Analytical Letters,
Год журнала:
2024,
Номер
unknown, С. 1 - 16
Опубликована: Июнь 21, 2024
Synchronous
molecular
fluorescence
with
multivariate
calibration
was
investigated
to
assay
seven
polycyclic
aromatic
hydrocarbons
(PAHs)
and
three
oxygenated
derivatives
(O-PAHs)
in
printer
toner.
Great
sensitivity
a
good
data
compression
capacity
were
achieved;
therefore,
relatively
small
number
of
factors
used.
Correlation
coefficients
above
0.95
for
the
functions
obtained,
recoveries
lie
between
70
130%
analyzing
synthetic
samples
(13
PCs).
For
real
assayed,
81
125%
obtained
when
compared
results
by
gas
chromatography
–
tandem
mass
spectrometry
(GC-MS/MS).
Despite
certain
loss
accuracy
chromatography,
proposed
methodology
is
faster,
simpler,
lower
cost.
The
tool
proved
be
an
expeditious
alternative
screening
toner
relation
presence
abundance
PAHs
derivatives.
Environment International,
Год журнала:
2023,
Номер
177, С. 107991 - 107991
Опубликована: Май 23, 2023
There
is
ample
evidence
from
occupational
studies
that
exposure
to
a
mixture
of
Polycyclic
Aromatic
Hydrocarbons
(PAHs)
causally
associated
with
an
increased
incidence
lung
cancers.
In
both
atmospheres
and
ambient
air,
PAHs
are
present
as
many
compounds,
but
the
composition
in
air
differs
atmosphere,
varies
time
space
air.
Estimates
cancer
risk
for
PAH
mixtures
based
upon
unit
risks
which
derive
extrapolation
data
or
animal
model
data,
case
WHO
use
one
compound,
benzo[a]pyrene
marker
entire
mixture,
irrespective
composition.
The
U.S.
EPA
has
used
study
inhalation
alone,
there
have
been
number
rankings
relative
carcinogenic
potency
other
calculate
frequently
incorrectly
by
adding
estimated
individual
applying
total
"B[a]P
equivalent"
risk,
already
applies
mixture.
Such
often
solely
historic
US
group
16
compounds
do
not
include
apparently
more
potent
carcinogens.
no
human
PAHs,
conflicting
additivity
carcinogenicity
mixtures.
This
paper
finds
large
divergences
between
estimates
deriving
methods,
well
considerable
sensitivity
composition,
assumed
potencies.
Of
two
approach
appears
likely
provide
reliable
estimates,
recently
proposed
mixture-based
approaches
using
vitro
toxicity
may
offer
some
advantages.
Chemosensors,
Год журнала:
2023,
Номер
11(1), С. 35 - 35
Опубликована: Янв. 2, 2023
The
increase
of
production
and
consumption
persistently
introduce
different
pollutants
into
the
environment.
constant
development
improvement
analytical
methods
for
tracking
environmental
contaminants
are
essential.
demand
high
sample
throughput
analysis
has
hit
spotlight
developing
selective
sensors
to
avoid
time-consuming
preparation
techniques.
In
addition,
sensor’s
sensitivity
should
satisfy
rigorous
demands
harmful
compound
tracking.
Molecularly
imprinted
plasmonic-based
excellent
candidates
overcome
selectivity
issues.
polymers
robust,
stable
in
aqueous
organic
solvents,
at
extreme
pHs
temperatures,
include
a
low-cost
synthesis
procedure.
Combined
with
techniques,
they
perspective
choice
applications
field
protection.
Plasmonic-based
offer
lower
limit
detection,
broad
linearity
range,
sensitivity,
compared
other
detection
This
review
outlines
optical
plasmonic
molecularly
as
sensing
elements.
main
focus
is
on
affecting
human
animal
health,
such
pesticides,
pharmaceuticals,
hormones,
microorganisms,
polycyclic
aromatic
hydrocarbons,
dyes,
metal
particles.
Although
currently
have
their
application
mostly
biomedical
field,
we
eager
point
them
out
highly
prospective
solution
many
problems.
Applied Sciences,
Год журнала:
2023,
Номер
13(13), С. 7877 - 7877
Опубликована: Июль 5, 2023
The
chemical
group
comprising
polycyclic
aromatic
hydrocarbons
(PAHs)
has
received
prolonged
evaluation
and
scrutiny
in
the
past
several
decades.
PAHs
are
ubiquitous
carcinogenic
pollutants
pose
a
significant
threat
to
human
health
through
their
environmental
prevalence
distribution.
Regardless
of
origin,
natural
or
anthropogenic,
generally
stem
from
incomplete
combustion
organic
materials.
Dietary
intake,
one
main
routes
exposure
PAHs,
is
modulated
by
pre-existing
food
contamination
(air,
water,
soil)
formation
accumulation
during
processing.
To
this
end,
processing
techniques
cooking
options
entailing
thermal
treatment
carry
additional
weight
determining
PAH
levels
final
product.
With
background
provided,
study
aims
provide
an
improved
understanding
occurrence
meat,
edible
oils,
cereal
products.
factors
influencing
formation,
including
operational
conditions
parameters,
product
composition,
storage
settings,
described.
discussion
also
addresses
reduction
directions
with
respect
informing
choice
employed
technique,
fuel
type,
time–temperature
ingredient
variations.
Considering
disparities
caused
wide
variations
contamination,
challenges
associated
control
requirements
outlined
context
relevant
preventive
approaches
Environmental Research,
Год журнала:
2024,
Номер
249, С. 118394 - 118394
Опубликована: Фев. 1, 2024
Polycyclic
Aromatic
Hydrocarbons
(PAHs)
represent
persistent
environmental
pollutants
ubiquitously
distributed
in
the
environment.
Their
presence
alongside
various
other
contaminants
gives
rise
to
intricate
interactions,
culminating
profound
deleterious
consequences.
The
combination
effects
of
different
PAH
mixtures
on
biota
remains
a
relatively
unexplored
domain.
Recent
studies
have
harnessed
exceptional
sensitivity
metabolomic
techniques
unveil
significant
ecotoxicological
perils
pollution
confronting
both
human
populations
and
ecosystems.
This
article
furnishes
comprehensive
overview
current
literature
focused
metabolic
repercussions
stemming
from
exposure
complex
PAHs
or
PAH-pollution
sources
using
metabolomics
approaches.
These
insights
are
obtained
through
wide
range
models,
including
vitro
assessments,
animal
studies,
investigations
subjects,
botanical
specimens,
soil
environments.
findings
underscore
that
induce
cellular
stress
responses
systemic
effects,
leading
dysregulations
amino
acids,
carbohydrates,
lipids,
key
metabolites
(e.g.,
organic
purines),
with
specific
variations
observed
based
organism
compounds
involved.
Additionally,
ecological
consequences
plant
microbial
emphasized,
revealing
changes
stress-related
nutrient
cycling
interplay
their
several
as
elucidated
metabolomics,
highlight
urgency
further
research
need
for
strategies
mitigate
risks
posed
by
these
widespread
pollutants.
Journal of Hazardous Materials,
Год журнала:
2022,
Номер
440, С. 129795 - 129795
Опубликована: Авг. 18, 2022
Biochar
applied
into
the
soil
is
recommended
as
an
effective
tool
for
increasing
its
properties
and
crop
productivity.
However,
biochar
can
contain
some
potentially
toxic
compounds
such
polycyclic
aromatic
hydrocarbons
(PAHs).
Moreover,
during
production
or
environmental
application
(e.g.
fertilizer),
more
PAHs
derivatives
containing
nitrogen,
oxygen
sulfur
be
formed.
There
a
lack
of
information
on
how
factors
affect
bioavailability
long-term
BC
soil.
In
presented
studies
effects
physical
(freeze-thaw
cycles)
chemical
aging
(temperatures
60
°C
90
°C)
total
bioavailable
content
their
were
estimated.
The
results
indicate
that
(6
months)
affected
physicochemical
characteristic
biochars
promoting
formation
new
C
O-containing
species
surface
polarity
hydrophilicity.
Physical
promoted
with
higher
molecular
weight
significant
(up
to
550
%)
increase
in
derivatives.
this
study
highlight
importance
fraction
evaluation
toxicity
aged
biochar.
Journal of Hazardous Materials,
Год журнала:
2024,
Номер
473, С. 134605 - 134605
Опубликована: Май 14, 2024
Polycyclic
aromatic
compounds
(PACs),
including
polycyclic
hydrocarbons
(PAHs)
and
heteroatom-containing
analogues,
constitute
an
important
environmental
contaminant
class.
For
decades,
limited
numbers
of
priority
PAHs
have
been
routinely
targeted
in
pollution
investigations,
however,
there
is
growing
awareness
for
the
potential
occurrence
thousands
PACs
environment.
In
this
study,
untargeted
Fourier
transform
ion
cyclotron
resonance
mass
spectrometry
was
used
molecular
characterisation
a
sediment
core
from
Chiswick
Ait,
River
Thames,
London,
UK.
Using
complex
mixture
analysis
approaches,
aromaticity
index
calculations,
number
PAC
components
determined
eight
depths,
extending
back
to
1930s.
A
maximum
1676
compositions
representing
detected
at
depth
corresponding
1950s,
decline
observed
up
core.
case
linking
London's
coal
consumption
history
presented,
alongside
other
possible
sources,
with
some
data
features
indicating
pyrogenic
origins.
The
overall
profile
trend
components,
oxygen,
sulfur,
nitrogen,
chlorine
atoms,
shown
broadly
correspond
16
PAH
concentration
previously
These
findings
implications
industry-impacted
environments.
Cogent Engineering,
Год журнала:
2023,
Номер
10(1)
Опубликована: Апрель 9, 2023
Atmospheric
polycyclic
aromatic
hydrocarbons
(PAHs)
are
associated
with
adverse
health
effects
in
exposed
populations.
Understanding
PAH
pollution
ambient
air
and
its
impacts
is
essential
for
developing
effective
actions
combating
pollution.
This
review
paper
summarised
discussed
the
findings
of
research
work
that
determined
concentrations,
distribution
sequence,
risk
exposure
levels
atmospheric
PAHs
cities
worldwide.
It
also
gave
an
overview
sources
methodology
appraising
to
PAHs.
Eighty-five
articles
published
peer-reviewed
journals
from
2010
2023
were
identified
academic
databases,
55
reporting
on
PAHs,
while
30
evaluated
air.
The
narrative
approach
was
employed
critically
analyse
produce
descriptive
summaries
patterns
a
tabular
form.
showed
total
concentration
urban
areas
about
eight
times
greater
than
rural
environments
emanated
diverse
sources.
However,
vehicle
exhaust
industrial
emissions
primary
sequence
particulate
gas
phases
HMW>MMW>LMW
LMW>MMW>HMW
respectively.
Chronic
environment
increased
asthma,
cardiovascular
disease,
lung
cancer.
Adoption
stricter
emission
standards,
cleaner
energy
sources,
more
efficient
technology
will
aid
reduction
negative
consequences
areas.