Green development of molecularly imprinted polymers and the application in CO2 adsorption and separation: A review
Separation and Purification Technology,
Год журнала:
2025,
Номер
unknown, С. 131784 - 131784
Опубликована: Янв. 1, 2025
Язык: Английский
Green chemistry advances: integrating digital images and microextraction
TrAC Trends in Analytical Chemistry,
Год журнала:
2024,
Номер
unknown, С. 118022 - 118022
Опубликована: Окт. 1, 2024
Язык: Английский
Rapid Separation of Representative Monomer Compound Rutin From Natural Product by Molecularly Imprinted Macroporous Adsorption Resin
Yue Qi,
Xueqin Jin,
Yuepeng Yang
и другие.
Journal of Separation Science,
Год журнала:
2025,
Номер
48(1)
Опубликована: Янв. 1, 2025
ABSTRACT
Monomer
compounds
from
natural
products
are
the
major
source
of
active
pharmaceutical
molecules,
which
provide
great
opportunities
for
discovering
new
drugs.
However,
contain
a
large
number
rather
complex
compounds.
It
is
difficult
to
obtain
high‐purity
monomer
products.
Herein,
we
developed
molecularly
imprinted
macroporous
adsorption
resins
(MIRs‐PDA)
selective
target
The
response
surface
methodology
was
employed
optimize
fabrication
parameters.
separation
performance
MIRs‐PDA
representative
compound
rutin
thoroughly
studied.
We
found
that
presented
capacity
(107.82
mg/g),
high
selectivity
(selectivity
coefficient
2.90),
good
repeatability,
and
reusability.
can
reach
78.5%
equilibrium
in
20
min,
showing
quick
binding
kinetic
behavior.
Furthermore,
showed
specific
real
sample
Fagopyrum
tataricum
extract
solution.
study
mechanism
on
spontaneous
thermodynamically
feasible.
parameters
adapted
well
pseudo‐second‐order
model,
there
existed
equivalent
sites
MIRs‐PDA.
show
promising
application
prospects
Язык: Английский
A Molecularly Imprinted Polymer-Based Porous Silicon Optical Sensor for Quercetin Detection in Wines
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 11, 2025
Quercetin
(QU),
a
bioactive
flavonoid
with
significant
nutritional
and
antioxidant
properties,
plays
vital
role
in
the
quality
stability
of
wine.
This
study
presents
development
molecularly
imprinted
polymer
(MIP)-based
optical
sensor
for
selective
sensitive
detection
quercetin
red
white
wines.
The
combines
molecular
recognition
capabilities
MIPs
properties
nanostructured
porous
silica
(PSiO2)
scaffolds,
which
serve
as
transducer.
MIP
synthesis
was
achieved
through
novel
room-temperature
vapor-phase
polymerization
method
using
pyrrole
functional
monomer.
Computational
simulations
were
used
to
optimize
interactions
QU
at
level,
explore
binding
resulting
polypyrrole
(PPy)
matrix.
Comprehensive
characterization
including
UV–vis
reflectance
spectroscopy
advanced
surface
analyses
confirmed
successful
formation.
exhibited
high
sensitivity
dual
linear
response
range
(2.5–80
μM
80–200
μM),
limit
0.7
μM.
Selectivity
tests
against
structurally
similar
flavonoids
antioxidants
demonstrated
significantly
higher
quercetin,
an
imprinting
factor
3.6.
validated
real
wine
samples,
demonstrating
ability
detect
without
prior
sample
preparation.
Results
showed
strong
agreement
high-performance
liquid
chromatography
(HPLC),
confirming
reliability.
Additionally,
excellent
reusability
minimal
signal
variation
(RSD
=
2.6%)
good
over
60
days
3%).
work
highlights
potential
MIP-based
sensors
real-time
monitoring
compounds
complex
food
matrices,
such
wine,
offering
robust
cost-effective
alternative
control
applications.
Язык: Английский
Rational designed aqueous emulsion ion imprinted polymers for rare earths with enhanced selectivity
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 160322 - 160322
Опубликована: Фев. 1, 2025
Язык: Английский
Quasi-solid hydrogel electrolyte/nitrogen dot-based electrochemiluminescence sensor for enrofloxacin detection in milk
Food Chemistry,
Год журнала:
2025,
Номер
480, С. 143890 - 143890
Опубликована: Март 15, 2025
Язык: Английский
Preparation of Hybrid Molecularly Imprinted Polymers Based on 3‐Triethoxysilylpropyl Methacrylic Amide for Solid‐Phase Extraction of Gatifloxacin From Lake Water
Journal of Separation Science,
Год журнала:
2025,
Номер
48(3)
Опубликована: Март 1, 2025
ABSTRACT
A
novel
molecularly
imprinted
polymer
(MIP)
against
gatifloxacin
based
on
a
hybrid
monomer
(3‐triethoxysilylpropyl
methacrylic
amide,
APTES‐MAA)
was
reported.
In
this
study,
the
monolith
synthesized
with
as
template,
ethylene
glycol
dimethacrylate
(EGDMA)
cross‐linker,
and
APTES‐MAA
functional
in
mixture
of
acetonitrile
isooctane
porogen
via
an
optimization
density
theory
(DFT).
The
polymers
were
characterized
by
scanning
electron
microscopy,
Fourier
transform
infrared
spectroscopy,
mercury
porosimetry.
resulting
MIPs
(HMIPs)
showed
high
affinity
selectivity
to
template
molecule
factor
16.28
±
0.53,
which
6.1
times
higher
than
that
traditional
acid–based
MIP.
MIP
used
adsorbent
solid‐phase
extraction
lake
water
gatifloxacin.
recovery
96.52
2.69%.
method
exhibits
advantageous
features
cost‐effectiveness
sensitivity,
rendering
it
promising
approach
for
analyzing
organic
pollutants
water.
Язык: Английский
Recent Progress of Molecularly Imprinted Technique for the Detection of Mycotoxins in Food
Yuan Wang,
Dizhe Wei,
Yu Wang
и другие.
Foods,
Год журнала:
2024,
Номер
13(24), С. 4125 - 4125
Опубликована: Дек. 20, 2024
Mycotoxins
are
a
group
of
toxic
metabolites
produced
by
fungi
that
infect
agricultural
products.
Consuming
mycotoxin-contaminated
foods
and
feeds
can
cause
various
adverse
health
effects
in
humans
animals.
Therefore,
developing
rapid
sensitive
analytical
methods
for
detecting
mycotoxins
is
an
urgent
task.
The
molecularly
imprinted
technique
advanced
tool
the
specific
recognition
selective
enrichment
target
molecules.
For
development
detection
mycotoxins,
synthesized
polymers
(MIPs)
serve
as
elements.
By
integrating
MIPs
with
sensing
platforms,
such
solid-phase
extraction,
electrochemical
sensors,
fluorescence
surface-enhanced
Raman
spectroscopy,
surface
plasmonic
resonance
remarkable
progress
has
been
made
foods.
This
review
focuses
on
advances
application
over
past
five
years.
new
MIP
synthesis
categorized
summarized.
Moreover,
future
potential
MIP-based
mycotoxin
also
discussed
highlighted.
Язык: Английский