Advanced Sustainable Systems,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 24, 2025
Abstract
In
recent
years,
metal
phosphide
catalysts
have
garnered
immense
attention
among
the
catalysis
community
due
to
their
facile
synthesis
and
excellent
catalytic
activity
but
promising
potential
in
field
of
organic
transformation
is
not
been
fully
explored.
The
synergistic
coupling
between
support
material
plays
a
crucial
role
enhancing
overall
as
well
recovery
catalyst.
Herein,
this
study
reports
nickel
(Ni
2
P)
graphitic
carbon
nitride
(GCN)
nanosheets
an
interfacial
catalyst
for
effective
efficient
transfer
hydrogenation
quinoline.
significance
developed
interface
Ni
P
GCN
revealed
by
detailed
spectroscopic
theoretical
investigations,
which
enhances
dissociation
hydrogen
source
substrate
interaction
with
surface
catalyst,
thereby
selective
quinoline
1,2,3,4‐tetrahydroquinoline.
proposed
protocol
quinoline,
formic
acid
utilized
bio‐renewable
source,
serves
replacement
molecular
hydrogen.
Further,
optimization
studies
are
carried
out
achieve
good
selectivity
product
yield
varying
reaction
parameters.
Therefore,
using
mechanistic
studies,
supported
on
P‐GCN)
provides
Bulletin of the Chemical Society of Japan,
Journal Year:
2023,
Volume and Issue:
97(1)
Published: Dec. 1, 2023
Abstract
Nanotechnology
has
revealed
the
science
of
nanoscale.
The
global
challenge
that
will
follow
is
to
build
functional
materials
with
knowledge
nanoscale
phenomena.
This
task
carried
out
by
nanoarchitectonics
as
a
postnanotechnology
concept.
goal
material
systems
architecting
atoms,
molecules,
and
nanomaterials
building
blocks.
Fundamentally,
all
are
made
atoms
molecules.
Therefore,
nanoarchitectonics,
which
architects
from
can
be
universal
way
create
materials.
It
may
said
method
for
everything
in
science.
From
basic
units,
living
cells,
complex
systems,
components
nanoarchitectonics.
paper
presents
recent
examples
research
at
various
size
levels,
atomic
cellular
level,
specifically,
(i)
atomistic
(ii)
molecular
(iii)
supramolecular
(iv)
inorganic
(v)
biomolecular
(vi)
cell-mimic
(vii)
cell-based
possibility
science,
an
integrative
then
explored.
ACS Catalysis,
Journal Year:
2024,
Volume and Issue:
14(7), P. 4865 - 4926
Published: March 18, 2024
Rapid
industrialization
and
development
have
led
to
a
tremendous
increase
in
the
use
of
various
types
plastic
commodities
daily
life.
For
past
several
years,
pollution
has
become
global
issue,
posing
serious
threat
mankind.
The
primary
issue
with
increasing
is
lack
proper
management
which
created
huge
havoc
environment.
From
initial
phase
waste
management,
been
discarded,
recycled,
downcycled,
or
dumped
into
landfills
large
proportion,
causing
extreme
damage
ecosystem.
Conventionally,
treated
via
thermal
processes
such
as
pyrolysis
incineration
plants
require
amount
capital
and,
therefore,
harms
aim
circular
economy.
Chemical
upcycling
gaining
attention
high-potential
catalytic
strategy
convert
plastics,
polyethylene
terephthalate,
polyethylene,
polystyrene,
etc.
fuels,
functionalized
polymers,
other
value-added
chemicals
having
direct
impact
on
affordability
viability.
In
this
review,
we
focused
photocatalysis,
electrocatalysis,
photoelectrocatalysis
effective
efficient
technologies.
These
approaches
can
lower
dependence
nonrenewable
resources
are
more
environmentally
friendly
contrast
conventional
approaches.
This
review
elaborately
discusses
pros
cons
provides
detailed
overview
potential
renewable
energy-driven
for
conversion
wastes
valuable
fuels
commodity
chemicals,
along
challenges
future
directions
emerging
approach
treatment.
ACS Catalysis,
Journal Year:
2024,
Volume and Issue:
14(6), P. 4211 - 4248
Published: March 5, 2024
Catalytic
transfer
hydrogenation
(CTH)
methodology
has
drawn
profound
attention
of
researchers
as
an
economical
and
environmentally
benign
alternate
to
conventional
method.
Unlike
method,
CTH
exhibits
better
reaction
efficiency
atom
economy,
it
makes
use
simple,
easily
accessible,
low-cost
hydrogen
sources.
Current
research
on
reactions
is
oriented
toward
the
development
non-noble-metal-based
catalysts
due
their
high
abundance
potential
large-scale
applicability.
In
this
Review,
different
organic
transformation
reactions,
such
nitroarenes,
nitriles,
alkenes,
alkynes,
carbonyl
compounds,
hydrogenolysis,
reductive
amination,
formylation
using
sources
have
been
summarized
comprehensively.
addition,
synthesis
strategies
heterogeneous
structure–activity
relationship
involving
metal–support
interaction,
single-atom
catalysis,
synergistic
effect
are
highlighted.
Furthermore,
optimization
parameters─such
temperature,
time,
solvents,
additives─for
enhancing
catalytic
activity
selectivity
product
discussed
in
detail.
This
Review
provides
detailed
insights
into
recent
progress
made
with
a
specific
focus
catalyst
development,
sources,
mechanistic
exploration.
Chemical Communications,
Journal Year:
2024,
Volume and Issue:
60(16), P. 2152 - 2167
Published: Jan. 1, 2024
In
nanoarchitectonics
approaches,
rational
physical
and
chemical
communications
will
lead
to
the
development
of
more
advanced
functional
materials.
Layer-by-layer
assembly
can
be
a
powerful
tool
for
this
purpose,
as
exemplified
in
feature
paper.
Materials,
Journal Year:
2025,
Volume and Issue:
18(3), P. 654 - 654
Published: Feb. 1, 2025
The
development
of
functional
materials
and
the
use
nanotechnology
are
ongoing
projects.
These
fields
closely
linked,
but
there
is
a
need
to
combine
them
more
actively.
Nanoarchitectonics,
concept
that
comes
after
nanotechnology,
ready
do
this.
Among
related
research
efforts,
into
creating
through
formation
thin
layers
on
surfaces,
molecular
membranes,
multilayer
structures
these
have
lot
implications.
Layered
especially
important
as
key
part
nanoarchitectonics.
diversity
components
used
in
layer-by-layer
(LbL)
assemblies
notable
feature.
Examples
LbL
introduced
this
review
article
include
quantum
dots,
nanoparticles,
nanocrystals,
nanowires,
nanotubes,
g-C3N4,
graphene
oxide,
MXene,
nanosheets,
zeolites,
nanoporous
materials,
sol–gel
layered
double
hydroxides,
metal–organic
frameworks,
covalent
organic
conducting
polymers,
dyes,
DNAs,
polysaccharides,
nanocelluloses,
peptides,
proteins,
lipid
bilayers,
photosystems,
viruses,
living
cells,
tissues.
examples
assembly
show
how
useful
versatile
it
is.
Finally,
will
consider
future
challenges
Langmuir,
Journal Year:
2023,
Volume and Issue:
39(36), P. 12865 - 12877
Published: Aug. 28, 2023
The
MoS2-based
reduced
graphene
oxide
aerogel
(MoS2-rGOA)-assisted
organic
transformation
reactions
are
presented.
MoS2-rGOA
is
used
as
a
heterogeneous
catalyst
for
the
reduction
of
benzene
derivatives
such
benzaldehyde,
nitrobenzene,
and
benzonitrile
to
benzyl
alcohol,
aniline,
benzamide
their
derivatives,
respectively,
in
green
solvents
(water/methanol)
reducing
agents
(hydrazine
hydrate
having
N2
H2
byproducts).
mechanistic
features
pathway,
substrate
scope,
best
suitable
conditions
by
varying
temperature,
solvent,
agent,
loading,
time,
etc.
optimized.
All
synthesized
products
obtained
quantitative
yield
with
purity
well
characterized
based
on
nuclear
magnetic
resonance
analysis.
Further,
it
also
observed
that
our
efficiently
recyclable
works
checked
up
5
cycles.
ACS Applied Materials & Interfaces,
Journal Year:
2023,
Volume and Issue:
15(7), P. 9412 - 9420
Published: Feb. 13, 2023
One
of
the
important
industrial
processes
commonly
employed
in
pharmaceutical,
explosive,
and
plastic
manufacturing
industries
is
ipso-hydroxylation
arylboronic
acids.
In
this
work,
a
straightforward,
metal-free
methodology
for
synthesis
phenols
from
acids
has
been
demonstrated
using
hydroxyl
functionalized
boron
nitride
(BN–OH)
nanosheets.
The
groups
on
BN
nanosheets
act
as
active
sites
hydroxylation
reaction
to
take
place.
detailed
optimization
parameters
was
done
order
attain
high
catalytic
efficiency,
reactions
were
conducted
water,
which
eliminates
use
toxic
solvents.
as-synthesized
catalysts
exhibited
excellent
recyclability
reusability
addition
product
yields
good
turnover
numbers.
green
metrics
also
evaluated
model
examine
sustainable
nature
developed
protocol.
BN–OH
under
base-free
conditions
environmentally
benign
solvents
utmost
desired
can
pave
way
toward
organic
catalysis.
