Polymers,
Год журнала:
2022,
Номер
14(4), С. 684 - 684
Опубликована: Фев. 11, 2022
A
new
method
for
the
recycling
of
a
polyester
tire
cord
under
action
oligoethylene
terephthalates,
bis(2-hydroxyethyl)
terephthalate
and
ethylene
glycol
has
been
proposed.
The
involves
simultaneous
homogeneous
glycolysis
polyethylene
devulcanization
crumb
rubber.
Polyester
glycolysates
were
characterized
by
FTIR
spectroscopy
gel
permeation
chromatography
(GPC).
process
was
investigated
swelling-based
methods.
rate
proposed
in
melt
phase
proved
to
be
higher
than
one
heterogeneous
glycolysis.
assumption
more
efficient
presence
softener
also
confirmed.
degree
46.07%,
apparent
swelling
167.4%,
constant
0.0902
min-1
achieved.
results
indicate
that
made
it
possible
carry
out
deeply
known
with
various
agents,
but
further
research
is
needed
industrial
implementation.
Journal of Composites Science,
Год журнала:
2024,
Номер
8(6), С. 215 - 215
Опубликована: Июнь 7, 2024
The
development
of
efficient
waste
valorization
strategies
has
emerged
as
an
important
field
in
the
overall
efforts
for
alignment
with
environmental
goals
that
have
been
set
by
European
Union
(EU)
Green
Deal
regarding
sustainable
circular
economy
models.
Additive
manufacturing
a
method
secondary
life
product
main
advantages
it
being
form
net-zero
production
and
having
ability
to
successfully
transport
complex
design
actual
products
finding
applications
industry
rapid
prototyping
or
tailored
products.
insertion
eco-friendly
materials
these
processes
can
lead
significant
reduction
material
footprints
lower
energy
demands
process,
helping
achieve
Sustainable
Development
Goal
12
(SDG12)
EU
responsible
consumption.
aim
this
comprehensive
review
is
state
existing
progress
incorporation
polymeric
composite
additive
(AM)
identify
possible
gaps
further
research.
In
context,
presentation
reacquired
coming
from
urban
industrial
are
used
produce
composites
made.
Then,
assessment
printability
mechanical
response
constructed
made,
taking
into
consideration
some
key
thermal,
rheological
properties
(e.g.,
viscosity,
melting
degradation
temperature,
tensile
impact
strength).
Finally,
cycle
analysis
results
presented
footprint
during
waste-to-feedstock
processes.
A
lack
scientific
research
was
observed,
manifestation
novel
evaluation
techniques
such
dynamic
testing.
Assessing
vital
evaluating
whether
types
adequate
upscaling
use
real
applications.
Polymer Composites,
Год журнала:
2022,
Номер
43(11), С. 7724 - 7738
Опубликована: Июль 21, 2022
Abstract
The
current
research
has
produced
engineering
plastics
composite
for
automotive
applications
using
waste
recycled
plastic
polyethylene
terephthalate
(RPET)
bottles
as
the
matrix
and
compounded
with
chemically
modified
natural
kenaf
fibers
in
comparison
virgin
(PET)
composites
under
same
processing
conditions.
Kenaf
were
surface
by
alkali
epoxy
coating
treatment
methods.
RPET
which
mechanically
pulverized
a
5
mm
mesh
size
aperture
into
flakes
melt‐mixed
10
wt%
of
short
twin‐screw
extruder
compression‐molded
at
240°С
optimized
temperature.
Mechanical
thermal
analyses
performed
on
both
RPET,
PET
(VPET),
their
constituent
composites.
Scanning
electron
microscopy
(SEM)
was
carried
out
to
assess
composite's
morphological
characteristics.
results
show
that
treated
(TKF/RPET
TKF/VPET)
gave
higher
mechanical
properties
compared
untreated
(KF/RPET
KF/VPET)
its
impact
than
VPET
However,
tensile
flexural
strength
showed
melting
peak
temperatures
252.9°C
245.8°C
respectively.
Both
TKF/RPET
TKF/VPET
more
thermally
stable
decomposed
SEM
strong
fiber/matrix
adhesion
no
clear
evidence
fiber
degradation
It
can
be
concluded
possessed
similar
counterpart
serve
substitute
formulation.
Additive manufacturing,
Год журнала:
2023,
Номер
75, С. 103744 - 103744
Опубликована: Авг. 1, 2023
To
implement
a
circular
economic
life
for
thermoplastic
waste,
such
as
polylactic
acid
(PLA)
waste
from
filament-based
material
extrusion
(FME)
printing
and
reduce
the
costs
associated
with
producing
filaments
FME
process,
granule-based
(GME)
printer
was
developed
by
modifying
head
head.
However,
concerns
have
been
raised
about
mechanical
performance
of
parts
printed
using
GME
method.
Previous
studies
reported
mixed
results,
some
finding
inferior
compared
to
counterparts,
while
others
comparable
or
slightly
better
performance.
Moreover,
these
were
limited
tensile
flexural
evaluations,
lacked
clear
explanation
support
them.
Therefore,
address
this
uncertainty
research
gaps,
comprehensive
comparison
analysis
study
conducted
among
specimens
two
types
printers.
Characterization
tests
conducted,
including
tests,
impact
3-point
bending
hardness
reveal
properties
parts.
Furthermore,
scanning
electron
microscope
(SEM)
differential
calorimetry
(DSC)
thermal
imaging,
rheological
gel
permeation
chromatography
(GPC)
carried
out
analyze
explain
results.
The
results
indicated
no
significant
differences
(P
>
0.05)
in
terms
properties,
strength
modulus,
strength.
there
difference
shore
D
strain
at
break
between
methods,
complex
viscosity
samples
greater
than
that
counterparts.
Remarkably,
average
molecular
weights
higher
those
ones,
which
can
be
attributed
lower
actual
temperature
chamber
due
its
different
location
heater,
thermistor
melting
Journal of Reinforced Plastics and Composites,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 2, 2024
Three-dimensional
(3D)
printing
of
waste
plastic
such
as
acrylonitrile
butadiene
styrene
(ABS)
is
challenging
because
multiple
heating
cycles
and
irregular
cooling
cause
accumulation
stress
in
3D-printed
structures,
which
significantly
affects
mesostructured
fiber-to-fiber
bond
strength.
Hence,
this
study
demonstrates
the
ability
to
print
high-quality
parts
via
3D
using
ABS
waste.
The
different
weight
proportions
(100,
90/10,
80/20,
70/30,
60/40,
50/50)
recycled
(RABS)/virgin
(VABS)
are
selected
for
experimentation.
It
found
that
increasing
VABS
content
RABS
improved
physical
properties
samples.
Due
blending
RABS,
average
enhancement
flexural
strength
(Sf),
flex
modulus
(Ef),
work
fracture
(WOF)
11.49%,
5.45%,
17.31%,
respectively,
when
compared
with
100%
Similarly,
increase
Young’s
(E),
tensile
at
yield
(Ty),
ultimate
(UTS)
7.71%,
5.19%,
3.51%,
respectively.
samples
printed
50%
RABS/50%
blends
show
superior
mechanical
than
others,
also
90%
RABS/10%
80%
RABS/20%
very
close
provides
unique
opportunities
sustainable
use
technology.
International Journal of Lightweight Materials and Manufacture,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 1, 2024
The
Fused
Filament
Fabrication
is
an
economic
3D
printing
process
to
produce
lightweight
polymers-based
structures.
Therefore,
it
drawing
a
consistently
increasing
interest
from
industry
and
researchers.
Flexural
impact
properties
are
two
of
the
critical
performance
measures
for
gauging
integrity
printed
Since
2014,
numerous
studies
have
been
carried
out
on
this
topic,
however,
their
holistic
overview
with
focus
flexural
has
barely
presented
in
literature.
current
article
reviews
relationship
between
parameters,
both
operating
geometrical,
these
detail.
cause-effect
thoroughly
examined
considering
material
effect.
This
allows
identification
complex
interactive
effects
conducive
ranges
important
parameters
effectively
control
achieving
desired
mechanical
properties.
review
establishes
that
crystallinity
post-printed
polymers
crucial
factor
controlling
properties,
filled
generally
offer
better
than
unfilled
ones
if
right
filler
given
chosen.
Topology
optimization,
recyclability
through
FFF,
retention
polymer
after
also
discussed
as
innovative
trends.
Finally,
limitations
research
gaps
identified,
latest
ideas
proposed
way
forward
further
development
FFF
technology.
Smart Materials and Structures,
Год журнала:
2025,
Номер
34(3), С. 035012 - 035012
Опубликована: Янв. 31, 2025
Abstract
Polyvinylidene
fluoride
(PVDF)
is
a
smart
piezoelectric
material
with
remarkable
properties,
offering
vast
potential
for
applications
in
areas
such
as
energy
harvesting,
biomedical
devices,
and
sensors.
Among
its
various
crystalline
phases,
the
β
-phase
most
electroactive,
characterized
by
high
dielectric
properties.
Recently,
PVDF
has
been
processed
using
3D
printing
due
to
technology’s
ability
fabricate
complex
intricate
structures,
along
advantages
design
flexibility,
efficiency,
rapid
prototyping.
While
content
often
enhanced
through
additives
or
post-processing,
limited
attention
given
role
of
feedstock
preparation
extrusion
parameters
phase
enhancement.
In
this
study,
we
investigated
how
influence
PVDF,
aiming
optimize
properties
applications.
filaments
were
produced
two
different
methods:
direct
from
pellets
solution-based
process
involving
dissolution
solvent,
followed
extrusion.
Phase
content,
structural
changes,
thermal
stability
assessed
x-ray
diffraction
(XRD),
Fourier-transform
infrared
spectroscopy,
differential
scanning
calorimetry.
Results
show
that
processing
conditions
significantly
impact
crystallinity
concentration
filaments.
Notably,
solution-processed
exhibited
higher
compared
pellet-based
method,
suggesting
approach
may
enhance
performance.
This
study
highlights
importance
techniques
means
tailoring
electroactive
advanced
3D-printed
ACS Sustainable Chemistry & Engineering,
Год журнала:
2024,
Номер
12(4), С. 1405 - 1419
Опубликована: Янв. 17, 2024
The
study
focuses
on
the
mechanical
performance
of
a
blend
ocean-recycled
high-density
polyethylene
(rHDPE)
and
polypropylene
(rPP)
explores
effect
adding
burlap
biocarbon
from
post-industrial
waste
as
filler.
This
aims
to
upcycle
plastic
compare
conventional
injection
molding
with
3D
printing.
Taguchi-gray
relational
analysis
was
utilized
determine
preferred
printing
conditions
for
both
rHDPE–rPP
rHDPE–rPP–biocarbon
composite.
found
that
were
raster
angle
0°,
speed
900
mm/min,
nozzle
temperature
215
°C,
while
composite
1200
255
°C.
also
compared
properties
printed
injection-molded
samples,
demonstrating
higher
tensile
flexural
moduli
percent
increase
7
12%,
respectively,
counterparts.
However,
no
considerable
difference
in
modulus
observed
between
samples
Moreover,
it
addition
resulted
an
enhancement
optimized
specimen
17
5%,
respectively.
exhibited
decrease
impact
strength
63
23%,