A universal route to graft highly dispersed Cobalt Phthalocyanine on porous carbon for efficient CO2 Electroreduction DOI

Shide Wu,

Mengjin Gao,

Dan Ping

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A promising catalyst for dispersing CoPc on three-dimensional porous carbon was prepared and showed impressive performance CO 2 electroreduction to CO.

Language: Английский

Spin effect in dual-atom catalysts for electrocatalysis DOI Creative Commons

Xiaoqin Xu,

Jingqi Guan

Chemical Science, Journal Year: 2024, Volume and Issue: 15(36), P. 14585 - 14607

Published: Jan. 1, 2024

The development of high-efficiency atomic-level catalysts for energy-conversion and -storage technologies is crucial to address energy shortages. spin states diatomic (DACs) are closely tied their catalytic activity. Adjusting the DACs' active centers can directly modify occupancy d-orbitals, thereby influencing bonding strength between metal sites intermediates as well transfer during electro reactions. Herein, we discuss various techniques characterizing atomic strategies modulating center states. Next, outline recent progress in study effects DACs oxygen reduction reaction (ORR), evolution (OER), hydrogen (HER), electrocatalytic nitrogen/nitrate (eNRR/NO

Language: Английский

Citations

27
Hydrophobic carbon quantum dots with Lewis-Basic nitrogen sites for electrocatalyst CO2 reduction to CH4 DOI
Shuai Fu, Bijun Tang, Zeming Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157207 - 157207

Published: Oct. 1, 2024

Language: Английский

Citations

18
Recent advances and challenges of double-atom catalysts in diverse environmental applications: A state-of-the-art review DOI
Tong Hu, Wenjun Zhou,

Wangwang Tang

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216545 - 216545

Published: Feb. 19, 2025

Language: Английский

Citations

2
Boosting Electrocatalytic Carbon Dioxide Reduction via Self‐Relaxation of Asymmetric Coordination in Fe‐Based Single Atom Catalyst DOI

Zhaoyong Jin,

Dongxu Jiao,

Yilong Dong

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(6)

Published: Dec. 16, 2023

Addressing the limitations arising from consistent catalytic behavior observed for various intermediates during electrochemical carbon dioxide reduction reaction (CO

Language: Английский

Citations

40
Do we achieve “1 + 1 > 2” in dual-atom or dual-single-atom catalysts? DOI
Xue Yang,

Linyao Xu,

Yuxin Li

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 516, P. 215961 - 215961

Published: May 29, 2024

Language: Английский

Citations

10
Modulation of charge structure in Bi/Bi2O3-In2O3@C for efficient CO2 electroreduction to formate DOI
Zhongbao Feng,

Yumo Fu,

Ziyuan Yang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 913 - 923

Published: Sept. 23, 2024

Language: Английский

Citations

10
Atomically integration of O-bridged Co-Fe hetero-pairs as tandem photocatalyst towards highly efficient hydroxyl radicals production DOI

Yali Luo,

Yang Deng, Pengfei Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 356, P. 124255 - 124255

Published: May 31, 2024

Language: Английский

Citations

9
Recent progress in Cu-based electrocatalysts for CO2 reduction DOI

R. Q. Xiong,

Huimin Xu, Hong-Rui Zhu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159210 - 159210

Published: Jan. 1, 2025

Language: Английский

Citations

1
From Single-atom to Bi-atom and Ordered Multi-atom: Not Just a Number Changing for Electrocatalysis DOI
Wenting Lu, Xiao Zhao

Chemical Research in Chinese Universities, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Language: Английский

Citations

1
Synergistic Catalysis in Fe─In Diatomic Sites Anchored on Nitrogen‐Doped Carbon for Enhanced CO2 Electroreduction DOI Open Access
Dapeng Meng, Jingxuan Zheng, Junxin Guo

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 31, 2025

Diatomic catalysts are promising for the electrochemical CO2 reduction reaction (CO2RR) due to their maximum atom utilization and presence of multiple active sites. However, atomic-scale design diatomic elucidation synergistic catalytic mechanisms between centers remain challenging. In this study, heteronuclear Fe─In sites anchored on nitrogen-doped carbon (FeIn DA/NC) constructed. The FeIn DA/NC electrocatalyst achieves a CO Faradaic efficiency exceeding 90% across wide range applied potentials from -0.4 -0.7 V, with peak 99.1% at -0.5 V versus reversible hydrogen electrode. situ, attenuated total reflection surface-enhanced infrared absorption spectroscopy density functional theory calculations reveal that interaction Fe induce an asymmetric charge distribution, which promote adsorption site lowered energy barrier formation *COOH. Moreover, unique structure increase *OH through bridging interaction, decrease water dissociation further promoted CO2RR activity.

Language: Английский

Citations

1