Development of a chitosan-gold nanocomposite based disposable pencil graphite electrode for the selective detection of thiram in peach juice DOI
Nazife Aslan, Nilgün Şen,

Melike Akan

и другие.

International Journal of Environmental & Analytical Chemistry, Год журнала: 2024, Номер unknown, С. 1 - 15

Опубликована: Май 13, 2024

Hazardous chemicals that are mostly employed in modern agriculture for pest management have caused long-term environmental accumulation as well major issues with food safety and human health. So, there is an urgent demand efficient detection methods monitoring. To do this, the most contemporary electrochemical sensor technology suggested. In this study, a new has been developed to detect thiram (Th) fungicide, utilising modified activated pencil graphite electrode (a-PGE) made from chitosan-gold nanoparticle polymer (Ch-AuNPs) first time. The Ch-AuNPs/a-PGE surface characterised using cyclic voltammetry (CV), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS). Following adjustments experimental parameters, proposed demonstrated linear calibration curve within range of 4.90–140 μM, displaying rapid response limit 1.15 μM. exhibited notable selectivity, stability, reproducibility. assess its practical utility, was applied analyse peach juice, recovery process indicated effectiveness practical, swift, tool pesticide residue

Язык: Английский

DNA-Coupled AuNPs@CuMOF for Sensitive Electrochemical Detection of Carcinoembryonic Antigen DOI
Mohamed Bahri, Zina Fredj, Peiwu Qin

и другие.

ACS Applied Nano Materials, Год журнала: 2024, Номер 7(10), С. 11921 - 11930

Опубликована: Май 16, 2024

Detecting preinvasive tumors before the onset of advanced clinical symptoms represents a critical advancement in improving efficacy early medical interventions and reducing cancer-related mortality rates. Immunosensors have emerged as preferred choice for analyzing oncomarkers meeting ever-increasing demands diagnostics. Therefore, quest development highly specific sensitive immunosensors remains most sought-after to open new avenues personalized healthcare monitoring. Here, we report amplification-free nonlabeled DNA framework-coupled AuNPs@CuMOF ultrasensitive electrochemical detection carcinoembryonic antigen (CEA). Upon CEA concentration variation from 0.0001 200 ng mL–1, proposed biosensor led limit (LOD) 0.25 pg surpassing previously published biosensors that rely on methods aligns with those based amplification techniques. Furthermore, suggested immunosensor demonstrated auspiciously high specificity sensitivity detecting human serum comparable commercial ELISA within relative error falling between 6.25% 2.26%. The analytical approach, hinging synergy effect CuMOF's large surface area mechanical rigidity three-dimensional tetrahedron structured probes (3D TDNA), obviously broadens potential immunosensors, offering higher lower LOD. this work is not only an expansion CuMOF exploitation biosensing but also major milestone diverse biomarkers settings tumor diagnosis.

Язык: Английский

Процитировано

8

Electrochemical Sensor Based on Tadpole-Shaped Au Nanostructures Supported on TiO2: Enhanced Detection of Nicotine in Electronic Cigarettes and Clinical Samples DOI
Antônio Gomes dos Santos Neto, Camila Silva de Sousa,

Carleane Patrícia da Silva Reis

и другие.

Talanta, Год журнала: 2025, Номер unknown, С. 127652 - 127652

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

A novel perspective for estimating the passivation and energy storage characteristics in micro-mass coatings using CV, EIS, and EQCM techniques: Ultrahigh supercapacitor behaviors of Bismarck Brown R and Bismarck Brown Y polymer films DOI
Lokman Liv,

Serap Gençtürk Tosun

Journal of Energy Storage, Год журнала: 2025, Номер 115, С. 115985 - 115985

Опубликована: Фев. 27, 2025

Язык: Английский

Процитировано

1

Catalytic Competence of Gold Clusters Decorated Yellow 2 G Polymer Composite Film for Voltammetric Sensing of Dopamine and Nicotine in Biological Fluids DOI
Lokman Liv

Synthetic Metals, Год журнала: 2024, Номер 309, С. 117765 - 117765

Опубликована: Окт. 9, 2024

Язык: Английский

Процитировано

4

Batch-fabricated full glassy carbon fibers for real-time tonic and phasic dopamine detection DOI Creative Commons

Umisha Siwakoti,

May Yoon Pwint,

Austin M. Broussard

и другие.

Frontiers in Bioengineering and Biotechnology, Год журнала: 2025, Номер 13

Опубликована: Фев. 28, 2025

Dopamine (DA) is a critical neurotransmitter that key in regulating motor functions, motivation, and reward-related behavior. Measuring both tonic (baseline, steady-state) phasic (rapid, burst-like) DA release essential for elucidating the mechanisms underlying neurological disorders, such as schizophrenia Parkinson’s disease, which are associated with dysregulated signaling. Carbon fiber microelectrodes (CFEs) considered gold standard measuring rapid changes due to their small size (5–10 µm), biocompatibility, flexibility, excellent electrochemical properties. However, achieving consistent results large-scale production of CFE arrays through manual fabrication poses significant challenges. We previously developed flexible glassy carbon (GC) microelectrode (MEAs) GC fiber-like MEAs (GCF MEAs) detection electrophysiology recording. also demonstrated feasibility fabricating MEA electrodes interconnects made from single homogeneous material, eliminating need metal interconnections addressing related concerns about electrical mechanical stability under prolonged cycling. Building on our prior experience, we now present double-etching microfabrication technique batch 10 μm × µm full fibers (fGCFs) fGCF arrays, composed entirely material. This process uses 2 µm-thick low-stress silicon nitride bottom insulator layer fGCFs. The effectiveness was validated scanning electron microscophy (SEM) energy dispersive X-ray spectroscopy (EDS) elemental analyses, confirmed uniformity Si₃N₄ insulation ensured overall integrity Using finite element analysis, optimized form factor achieve self-penetration up 3 mm into mouse striatum without additional support. characterization fGCFs high conductivity wide window. ability detect using fast scan cyclic voltammetry (FSCV) square wave (SWV), respectively, vitro vivo . With sensitivity detection, combined scalable self-supporting insertion capability, promising sensors offer enhanced practicality comprehensive monitoring.

Язык: Английский

Процитировано

0

A first in class disposable copolymer-graphite platform for electrocatalytic detection of dipicrylamine explosive in wastewater and soil samples DOI

Ecenur Daşdemir,

Nazife Aslan, Nilgün Şen

и другие.

Microchemical Journal, Год журнала: 2025, Номер unknown, С. 113930 - 113930

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Nitrogen-Doped Carbon Nanosheet/Poly(amidoamine) Dendrimer-based Electrochemical Sensor for Nicotine in Flavored Hookah Pipe Tobacco DOI Creative Commons

Sesethu Makaluza,

Nyasha Midzi,

Foluke O. G. Olorundare

и другие.

Analytical Methods, Год журнала: 2024, Номер 16(44), С. 7518 - 7526

Опубликована: Янв. 1, 2024

Towards the nicotine addiction challenge in smoking of hookah pipe products, we hereby present development an electrochemical sensor for detection. A nitrogen-doped carbon nanosheet (N-CNS)/poly(amidoamine) dendrimer (PAMAM) nanocomposite-modified electrode was prepared as a detection analytical and real samples. The N-CNSs were by hydrothermal method dropcast on glassy followed electro-deposition PAMAM to form (GCE/N-CNSs/PAMAM). characterized with electron microscopy, Raman spectroscopy FTIR. voltammetry impedance spectroscopy. N-CNS/PAMAM enhanced performance towards oxidation nicotine. achieved limit 0.05 μM linear concentration range 1.93-61.64 standard showed good reproducibility, repeatability, selectivity. successful selectively detecting two local brands tobacco 113-121 percent recovery. Nicotine, up 0.35-0.39 mg g

Язык: Английский

Процитировано

2

Sunset Yellow-Cu(II) Complex: DFT-supported electrochemical investigation and determination of Cu(II) ions in human serum and artificial sweat DOI
Lokman Liv,

Serap Gençtürk Tosun,

Zekihan Özerdem

и другие.

Microchemical Journal, Год журнала: 2024, Номер 208, С. 112441 - 112441

Опубликована: Дек. 11, 2024

Язык: Английский

Процитировано

0

Development of a chitosan-gold nanocomposite based disposable pencil graphite electrode for the selective detection of thiram in peach juice DOI
Nazife Aslan, Nilgün Şen,

Melike Akan

и другие.

International Journal of Environmental & Analytical Chemistry, Год журнала: 2024, Номер unknown, С. 1 - 15

Опубликована: Май 13, 2024

Hazardous chemicals that are mostly employed in modern agriculture for pest management have caused long-term environmental accumulation as well major issues with food safety and human health. So, there is an urgent demand efficient detection methods monitoring. To do this, the most contemporary electrochemical sensor technology suggested. In this study, a new has been developed to detect thiram (Th) fungicide, utilising modified activated pencil graphite electrode (a-PGE) made from chitosan-gold nanoparticle polymer (Ch-AuNPs) first time. The Ch-AuNPs/a-PGE surface characterised using cyclic voltammetry (CV), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS). Following adjustments experimental parameters, proposed demonstrated linear calibration curve within range of 4.90–140 μM, displaying rapid response limit 1.15 μM. exhibited notable selectivity, stability, reproducibility. assess its practical utility, was applied analyse peach juice, recovery process indicated effectiveness practical, swift, tool pesticide residue

Язык: Английский

Процитировано

0