Hydro-phosphorothiolation of Styrene and Cyclopropane with S-Hydrogen Phosphorothioates under Ambient Conditions
Organic Letters,
Год журнала:
2024,
Номер
26(24), С. 5141 - 5145
Опубликована: Июнь 7, 2024
A
metal-free
hexafluoroisopropanol-mediated
hydro-phosphorothiolation
of
styrenes
and
donor-acceptor
cyclopropanes
with
Язык: Английский
HFIP-Mediated Cascade Aminomethylation and Intramolecular Cyclization of Allenamides with N,O-Acetals to Access Tetrahydro-β-carboline Derivatives
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
cascade
of
two
C–C
bond
forming
reactions
promoted
alone
by
HFIP
is
described
delivering
tetrahydro-β-carboline
derivatives
embedded
with
an
allylic
amine
functionality.
Язык: Английский
Research Progress of Homogeneous Catalytic Reactions of Hexafluoroisopropanol (HFIP)
Tetrahedron Green Chem,
Год журнала:
2025,
Номер
5, С. 100071 - 100071
Опубликована: Фев. 27, 2025
Язык: Английский
Hexafluoroisopropanol (HFIP)-Mediated Intramolecular Cyclization of Allenamides To Access C1-Vinyl Tetrahydro-β-carbolines
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(16), С. 11783 - 11788
Опубликована: Июль 26, 2024
The
construction
of
biologically
interesting
N-heterocycles
under
metal-free
conditions
is
a
constant
goal
in
industry
and
academia.
Herein,
we
have
developed
an
hexafluoroisopropanol
(HFIP)-mediated
intramolecular
cyclization
allenamides,
providing
tetrahydro-β-carboline
derivatives
embedded
with
C1-vinyl
functionality.
protocol
provided
atom-efficiently
room
temperature
broad
substrate
scope
good
to
excellent
yields.
potential
impact
the
further
highlighted
by
synthesizing
important
molecules
diversified
scaffolds
via
postsynthetic
modifications.
Язык: Английский