ACS Applied Nano Materials,
Год журнала:
2024,
Номер
7(8), С. 8914 - 8925
Опубликована: Апрель 10, 2024
The
nickel
phosphides
have
garnered
increasing
attention
as
an
excellent
catalytic
site
in
the
fields
of
electrocatalysis
and
hydrotreating,
but
their
application
organic
synthesis
remains
infrequent.
In
this
study,
ammonium
phosphate
chloride
were
employed
doping
sources
for
first
time
to
synthesize
Ni-based
ZIF-8
precursor
via
host–guest
method.
Subsequently,
was
pyrolyzed
obtain
Ni2P
nanoparticles
(NPs)
supported
on
N,
P
co-doped
carbon.
composite
materials
exhibit
elevated
metal
loading
effective
dispersion
due
synergistic
combination
phosphorus
nickel.
Specifically,
compared
with
Ni-NC,
optimal
Ni2P-NCP-1
exhibits
enhanced
activity
α-alkylation
arylacetonitriles
alcohols
using
KOH
base.
It
shows
a
wide
broad
substrate
scope
at
140
°C
12
h
n-octane
hydrogen
borrowing
strategy.
Through
characterizations
mechanistic
studies,
it
has
been
discovered
that
introduction
source
not
only
provides
more
basic
sites
carbon
matrix
also
leads
formation
NPs,
which
facilitates
efficiency
by
modifying
electronic
structure
Ni.
Compared
metallic
Ni
species,
effect
between
acid-basic
significantly
influences
dehydrogenation
generate
Ni–H
species.
This
study
successfully
achieves
simultaneous
phosphating
both
support,
demonstrates
N2P-NCP-1
catalyst
significant
potential
heterogeneous
transformation
field.
Bulletin of the Chemical Society of Japan,
Год журнала:
2023,
Номер
97(1)
Опубликована: Дек. 1, 2023
Abstract
Nanotechnology
has
revealed
the
science
of
nanoscale.
The
global
challenge
that
will
follow
is
to
build
functional
materials
with
knowledge
nanoscale
phenomena.
This
task
carried
out
by
nanoarchitectonics
as
a
postnanotechnology
concept.
goal
material
systems
architecting
atoms,
molecules,
and
nanomaterials
building
blocks.
Fundamentally,
all
are
made
atoms
molecules.
Therefore,
nanoarchitectonics,
which
architects
from
can
be
universal
way
create
materials.
It
may
said
method
for
everything
in
science.
From
basic
units,
living
cells,
complex
systems,
components
nanoarchitectonics.
paper
presents
recent
examples
research
at
various
size
levels,
atomic
cellular
level,
specifically,
(i)
atomistic
(ii)
molecular
(iii)
supramolecular
(iv)
inorganic
(v)
biomolecular
(vi)
cell-mimic
(vii)
cell-based
possibility
science,
an
integrative
then
explored.
ACS Catalysis,
Год журнала:
2024,
Номер
14(7), С. 4865 - 4926
Опубликована: Март 18, 2024
Rapid
industrialization
and
development
have
led
to
a
tremendous
increase
in
the
use
of
various
types
plastic
commodities
daily
life.
For
past
several
years,
pollution
has
become
global
issue,
posing
serious
threat
mankind.
The
primary
issue
with
increasing
is
lack
proper
management
which
created
huge
havoc
environment.
From
initial
phase
waste
management,
been
discarded,
recycled,
downcycled,
or
dumped
into
landfills
large
proportion,
causing
extreme
damage
ecosystem.
Conventionally,
treated
via
thermal
processes
such
as
pyrolysis
incineration
plants
require
amount
capital
and,
therefore,
harms
aim
circular
economy.
Chemical
upcycling
gaining
attention
high-potential
catalytic
strategy
convert
plastics,
polyethylene
terephthalate,
polyethylene,
polystyrene,
etc.
fuels,
functionalized
polymers,
other
value-added
chemicals
having
direct
impact
on
affordability
viability.
In
this
review,
we
focused
photocatalysis,
electrocatalysis,
photoelectrocatalysis
effective
efficient
technologies.
These
approaches
can
lower
dependence
nonrenewable
resources
are
more
environmentally
friendly
contrast
conventional
approaches.
This
review
elaborately
discusses
pros
cons
provides
detailed
overview
potential
renewable
energy-driven
for
conversion
wastes
valuable
fuels
commodity
chemicals,
along
challenges
future
directions
emerging
approach
treatment.
ACS Catalysis,
Год журнала:
2024,
Номер
14(6), С. 4211 - 4248
Опубликована: Март 5, 2024
Catalytic
transfer
hydrogenation
(CTH)
methodology
has
drawn
profound
attention
of
researchers
as
an
economical
and
environmentally
benign
alternate
to
conventional
method.
Unlike
method,
CTH
exhibits
better
reaction
efficiency
atom
economy,
it
makes
use
simple,
easily
accessible,
low-cost
hydrogen
sources.
Current
research
on
reactions
is
oriented
toward
the
development
non-noble-metal-based
catalysts
due
their
high
abundance
potential
large-scale
applicability.
In
this
Review,
different
organic
transformation
reactions,
such
nitroarenes,
nitriles,
alkenes,
alkynes,
carbonyl
compounds,
hydrogenolysis,
reductive
amination,
formylation
using
sources
have
been
summarized
comprehensively.
addition,
synthesis
strategies
heterogeneous
structure–activity
relationship
involving
metal–support
interaction,
single-atom
catalysis,
synergistic
effect
are
highlighted.
Furthermore,
optimization
parameters─such
temperature,
time,
solvents,
additives─for
enhancing
catalytic
activity
selectivity
product
discussed
in
detail.
This
Review
provides
detailed
insights
into
recent
progress
made
with
a
specific
focus
catalyst
development,
sources,
mechanistic
exploration.
Chemical Communications,
Год журнала:
2024,
Номер
60(16), С. 2152 - 2167
Опубликована: Янв. 1, 2024
In
nanoarchitectonics
approaches,
rational
physical
and
chemical
communications
will
lead
to
the
development
of
more
advanced
functional
materials.
Layer-by-layer
assembly
can
be
a
powerful
tool
for
this
purpose,
as
exemplified
in
feature
paper.
Materials,
Год журнала:
2025,
Номер
18(3), С. 654 - 654
Опубликована: Фев. 1, 2025
The
development
of
functional
materials
and
the
use
nanotechnology
are
ongoing
projects.
These
fields
closely
linked,
but
there
is
a
need
to
combine
them
more
actively.
Nanoarchitectonics,
concept
that
comes
after
nanotechnology,
ready
do
this.
Among
related
research
efforts,
into
creating
through
formation
thin
layers
on
surfaces,
molecular
membranes,
multilayer
structures
these
have
lot
implications.
Layered
especially
important
as
key
part
nanoarchitectonics.
diversity
components
used
in
layer-by-layer
(LbL)
assemblies
notable
feature.
Examples
LbL
introduced
this
review
article
include
quantum
dots,
nanoparticles,
nanocrystals,
nanowires,
nanotubes,
g-C3N4,
graphene
oxide,
MXene,
nanosheets,
zeolites,
nanoporous
materials,
sol–gel
layered
double
hydroxides,
metal–organic
frameworks,
covalent
organic
conducting
polymers,
dyes,
DNAs,
polysaccharides,
nanocelluloses,
peptides,
proteins,
lipid
bilayers,
photosystems,
viruses,
living
cells,
tissues.
examples
assembly
show
how
useful
versatile
it
is.
Finally,
will
consider
future
challenges
Langmuir,
Год журнала:
2023,
Номер
39(36), С. 12865 - 12877
Опубликована: Авг. 28, 2023
The
MoS2-based
reduced
graphene
oxide
aerogel
(MoS2-rGOA)-assisted
organic
transformation
reactions
are
presented.
MoS2-rGOA
is
used
as
a
heterogeneous
catalyst
for
the
reduction
of
benzene
derivatives
such
benzaldehyde,
nitrobenzene,
and
benzonitrile
to
benzyl
alcohol,
aniline,
benzamide
their
derivatives,
respectively,
in
green
solvents
(water/methanol)
reducing
agents
(hydrazine
hydrate
having
N2
H2
byproducts).
mechanistic
features
pathway,
substrate
scope,
best
suitable
conditions
by
varying
temperature,
solvent,
agent,
loading,
time,
etc.
optimized.
All
synthesized
products
obtained
quantitative
yield
with
purity
well
characterized
based
on
nuclear
magnetic
resonance
analysis.
Further,
it
also
observed
that
our
efficiently
recyclable
works
checked
up
5
cycles.
