Journal of Energy Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Окт. 1, 2024
Язык: Английский
Journal of Energy Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Окт. 1, 2024
Язык: Английский
Chemical Science, Год журнала: 2024, Номер 15(36), С. 14585 - 14607
Опубликована: Янв. 1, 2024
The development of high-efficiency atomic-level catalysts for energy-conversion and -storage technologies is crucial to address energy shortages. spin states diatomic (DACs) are closely tied their catalytic activity. Adjusting the DACs' active centers can directly modify occupancy d-orbitals, thereby influencing bonding strength between metal sites intermediates as well transfer during electro reactions. Herein, we discuss various techniques characterizing atomic strategies modulating center states. Next, outline recent progress in study effects DACs oxygen reduction reaction (ORR), evolution (OER), hydrogen (HER), electrocatalytic nitrogen/nitrate (eNRR/NO
Язык: Английский
Процитировано
29Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 157207 - 157207
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
18Coordination Chemistry Reviews, Год журнала: 2025, Номер 532, С. 216545 - 216545
Опубликована: Фев. 19, 2025
Язык: Английский
Процитировано
10Angewandte Chemie International Edition, Год журнала: 2023, Номер 63(6)
Опубликована: Дек. 16, 2023
Addressing the limitations arising from consistent catalytic behavior observed for various intermediates during electrochemical carbon dioxide reduction reaction (CO
Язык: Английский
Процитировано
42Coordination Chemistry Reviews, Год журнала: 2024, Номер 516, С. 215961 - 215961
Опубликована: Май 29, 2024
Язык: Английский
Процитировано
14Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 356, С. 124255 - 124255
Опубликована: Май 31, 2024
Язык: Английский
Процитировано
12Journal of Colloid and Interface Science, Год журнала: 2024, Номер 678, С. 913 - 923
Опубликована: Сен. 23, 2024
Язык: Английский
Процитировано
10Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159210 - 159210
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
2Chemical Research in Chinese Universities, Год журнала: 2025, Номер unknown
Опубликована: Янв. 7, 2025
Язык: Английский
Процитировано
1Small, Год журнала: 2025, Номер unknown
Опубликована: Янв. 31, 2025
Diatomic catalysts are promising for the electrochemical CO2 reduction reaction (CO2RR) due to their maximum atom utilization and presence of multiple active sites. However, atomic-scale design diatomic elucidation synergistic catalytic mechanisms between centers remain challenging. In this study, heteronuclear Fe─In sites anchored on nitrogen-doped carbon (FeIn DA/NC) constructed. The FeIn DA/NC electrocatalyst achieves a CO Faradaic efficiency exceeding 90% across wide range applied potentials from -0.4 -0.7 V, with peak 99.1% at -0.5 V versus reversible hydrogen electrode. situ, attenuated total reflection surface-enhanced infrared absorption spectroscopy density functional theory calculations reveal that interaction Fe induce an asymmetric charge distribution, which promote adsorption site lowered energy barrier formation *COOH. Moreover, unique structure increase *OH through bridging interaction, decrease water dissociation further promoted CO2RR activity.
Язык: Английский
Процитировано
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