction can be followed by wide spectrum consecutive carbonylation reactions, but RWGS severely equilibrium limited at moderate temperatures carbonylations. Here we successfully reconcile both one pot, while avoiding incompatibilities zeolite‐based compartmentalized approach. More specifically, Pt encapsulated small‐pore LTA zeolite selectively generates mild conditions; an ensuing one‐pot allows continuous consumption CO. Moreover, encapsulation avoids undesired like hydrogenation olefin reactant molecular sieving effect. This strategy was first studied in‐depth for Rh‐catalyzed hydroformylation CO /H , affording aldehydes good yields high regioselectivities. methodology then extended variety carbonylations using synthesis bulk and fine chemicals.

Язык: Английский

Robust Noble Metal-Free Photoconversion of CO2 to CO with a Molecule/MOF Hybrid Catalyst for Straightforward Two-Chamber Organic Carbonylation DOI

Yuru Zhu,

Yilin Xue,

Zhen Wang

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 3546 - 3557

Опубликована: Фев. 12, 2025

Язык: Английский

Процитировано

1
Copper-PMHS System-Enabled Reductive Cyclization of o-Aminobenzamides with CO2 as a Single-Carbon Synthon DOI
Jiang Nan, Lu Zhang,

Rui Cao

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 18, 2025

Chemical utilization of carbon dioxide (CO2) has emerged as a sustainable access for synthesizing high-value chemicals. Continuously designing the more practical reaction systems is large importance. Herein, an unprecedented and powerful copper-PMHS reductive system o-aminobenzamides with CO2 disclosed. Synthetically, diverse range quinazolinones (>70 examples) are rapidly assembled excellent functional group tolerance in good yields. Moreover, building other types heterocycles such benzothiazoles benzimidazoles also allowable. Mechanistically, differing from reported carbonylation cases, this finding represents scarce example single-carbon atom synthon PMHS system.

Язык: Английский

Процитировано

0
Iridium-Catalyzed, Copper-Induced Reductive Cyclization of NO2-Pyrrolarenes with CO2 as a Single-Carbon Source DOI
Qiang Yan, Jiang Nan, Lanxin Zhu

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 25, 2025

A new catalytic conversion type of nitro substrate with CO2 as a single-carbon source is presented, wherein great collection azaheterocycles generated by newly established iridium-catalyzed, copper-induced reductive system. This procedure handily employs poly(methylhydrosiloxane) (PMHS) the reductant to simultaneously realize dual reduction highest oxidation-state and units in one operation. Elaborate mechanistic studies illustrate essential role iridium catalyst reducing NO2 moiety well double functions copper additive subsequent formylation C-H cyclization steps.

Язык: Английский

Процитировано

0
Recent Progress and Strategies on the Design of Zeolite-Based Catalysts for Hydroformylation of Olefins DOI Open Access
M. V. Nenasheva, Д. Н. Горбунов

Catalysts, Год журнала: 2024, Номер 14(12), С. 942 - 942

Опубликована: Дек. 20, 2024

Due to their unique structural and mechanical characteristics, zeolites are of great interest as carriers for the design catalysts. This review is focused on progress in development new zeolite-based catalysts hydroformylation. The procedures materials synthesis modification, methods metal introduction, effect catalyst structure activity, selectivity, stability hydroformylation discussed. highlights role up-to-date analytical techniques fine-tuned active selective greatest achievements over past five years considered detail this demonstrate a high potential Future prospects possible directions upcoming studies regarded.

Язык: Английский

Процитировано

2
Shape‐Selective Zeolites for Tandem CO2 Hydrogenation‐Carbonylation Reactions DOI
Hendrik Van Dessel, Sam Van Minnebruggen,

Jasper Dedapper

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 8, 2024

Abstract The valorization of carbon dioxide as a C1 building block in C−C bond forming reactions is critical link on the road to carbon‐circular chemistry. Activation this inert molecule through reduction with H 2 monoxide reverse water‐gas shift (RWGS) reaction can be followed by wide spectrum consecutive carbonylation reactions, but RWGS severely equilibrium limited at moderate temperatures carbonylations. Here we successfully reconcile both one pot, while avoiding incompatibilities zeolite‐based compartmentalized approach. More specifically, Pt encapsulated small‐pore LTA zeolite selectively generates mild conditions; an ensuing one‐pot allows continuous consumption CO. Moreover, encapsulation avoids undesired like hydrogenation olefin reactant molecular sieving effect. This strategy was first studied in‐depth for Rh‐catalyzed hydroformylation CO /H , affording aldehydes good yields high regioselectivities. methodology then extended variety carbonylations using synthesis bulk and fine chemicals.

Язык: Английский

Процитировано

1
Reductive Transformation of CO2 to Organic Compounds DOI Open Access

An‐Guo Wu,

Jie Ding, Lan Zhao

и другие.

The Chemical Record, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 9, 2024

Carbon dioxide is a major greenhouse gas and safe, abundant, easily accessible, renewable C1 resource that can be chemically converted into high value-added chemicals, fuels materials. The preparation of urea, organic carbonates, salicylic acid, etc. from CO

Язык: Английский

Процитировано

1
Substrate-Controlled Divergent Reductive Cyclization of 2-Arylanilines Using CO2 as a Switching Reagent DOI
Qiang Yan, Jiang Nan,

Rui Cao

и другие.

Organic Letters, Год журнала: 2024, Номер 27(1), С. 510 - 516

Опубликована: Дек. 30, 2024

Capturing CO2 is highly valued in the field of organic synthesis, especially underdeveloped dual-CO2 conversion. In this study, we detail a novel reductive cyclization 2-indolylanilines with dual as difunctional reagent presence PMHS [poly(methylhydrosiloxane)], delivering methyl-substituted quinoxalines. Furthermore, another chemoselective 2-pyrrolylanilines also realized by converting mono-CO2. Mechanistic investigations shed light upon fact that substrate-controlled divergence mainly depends on formation N-diacylative intermediates.

Язык: Английский

Процитировано

1
Shape‐Selective Zeolites for Tandem CO2 Hydrogenation‐Carbonylation Reactions DOI Open Access
Hendrik Van Dessel, Sam Van Minnebruggen,

Jasper Dedapper

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 8, 2024

Abstract The valorization of carbon dioxide as a C1 building block in C−C bond forming reactions is critical link on the road to carbon‐circular chemistry. Activation this inert molecule through reduction with H 2 monoxide reverse water‐gas shift (RWGS) reaction can be followed by wide spectrum consecutive carbonylation reactions, but RWGS severely equilibrium limited at moderate temperatures carbonylations. Here we successfully reconcile both one pot, while avoiding incompatibilities zeolite‐based compartmentalized approach. More specifically, Pt encapsulated small‐pore LTA zeolite selectively generates mild conditions; an ensuing one‐pot allows continuous consumption CO. Moreover, encapsulation avoids undesired like hydrogenation olefin reactant molecular sieving effect. This strategy was first studied in‐depth for Rh‐catalyzed hydroformylation CO /H , affording aldehydes good yields high regioselectivities. methodology then extended variety carbonylations using synthesis bulk and fine chemicals.

Язык: Английский

Процитировано

0