Lattice Charge Tuning-Driven Multi-Carbon Products from Carbon Dioxide DOI

Geetansh Chawla,

Saurav Ch. Sarma, Jithu Raj

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер 12(26), С. 9787 - 9794

Опубликована: Июнь 19, 2024

Mitigating global CO2 concentrations from anthropogenic sources through electrochemical conversion to value-added chemicals is the need of hour. In this work, fundamental concept "Lattice Charge" has been strategically manipulated in materials selectively produce multi-carbon products greenhouse gas. To achieve this, a series catalysts within well-known ABX2 family (A = Ag, Cu; B In, Ga, Fe; X S, Se) have explored, which exhibit significant activity toward reduction reaction (eCO2RR) and results formation higher carbon including C3 products, acetone, energy-dense isopropanol (FE 24.5 ± 2.5%). The Hirshfeld charge analysis technique highlighted structure–activity correlation importance optimized lattice distribution as crucial tool manipulate eCO2RR product electrocatalyst designs, real-time situ ATR-FTIR probes intermediate species adsorbed during process.

Язык: Английский

Recent Progress in Using Covalent Organic Frameworks to Stabilize Metal Anodes for Highly‐Efficient Rechargeable Batteries DOI Creative Commons
Jianlu Sun, Fangyuan Kang,

Dongbo Yan

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(28)

Опубликована: Май 7, 2024

Alkali metals (e.g. Li, Na, and K) multivalent Zn, Mg, Ca, Al) have become star anodes for developing high-energy-density rechargeable batteries due to their high theoretical capacity excellent conductivity. However, the inevitable dendrites unstable interfaces of metal pose challenges safety stability batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, been widely investigated regular porous structure, flexible molecular design, specific surface area. In this minireview, we summarize research progress COFs in stabilizing anodes. First, present origins delve into advantages based on physical/chemical properties alkali metals. Then, special attention has paid application host design anodes, artificial solid electrolyte interfaces, additives, solid-state electrolytes, separator modifications. Finally, a new perspective is provided from pore modulation, synthesis COFs.

Язык: Английский

Процитировано

41
Covalent Organic Frameworks for Photocatalytic Reduction of Carbon Dioxide: A Review DOI
Jinglun Yang, Zihao Chen, Lei Zhang

и другие.

ACS Nano, Год журнала: 2024, Номер 18(33), С. 21804 - 21835

Опубликована: Авг. 8, 2024

Covalent organic frameworks (COFs) are crystalline networks with extended backbones cross-linked by covalent bonds. Due to the semiconductive properties and variable metal coordinating sites, along rapid development in linkage chemistry, utilization of COFs photocatalytic CO2RR has attracted many scientists' interests. In this Review, we summarize latest research progress on for CO2 reduction. first part, present COF linkages that have been used CO2RR, discuss four mechanisms including as intrinsic photocatalysts, photosensitive motifs metalated semiconductors heterojunction photocatalysts. Then, principles structural designs functional building units stacking mode exchange. Finally, outlook challenges provided. This Review is intended give some guidance design synthesis diverse different linkages, various structures, divergent modes efficient photoreduction CO2.

Язык: Английский

Процитировано

34
Constructing an Asymmetric Covalent Triazine Framework to Boost the Efficiency and Selectivity of Visible‐Light‐Driven CO2 Photoreduction DOI Creative Commons

Guang‐Dong Qi,

Dan Ba,

Yujie Zhang

и другие.

Advanced Science, Год журнала: 2024, Номер 11(28)

Опубликована: Май 13, 2024

The photocatalytic reduction of CO

Язык: Английский

Процитировано

26
Enigma of Sustainable CO2 Conversion to Renewable Fuels and Chemicals Through Photocatalysis, Electrocatalysis, and Photoelectrocatalysis: Design Strategies and Atomic Level Insights DOI Open Access

Diksha Suri,

Srimanta Das,

Shivani Choudhary

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Янв. 2, 2025

Growing global population, escalating energy consumption, and climate change threaten future security. Fossil fuel combustion, primarily coal, oil, natural gas, exacerbates the greenhouse effect driving warming through CO

Язык: Английский

Процитировано

6
Strongly Coupled Interface in Electrostatic Self-Assembly Covalent Triazine Framework/Bi19S27Br3 for High-Efficiency CO2 Photoreduction DOI
Jiajing Zhang, Mei Zheng, Yao Wu

и другие.

ACS Nano, Год журнала: 2025, Номер unknown

Опубликована: Янв. 7, 2025

Constructing a strong bonded interface is highly desired to build fast charge-transfer channels and tune reactive sites for optimizing CO2 photoreduction. In this work, covalent triazine framework (CTF) combined with Bi19S27Br3 heterojunction designed using an electrostatic self-assembly process. Due the oppositely charged states between two components ultrasonic treatment, coupled realized formation of Bi–C/N/O bonds, leading robust interfacial polarization. This feature causes charge redistribution, intensifies interaction N CO2, stabilizes intermediate state, lowers reaction energy barrier. Meanwhile, chemically favors rapid electron migration from CTF, as proved by ultrafast transient absorption spectroscopy in situ irradiation XPS. As result, CTF/Bi19S27Br3 delivers superior photoreduction performance yield CO (572.2 μmol g–1 h–1) pure water system, which 38.6 times that Bi19S27Br3, apparent quantum yields up 7.9 6.2% at 380 400 nm, respectively. coupling strategy provides accessible pathway designing polarized, high-efficiency photocatalysts.

Язык: Английский

Процитировано

5
Construction on ferrocene-derived imidazole ionic polymers for carbon dioxide cycloaddition and iodine capture DOI
Jiaojiao Zhao, Xiuli Yan,

Xuanbo Liu

и другие.

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 115695 - 115695

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

3
Recent Progress in Using Covalent Organic Frameworks to Stabilize Metal Anodes for Highly‐Efficient Rechargeable Batteries DOI Creative Commons
Jianlu Sun, Fangyuan Kang,

Dongbo Yan

и другие.

Angewandte Chemie, Год журнала: 2024, Номер 136(28)

Опубликована: Май 7, 2024

Abstract Alkali metals (e.g. Li, Na, and K) multivalent Zn, Mg, Ca, Al) have become star anodes for developing high‐energy‐density rechargeable batteries due to their high theoretical capacity excellent conductivity. However, the inevitable dendrites unstable interfaces of metal pose challenges safety stability batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, been widely investigated regular porous structure, flexible molecular design, specific surface area. In this minireview, we summarize research progress COFs in stabilizing anodes. First, present origins delve into advantages based on physical/chemical properties alkali metals. Then, special attention has paid application host design anodes, artificial solid electrolyte interfaces, additives, solid‐state electrolytes, separator modifications. Finally, a new perspective is provided from pore modulation, synthesis COFs.

Язык: Английский

Процитировано

10
Designed Synthesis of Imine-Linked 2D Covalent Organic Frameworks with Enhanced Stability and Functionality DOI
Ting Chen,

W. Y. Jiao,

Wei-De Zhu

и другие.

Chemistry of Materials, Год журнала: 2024, Номер 36(15), С. 7362 - 7369

Опубликована: Июль 26, 2024

Covalent organic frameworks (COFs) linked by imine bonds have attracted significant attention, primarily due to the accessibility of monomers and facile synthesis highly crystalline materials. However, reversible nature raises stability concerns for these materials in practical applications. Therefore, there is a pressing need development imine-linked COFs that can combine high crystallinity, good stability, functionality. Here, adopting two-in-one molecular design strategy, we designed an building block containing both acetal amino connecting groups, featuring pyridine functional site, with side chains consisting alkoxyl groups. Following synthesis, elements were combined confined channel (0.85 nm), leading two-dimensional (2D) (COF-LIFM4 COF-LIFM5) crystallinity strong acid base conditions. Moreover, COF-LIFM5 exhibited favorable CO2 affinity appropriate hydrophobicity, making it promising modifier improving mass transfer reduction reaction (CO2RR). As result, Cu/COF-LIFM5 showcased enhanced C2+ product selectivity CO2RR, Faradaic efficiency exceeding 80% at current density 500 mA cm–2 flow cell.

Язык: Английский

Процитировано

10
Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction DOI Creative Commons
Chao Li,

Hong Yan,

Hanlu Yang

и другие.

Science China Materials, Год журнала: 2024, Номер 68(1), С. 21 - 38

Опубликована: Ноя. 8, 2024

Abstract The conversion of carbon dioxide (CO 2 ) to the reduced chemical compounds offers substantial environmental benefits through minimizing emission greenhouse gas and fostering sustainable practices. Recently, unique properties metal-organic frameworks (MOFs) make them attractive candidates for electrocatalytic CO reduction reaction RR), providing many opportunities develop efficient, selective, environmentally processes mitigating emissions utilizing as a valuable raw material synthesis fuels chemicals. Here, recent advances in MOFs efficient catalysts RR are summarized. detailed characteristics, mechanisms, practical approaches improving efficiency, selectivity, durability under realistic conditions also clarified. Furthermore, outlooks on prospects MOF-based electrocatalysts provided.

Язык: Английский

Процитировано

8
A Covalent Organic Nanoribbon: Preparation, Single‐Crystal Structure with Chinese Luban Lock Configuration, and Photocatalytic Behavior DOI Creative Commons
Lei Zhang, Zihao Chen,

Xiao‐Xin Li

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Июнь 27, 2024

Abstract The multiple mortise‐and‐tenon joint parts are the core factors to provide structural stability and diversity of Chinese Luban locks; however, constructing such structures is very challenging. Herein, single crystals a covalent organic nanoribbon (named CityU‐27 ) prepared through assembly hexahydroxytriphenylene (HHTP), 4,4′‐vinylenedipyridine (BYE), phenylboronic acid (BA) together dative boron←nitrogen (B←N) bonds. single‐crystal X‐ray diffraction analysis indicates that has structure, where each forms tight π–π interactions with four neighboring others generate lock‐like configuration. been demonstrated be an efficient photocatalyst in one‐pot tandem reaction hydrogen evolution (HER) semi‐hydrogenation alkynes series produce olefins without any additional photosensitizers co‐catalysts (metal‐free).

Язык: Английский

Процитировано

7