Supramolecular Systems Chemistry Based on the Interplay between Peptides and Porphyrins DOI
Yue Fu, Lian Zhang, Xuehai Yan

и другие.

ChemSystemsChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 23, 2024

Abstract The functions of living organisms are emergent from networks biomolecules. In this review, we discuss the creation synthetic life‐like systems based on interplay peptides and porphyrins in supramolecular chemical systems. particular, focus spatiotemporal control self‐assembly processes, which allows for development hierarchical structures biomimetic catalysis adaptive dynamics stimulus‐responsive structural transformations. Notably, when operating a nonequilibrium regime–characterized by kinetic traps, feedback loops, dissipative conditions–the landscape expands system‐level properties emerge, including transient catalysis, metabolic self‐replication, Darwinian‐like evolution. Controlling these at biointerface would facilitate intelligent therapeutic interventions anti‐tumor phototherapy. Supramolecular chemistry provides valuable framework exploring new physicochemical spaces porphyrins, may offer distinct advantages extensive applications across diverse fields.

Язык: Английский

Programmed Fabrication of Vesicle‐Based Prototissue Fibers with Modular Functionalities DOI Creative Commons
Tomoya Kojima, Kouichi Asakura, Pierangelo Gobbo

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Фев. 10, 2025

Abstract Multicellular organisms have hierarchical structures where multiple cells collectively form tissues with complex 3D architectures and exhibit higher‐order functions. Inspired by this, to date, protocell models been assembled tissue‐like termed prototissues. Despite recent advances in this research area, the programmed assembly of protocells into prototissue fibers emergent functions still represents a significant challenge. The possibility assembling will open up way novel type subunit capable unprecedented soft functional materials tunable architectures, modular distributed functionalities. Herein, first method fabricate freestanding vesicle‐based controlled lengths diameters is devised. Importantly, it also shown that can be composed different specialized modules that, for example, endow fiber magnetotaxis capabilities, or work synergistically take an input diffusible chemical signals transduce readable fluorescent output through hosted enzyme cascade reaction. Overall, addresses important challenge engineering find applications bio‐printing, tissue engineering, robotics as next‐generation bioinspired materials.

Язык: Английский

Процитировано

0

Engineering Protocell Networks for Prototissue Development DOI

Zhetong Liu,

Lei Liu, R. Stephanie Huang

и другие.

Advanced Healthcare Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 3, 2025

The assembly of protocells into prototissues represents a significant step forward in mimicking the hierarchical structure and complex functions biological tissues. This review explores construction various protocell models, including lipid vesicles, polymer proteinosomes, membraneless coacervates, emulsion droplets. It examines range chemical physical methods employed to spatially organize these structured, functional prototissues. Furthermore, highlights distinctive properties prototissues, such as their ability facilitate intra- inter-protocell communication, exhibit collective behaviors like oscillations deformation, promising applications biomedicine. By bridging gap between synthetic cells tissue-like systems, this provides insights design, fabrication, potential biology regenerative medicine.

Язык: Английский

Процитировано

0

Matching Together Living Cells and Prototissues: Will There Be Chemistry? DOI Creative Commons
Stefano Valente, Agostino Galanti, Edoardo Maghin

и другие.

ChemBioChem, Год журнала: 2024, Номер 25(18)

Опубликована: Июнь 21, 2024

Abstract Scientific advancements in bottom‐up synthetic biology have led to the development of numerous models cells, or protocells. To date, research has mainly focused on increasing (bio)chemical complexity these bioinspired micro‐compartmentalized systems, yet successful integration protocells with living cells remains one major challenges biology. In this review, we aim summarize current state art hybrid protocell/living cell and prototissue/living systems. Inspired by recent breakthroughs tissue engineering, review chemical, bio‐chemical, mechano‐chemical aspects that hold promise for achieving an effective non‐living matter. The future production fully integrated systems increasingly complex not only potential revolutionize field but also paves way new technologies (bio)sensing, personalized therapy, drug delivery.

Язык: Английский

Процитировано

1

Supramolecular Systems Chemistry Based on the Interplay between Peptides and Porphyrins DOI
Yue Fu, Lian Zhang, Xuehai Yan

и другие.

ChemSystemsChem, Год журнала: 2024, Номер unknown

Опубликована: Окт. 23, 2024

Abstract The functions of living organisms are emergent from networks biomolecules. In this review, we discuss the creation synthetic life‐like systems based on interplay peptides and porphyrins in supramolecular chemical systems. particular, focus spatiotemporal control self‐assembly processes, which allows for development hierarchical structures biomimetic catalysis adaptive dynamics stimulus‐responsive structural transformations. Notably, when operating a nonequilibrium regime–characterized by kinetic traps, feedback loops, dissipative conditions–the landscape expands system‐level properties emerge, including transient catalysis, metabolic self‐replication, Darwinian‐like evolution. Controlling these at biointerface would facilitate intelligent therapeutic interventions anti‐tumor phototherapy. Supramolecular chemistry provides valuable framework exploring new physicochemical spaces porphyrins, may offer distinct advantages extensive applications across diverse fields.

Язык: Английский

Процитировано

1