Prodrug Self‐Assemblies Based on Plant Volatile Aldehydes with Improved Stability and Antimicrobial Activity Against Plant Pathogens DOI Open Access

Gaohua Hu,

Zhiyuan Zhou, Gang Tang

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Plant volatile aldehydes (PVAs) such as cinnamaldehyde (Cin), citral (Cit), citronellal (Citr), and perillaldehyde (Per) have broad-spectrum antimicrobial activity show great potential in agricultural sustainable production. However, most PVAs not only very high volatility but also are easily degradable environment, which seriously restricts their wide application. To address the inherent problems with PVAs, four prodrugs based on fabricated by conjugating individually Cin, Cit, Citr, Per to sodium bisulfite (Sod) through a simple addition reaction subsequently self-assembled into nanoparticles (prodrug self-assemblies) aqueous solutions. The results showed that pH of 7 temperature 35 °C optimal conditions for formation prodrug self-assemblies highest self-assembly rates. prepared spherical average particle sizes 100-200 nm, almost no volatilization, surface stability, can respond acidic redox microenvironments release PVAs. synergistic activities against Sclerotinia sclerotiorum Penicillium digitatum, good biological safety plants. Therefore, these findings important implications efficient utilization agriculture, ensuring ecological environment realizing development agriculture.

Язык: Английский

Scenario-oriented nanopesticides: Shaping nanopesticides for future agriculture DOI Creative Commons
Wenjie Shangguan, Huiping Chen, Pengyue Zhao

и другие.

Advanced Agrochem, Год журнала: 2024, Номер 3(4), С. 265 - 278

Опубликована: Июль 16, 2024

Nanopesticides, as a promising technology, bring scientific and technological impetus to sustainable development green revolution of agriculture. The excellent physicochemical properties, beneficial biological effects, functional potential nanopesticides have significantly contributed improving utilization rates pesticides, enhancing pest disease management, alleviating stresses. However, agricultural production plant cultivation are diverse, leading wide range application scenarios for pesticides. These put forward more precise requirements numerous innovative opportunities the nanopesticides. Scenario-oriented customized various methods, aligning with principles economical, efficient, future This article outlines status then reviews research progress scenario-oriented nanopesticides, encompassing nine major scenarios. Finally, priorities prospects summarized, offering concepts advancement

Язык: Английский

Процитировано

13

A hybrid of bimodal mesoporous silica and metal organic framework for intelligent co-delivery of dual-pesticide for synergistic controlling fungal disease and insect pest DOI

Hongling Pei,

Meijing Wang,

Tingze Yang

и другие.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер 709, С. 136140 - 136140

Опубликована: Янв. 7, 2025

Язык: Английский

Процитировано

1

Facile Synthesis of Flower-cluster ZIF Nanocarriers: Performance in Controlled Release of Thiamethoxam and Insecticidal Activity DOI
Xin Ding,

Kexin Yang,

Xin Yang

и другие.

Environmental Research, Год журнала: 2025, Номер 268, С. 120753 - 120753

Опубликована: Янв. 4, 2025

Язык: Английский

Процитировано

1

Photo-responsive supramolecular hydrogels to enhance pesticide bioavailability through multiple structural transformations DOI
Hanghang Zhang, Yingxi Zhang, Manli Yu

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер 505, С. 159473 - 159473

Опубликована: Янв. 11, 2025

Язык: Английский

Процитировано

1

Size Effects of Nanoenabled Agrochemicals in Sustainable Crop Production: Advances, Challenges, and Perspectives DOI
Hongyi Liu, Wenjie Shangguan, Pengyue Zhao

и другие.

ACS Nano, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Nanoenabled agrochemicals mainly including nanopesticides and nanofertilizers based on nanotechnology play a crucial role in plant protection food security. These exhibit high dose delivery efficiency biological activity due to their unique nanoscale properties. However, properties can also be double-edged sword, posing potential risks both humans the environment. As nanoenabled become more widely used, it is essential have an objective comprehensive discussion of size effects these agrochemicals. In this paper, we reviewed research progress terms delivery, activity, nontarget safety. We investigated complex factors affecting sought draw insights from biomedicine, engineering, food, other relevant fields. Based literatures review, could concluded that "the smaller better" not always case. further outlooked development prospects studying agrochemicals, emphasizing necessity for thorough in-depth while critically identifying key issues need addressed. conclusion, proper comprehension bridges gap between scientific community industry, bolstering advancing sustainable agriculture.

Язык: Английский

Процитировано

6

Two birds with one stone: Multifunctional controlled‐release formulations of pesticides DOI Creative Commons
Chunli Xu, Huiping Chen, Wenjie Shangguan

и другие.

New plant protection., Год журнала: 2024, Номер 1(1)

Опубликована: Сен. 1, 2024

Abstract Controlled release and nanotechnology techniques hold promising potential for propelling the pesticide industry toward goals of green revolution. This study introduces concept atom economy into multifunctionality controlled‐release formulations (CRFs) pesticides from both economic sustainable perspectives. In addition to their core function controlling active ingredient, carriers also provide additional benefits, including enhanced foliar adhesion translocation, nutritional function, synergistic bioactivity, safety nontarget organisms, crop stress alleviation, reduced soil leaching, remediation, fluorescence visualization. These functions are highlighted taken seriously. Through ingenious excogitation, multifunctional CRFs can achieve multiple objectives, enhancing input efficiency while minimizing environmental impacts. We tentatively blazed a trail by reviewing recent advances in perspective chemistry. Additionally, development implementation barriers were discussed, emphasizing necessity robust field trials comprehensive systems‐level efficacy/biosafety evaluations substantially boost technical readiness performance pesticides. Our goal is expand formulations, thereby accelerating global agrochemical products.

Язык: Английский

Процитировано

3

Fabrication of Novel Porous Nano-pesticides by Modifying MPN onto Cu-TCPP MOFs to Enhance Bactericidal Efficacy and Modulate Its Bioavailability DOI

Jiatong Han,

Guangyang Liu, Yushan Hou

и другие.

Nano Letters, Год журнала: 2024, Номер 24(45), С. 14405 - 14411

Опубликована: Окт. 29, 2024

Nano-pesticides have attracted much attention in the field of agriculture, due to existing problems such as decreased bactericidal effect and poor adhesion. An environmentally friendly metal porphyrin (Cu-TCPP)-based nanocarrier pesticide release diniconazole (DIN) was designed enhance efficacy modulate its bioavailability a multidimensional manner by constructing phenolic network (MPN) encapsulation. The introduction MPN prevents DIN from prematurely escaping Cu-TCPP@DIN@MPN environment gives it strong interfacial adhesion resist rain washing. resulting nanoparticles (NPs) showed lamellar stacked embedded structure, which improved inhibition Fusarium oxysporum (90.9%) photostability (67.2%), while they do not affect healthy plant growth meet relevant food safety requirements for residues. This work provides new ideas development superior photostable, adhesive, rainwater erosion-resistant, sustainable pesticides.

Язык: Английский

Процитировано

3

Formulation of Ethyl Cellulose Nanoparticles Encapsulated with Osthole Provides Long-Lasting Plant Protection against a Major Pest Mite DOI

Fang Dong,

Jie Men,

Ziwei Ding

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Янв. 29, 2025

The broader use of botanical pesticides has been limited by shorter residual activity on plants, slower onset action, and higher costs compared with conventional pesticides. These challenges could be overcome the development simple, cost-effective, long-lasting preventive nanocomposites for In this study, we successfully developed a low-cost ethyl cellulose (EC)-based delivery system pesticide osthole (OST), designed to provide extended protection against Tetranychus urticae infestations. A comparative analysis three (graphene oxide (GO)-OST, EC-OST, chitosan (CS)-OST) revealed that EC-OST exhibited superior thermal stability, UV resistance, controlled release OST payload, strong acaricidal activity. degradation leaf surfaces was reduced encapsulation in EC, while its penetration into plant tissues improved. When applied leaves, an increase T. mortality, reduction reproduction egg adhesion, impairment feeding behavior through searching times were observed. peak occurrence infestation delayed 10 days following application reducing damage protecting plants more than 20 days. This nanoinsecticide allows low-frequency application, farmers' production costs, increasing profitability, thereby offering great potential promoting protection.

Язык: Английский

Процитировано

0

Prodrug self-assemblies based on acifluorfen and glucose for improving the effective utilization and reducing the risks to environment DOI
Jianhua Xiao, Gang Tang, Xiaohong Zhang

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161382 - 161382

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Carrier‐free co‐delivery nanosystem based on prothioconazole and pyrimethanil to enhance fungicidal efficacy and reduce environmental risks DOI
Yulu Liu, Yuqi Huang,

Gaohua Hu

и другие.

Pest Management Science, Год журнала: 2025, Номер unknown

Опубликована: Апрель 17, 2025

The conventional application of fungicides suffers from substantial off-target loss due to photolysis, evaporation, and rain washing, resulting in risks the environment human health. To address these limitations, self-assembled nanopesticides based on two kinds have emerged as precision agrochemical delivery platforms that synchronize enhanced bioactivity with environmental risk mitigation. Herein, core-shell structured nanoparticles (PRO-PYR NPs) an average particle size 263 nm were fabricated prothioconazole (PRO) pyrimethanil (PYR) via non-covalent interactions using co-assembly technology. co-delivery system acid-responsive release property both antifungal activities against Botrytis cinerea Fusarium graminearum duration cinerea. Importantly, obtained PRO-PYR NPs could significantly improve photostability foliage adhesion reduce their volatility leaching potential. Additionally, reduced genotoxicity PRO PYR root tip cells Vicia faba acute toxicity zebrafish. commonly used successfully prepared by technology effectively physicochemical properties. Carrier-free strategy multiple components enhance control effect lower negative impacts associated non-target organisms for integrated pest management. © 2025 Society Chemical Industry.

Язык: Английский

Процитировано

0