Integrating multifactor for methane purification and storage in topological isomorphic tetranuclear cluster-based iron-organic frameworks

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: 361, P. 131422 - 131422

Published: Jan. 5, 2025

Language: Английский

Synergistic Binding Sites in a Robust and Scalable Metal–Organic Framework for Record CH₄ Capture

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 12, 2025

Abstract Effectual CH 4 reclamation from /N 2 blends by existing physisorbents in industrialization confronts the adversity of frustrated separation performance, weak structural strength, and restricted scale‐up preparation. To solve aforesaid bottlenecks, herein, a strategy is presented to fabricate synergistic strong recognition binding sites robust scalable optimum Cu(pma) with ultramicroporous feature regarding superb versus N . By virtue contribution multiple affinities accompanied enormous potential field overlap pore restriction, it imparts toward molecules. Equilibrium adsorption bears record KH, (88.2 cm 3 (STP) g −1 bar ), uptake (48.5 stacking density (303.9 L (1.52 mol ) coexisting one highest selectivity (11.5) Q0 st, (29.8 kJ hitherto, authorizing novel benchmark. Thermodynamically driven mechanisms within ‐established synergy forces are deciphered situ PXRD FT‐IR combined theoretical studies. The breakthrough effect dynamic (28.8 cooperation exceptional recyclability easy synthesis scalability under ambient conditions strengthened attractiveness

Language: Английский

Recent progress on customizable multi-dimensional carbon-supported metal–organic frameworks (Cx/MOFs) composites for efficient adsorption of gases and vapors

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132203 - 132203

Published: Feb. 1, 2025

Language: Английский