Investigation of Polyester Tire Cord Glycolysis Accompanied by Rubber Crumb Devulcanization DOI Open Access
Kirill Kirshanov, Р. В. Томс, P. V. Melnikov

и другие.

Polymers, Год журнала: 2022, Номер 14(4), С. 684 - 684

Опубликована: Фев. 11, 2022

A new method for the recycling of a polyester tire cord under action oligoethylene terephthalates, bis(2-hydroxyethyl) terephthalate and ethylene glycol has been proposed. The involves simultaneous homogeneous glycolysis polyethylene devulcanization crumb rubber. Polyester glycolysates were characterized by FTIR spectroscopy gel permeation chromatography (GPC). process was investigated swelling-based methods. rate proposed in melt phase proved to be higher than one heterogeneous glycolysis. assumption more efficient presence softener also confirmed. degree 46.07%, apparent swelling 167.4%, constant 0.0902 min-1 achieved. results indicate that made it possible carry out deeply known with various agents, but further research is needed industrial implementation.

Язык: Английский

Mechanical Performance of Recycled 3D Printed Sustainable Polymer-Based Composites: A Literature Review DOI Open Access

Ioannis Filippos Kyriakidis,

Nikolaos Kladovasilakis, Eleftheria Maria Pechlivani

и другие.

Journal of Composites Science, Год журнала: 2024, Номер 8(6), С. 215 - 215

Опубликована: Июнь 7, 2024

The development of efficient waste valorization strategies has emerged as an important field in the overall efforts for alignment with environmental goals that have been set by European Union (EU) Green Deal regarding sustainable circular economy models. Additive manufacturing a method secondary life product main advantages it being form net-zero production and having ability to successfully transport complex design actual products finding applications industry rapid prototyping or tailored products. insertion eco-friendly materials these processes can lead significant reduction material footprints lower energy demands process, helping achieve Sustainable Development Goal 12 (SDG12) EU responsible consumption. aim this comprehensive review is state existing progress incorporation polymeric composite additive (AM) identify possible gaps further research. In context, presentation reacquired coming from urban industrial are used produce composites made. Then, assessment printability mechanical response constructed made, taking into consideration some key thermal, rheological properties (e.g., viscosity, melting degradation temperature, tensile impact strength). Finally, cycle analysis results presented footprint during waste-to-feedstock processes. A lack scientific research was observed, manifestation novel evaluation techniques such dynamic testing. Assessing vital evaluating whether types adequate upscaling use real applications.

Язык: Английский

Процитировано

12

Characterization of recycled and virgin polyethylene terephthalate composites reinforced with modified kenaf fibers for automotive application DOI
Macaulay M. Owen,

Emmanuel O. Achukwu,

Hazizan Md Akil

и другие.

Polymer Composites, Год журнала: 2022, Номер 43(11), С. 7724 - 7738

Опубликована: Июль 21, 2022

Abstract The current research has produced engineering plastics composite for automotive applications using waste recycled plastic polyethylene terephthalate (RPET) bottles as the matrix and compounded with chemically modified natural kenaf fibers in comparison virgin (PET) composites under same processing conditions. Kenaf were surface by alkali epoxy coating treatment methods. RPET which mechanically pulverized a 5 mm mesh size aperture into flakes melt‐mixed 10 wt% of short twin‐screw extruder compression‐molded at 240°С optimized temperature. Mechanical thermal analyses performed on both RPET, PET (VPET), their constituent composites. Scanning electron microscopy (SEM) was carried out to assess composite's morphological characteristics. results show that treated (TKF/RPET TKF/VPET) gave higher mechanical properties compared untreated (KF/RPET KF/VPET) its impact than VPET However, tensile flexural strength showed melting peak temperatures 252.9°C 245.8°C respectively. Both TKF/RPET TKF/VPET more thermally stable decomposed SEM strong fiber/matrix adhesion no clear evidence fiber degradation It can be concluded possessed similar counterpart serve substitute formulation.

Язык: Английский

Процитировано

32

Granule-based material extrusion is comparable to filament-based material extrusion in terms of mechanical performances of printed PLA parts: A comprehensive investigation DOI Creative Commons
Handai Liu, Ke Gong, Alexandre Portela

и другие.

Additive manufacturing, Год журнала: 2023, Номер 75, С. 103744 - 103744

Опубликована: Авг. 1, 2023

To implement a circular economic life for thermoplastic waste, such as polylactic acid (PLA) waste from filament-based material extrusion (FME) printing and reduce the costs associated with producing filaments FME process, granule-based (GME) printer was developed by modifying head head. However, concerns have been raised about mechanical performance of parts printed using GME method. Previous studies reported mixed results, some finding inferior compared to counterparts, while others comparable or slightly better performance. Moreover, these were limited tensile flexural evaluations, lacked clear explanation support them. Therefore, address this uncertainty research gaps, comprehensive comparison analysis study conducted among specimens two types printers. Characterization tests conducted, including tests, impact 3-point bending hardness reveal properties parts. Furthermore, scanning electron microscope (SEM) differential calorimetry (DSC) thermal imaging, rheological gel permeation chromatography (GPC) carried out analyze explain results. The results indicated no significant differences (P > 0.05) in terms properties, strength modulus, strength. there difference shore D strain at break between methods, complex viscosity samples greater than that counterparts. Remarkably, average molecular weights higher those ones, which can be attributed lower actual temperature chamber due its different location heater, thermistor melting

Язык: Английский

Процитировано

23

Development and characterization of sustainable 3D printing filaments using post-consumer recycled PET: processing and characterization DOI
Ch Kapil Ror, Sushant Negi, Vishal Mishra

и другие.

Journal of Polymer Research, Год журнала: 2023, Номер 30(9)

Опубликована: Авг. 16, 2023

Язык: Английский

Процитировано

20

Three-dimensional printing with waste acrylonitrile butadiene styrene: Processing and characterization DOI
Vishal Mishra, Sushant Negi, S. Kar

и другие.

Journal of Reinforced Plastics and Composites, Год журнала: 2024, Номер unknown

Опубликована: Янв. 2, 2024

Three-dimensional (3D) printing of waste plastic such as acrylonitrile butadiene styrene (ABS) is challenging because multiple heating cycles and irregular cooling cause accumulation stress in 3D-printed structures, which significantly affects mesostructured fiber-to-fiber bond strength. Hence, this study demonstrates the ability to print high-quality parts via 3D using ABS waste. The different weight proportions (100, 90/10, 80/20, 70/30, 60/40, 50/50) recycled (RABS)/virgin (VABS) are selected for experimentation. It found that increasing VABS content RABS improved physical properties samples. Due blending RABS, average enhancement flexural strength (Sf), flex modulus (Ef), work fracture (WOF) 11.49%, 5.45%, 17.31%, respectively, when compared with 100% Similarly, increase Young’s (E), tensile at yield (Ty), ultimate (UTS) 7.71%, 5.19%, 3.51%, respectively. samples printed 50% RABS/50% blends show superior mechanical than others, also 90% RABS/10% 80% RABS/20% very close provides unique opportunities sustainable use technology.

Язык: Английский

Процитировано

9

Local thermal conditions influencing the mechanical properties of recycled polypropylene as a filament for fused filament fabrication DOI Creative Commons

Itsari Phuangmali,

Yao Xu,

Miaozi Huang

и другие.

Polymer, Год журнала: 2024, Номер 296, С. 126812 - 126812

Опубликована: Фев. 19, 2024

Язык: Английский

Процитировано

7

Insights into Flexural and Impact Properties of Polymer Based Materials Printed Through Fused Filament Fabrication: Progress in The Last Decade DOI Creative Commons
Wajid Khan, Malik Hassan, Iftikhar Ahmed

и другие.

International Journal of Lightweight Materials and Manufacture, Год журнала: 2024, Номер unknown

Опубликована: Июнь 1, 2024

The Fused Filament Fabrication is an economic 3D printing process to produce lightweight polymers-based structures. Therefore, it drawing a consistently increasing interest from industry and researchers. Flexural impact properties are two of the critical performance measures for gauging integrity printed Since 2014, numerous studies have been carried out on this topic, however, their holistic overview with focus flexural has barely presented in literature. current article reviews relationship between parameters, both operating geometrical, these detail. cause-effect thoroughly examined considering material effect. This allows identification complex interactive effects conducive ranges important parameters effectively control achieving desired mechanical properties. review establishes that crystallinity post-printed polymers crucial factor controlling properties, filled generally offer better than unfilled ones if right filler given chosen. Topology optimization, recyclability through FFF, retention polymer after also discussed as innovative trends. Finally, limitations research gaps identified, latest ideas proposed way forward further development FFF technology.

Язык: Английский

Процитировано

7

Enhancing the electroactive β-phase of PVDF filaments via feedstock processing DOI
Fawad Ali,

Imran Parvez,

Mohammad I. Albakri

и другие.

Smart Materials and Structures, Год журнала: 2025, Номер 34(3), С. 035012 - 035012

Опубликована: Янв. 31, 2025

Abstract Polyvinylidene fluoride (PVDF) is a smart piezoelectric material with remarkable properties, offering vast potential for applications in areas such as energy harvesting, biomedical devices, and sensors. Among its various crystalline phases, the β -phase most electroactive, characterized by high dielectric properties. Recently, PVDF has been processed using 3D printing due to technology’s ability fabricate complex intricate structures, along advantages design flexibility, efficiency, rapid prototyping. While content often enhanced through additives or post-processing, limited attention given role of feedstock preparation extrusion parameters phase enhancement. In this study, we investigated how influence PVDF, aiming optimize properties applications. filaments were produced two different methods: direct from pellets solution-based process involving dissolution solvent, followed extrusion. Phase content, structural changes, thermal stability assessed x-ray diffraction (XRD), Fourier-transform infrared spectroscopy, differential scanning calorimetry. Results show that processing conditions significantly impact crystallinity concentration filaments. Notably, solution-processed exhibited higher compared pellet-based method, suggesting approach may enhance performance. This study highlights importance techniques means tailoring electroactive advanced 3D-printed

Язык: Английский

Процитировано

1

Investigation of distributed recycling of polylactic acid over multiple generations via the granule-based material extrusion process DOI
Handai Liu, Ke Gong, Alexandre Portela

и другие.

Journal of Cleaner Production, Год журнала: 2024, Номер 436, С. 140609 - 140609

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

6

Creating Sustainable Composites from Pyrolyzed Burlap and Ocean-Recycled Plastics using FDM DOI
Malik Hassan, Akhilesh Kumar Pal, Arturo Rodriguez‐Uribe

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер 12(4), С. 1405 - 1419

Опубликована: Янв. 17, 2024

The study focuses on the mechanical performance of a blend ocean-recycled high-density polyethylene (rHDPE) and polypropylene (rPP) explores effect adding burlap biocarbon from post-industrial waste as filler. This aims to upcycle plastic compare conventional injection molding with 3D printing. Taguchi-gray relational analysis was utilized determine preferred printing conditions for both rHDPE–rPP rHDPE–rPP–biocarbon composite. found that were raster angle 0°, speed 900 mm/min, nozzle temperature 215 °C, while composite 1200 255 °C. also compared properties printed injection-molded samples, demonstrating higher tensile flexural moduli percent increase 7 12%, respectively, counterparts. However, no considerable difference in modulus observed between samples Moreover, it addition resulted an enhancement optimized specimen 17 5%, respectively. exhibited decrease impact strength 63 23%,

Язык: Английский

Процитировано

6