Recent progress on customizable multi-dimensional carbon-supported metal–organic frameworks (Cx/MOFs) composites for efficient adsorption of gases and vapors

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132203 - 132203

Опубликована: Фев. 1, 2025

Язык: Английский

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Integrating multifactor for methane purification and storage in topological isomorphic tetranuclear cluster-based iron-organic frameworks

Separation and Purification Technology, Год журнала: 2025, Номер 361, С. 131422 - 131422

Опубликована: Янв. 5, 2025

Язык: Английский

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Synergistic Binding Sites in a Robust and Scalable Metal–Organic Framework for Record CH₄ Capture

Small, Год журнала: 2025, Номер unknown

Опубликована: Янв. 12, 2025

Abstract Effectual CH 4 reclamation from /N 2 blends by existing physisorbents in industrialization confronts the adversity of frustrated separation performance, weak structural strength, and restricted scale‐up preparation. To solve aforesaid bottlenecks, herein, a strategy is presented to fabricate synergistic strong recognition binding sites robust scalable optimum Cu(pma) with ultramicroporous feature regarding superb versus N . By virtue contribution multiple affinities accompanied enormous potential field overlap pore restriction, it imparts toward molecules. Equilibrium adsorption bears record KH, (88.2 cm 3 (STP) g −1 bar ), uptake (48.5 stacking density (303.9 L (1.52 mol ) coexisting one highest selectivity (11.5) Q0 st, (29.8 kJ hitherto, authorizing novel benchmark. Thermodynamically driven mechanisms within ‐established synergy forces are deciphered situ PXRD FT‐IR combined theoretical studies. The breakthrough effect dynamic (28.8 cooperation exceptional recyclability easy synthesis scalability under ambient conditions strengthened attractiveness

Язык: Английский

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Pore Space Partition on Sulfonate-rich Metal-Organic Framework for Purification of Methane from Natural Gas

Chemical Communications, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A partitioned acs ( pacs ) MOF structure with abundant N/O interaction sites for one-step CH 4 purification from /C 2 H 6 3 8 ternary mixtures.

Язык: Английский

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