Carbon
circularity
is
crucial
for
achieving
a
circular
economy
but
has
wider
implications
and
impacts
with
respect
to
the
of
materials.
It
an
in-depth
transformative
effect
on
economy.
CO
Highlights of Sustainability,
Год журнала:
2024,
Номер
3(2), С. 205 - 239
Опубликована: Май 9, 2024
The
atmospheric
carbon
dioxide
(CO2)
accumulation
(2–2.5
ppmv/year)
is
the
result
of
enormous
gap
between
its
emissions
(37
Gton/year)
and
capture,
storage,
utilization
(<500
Mton/year).
Climate
has
been
dramatically
affected
due
to
failure
natural
sinks,
in
working
effectively.
To
address
this
Gton-scale
gap,
numerous
uses
applications
are
needed
particularly,
those
consuming
vast
volumes
compound
and/or
rendering
longevous
products
or
long
lifecycle
services.
Thus,
(CU)
can
be
seen
as
step
close
cycle.
Among
CU,
R&D
on
CO2
chemical
conversion
proposed
a
variety
processes,
with
different
degrees
developmental
maturity.
These
process
technologies
could
efficiently
effectively
integrated
into
refineries
upgrade
emitted
CO2.
A
technology
pipeline
consisting
database
these
processes
market
status
should
defined
based
published
scientific
results
patents.
Then,
an
innovative
top-down
methodology
eco-design
configurations
that
refinery,
warrant
sustainable
cycle
(in
terms
energy,
environment,
economy)
change
ways
producing
fuels,
chemicals,
materials.
Additionally,
used
identify
research
development
gaps
needs,
for
orienting
science
investments
measures.
Hopefully,
will
implemented
circular
C-based
economy
underpin
decarbonized
industry.
Chemical Society Reviews,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
This
review
discusses
the
behavior
of
low-concentration
carbon
dioxide
(LCC)
in
multiphase
flows
and
interfaces,
covering
diffusion,
adsorption,
catalytic
mechanisms,
applications
CO
2
capture,
storage,
conversion,
challenges,
prospect.
The Chemical Record,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 3, 2025
Abstract
Electrocatalysis
is
a
crucial
technology
that
will
enable
future
low‐carbon
chemical
production
and
energy
beyond
fossil
fuels.
Notwithstanding
the
intense
growing
research
in
area,
potentialities
of
field
are
largely
unexplored.
We
provide
case
examples
discuss
emerging
possibilities
have
still
not
been
investigated
enough
but
necessary
to
exploit
this
potential
e‐chemistry.
Starting
from
defining
trends
setting
scene,
as
well
clarifying
difference
between
electrochemistry
electrocatalysis,
some
elements
vision
foster
innovation
discussed.
The
aim
stimulate
discussion
reflection
rather
than
review
state‐of‐the‐art.
Aspects
discussed
regard
i)
passing
electro
photoelectrocatalytic
approaches,
ii)
making
chemicals
air,
iii)
exploitation
both
anodic
cathodic
reactions,
tandem/paired
electrocatalytic
iv)
for
selective
oxidation
mediated
synthesis.
Priorities
strategies
an
e‐chemistry
Intensifying
these
directions
extending
still‐too‐limited
current
including
modelling
design,
effort
accelerate
realisation
distributed
The Chemical Record,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 14, 2025
Abstract
Layered
Double
Hydroxides
(LDHs)
are
versatile
materials
with
tuneable
properties.
They
show
promising
electro‐
and
photo‐catalytic
activity
in
the
activation
conversion
of
CO
2
.
Their
unique
properties
make
LDHs
pivotal
emerging
sustainable
strategies
for
mitigating
effect
emissions.
However,
intricate
structure‐property
relationship
inherent
to
challenges
their
rational
design.
In
this
review,
we
provide
a
comprehensive
overview
both
experimental
computational
studies
about
photo‐
electro‐catalytic
,
mainly
focusing
on
Cu‐based
systems
due
superior
performance
producing
C
products.
We
present
background
framework,
describing
essentials
tools,
designed
support
experimentalists
theoreticians
development
tailored
LDH
efficient
valorisation.
Finally,
discuss
future
potential
advancements,
emphasizing
importance
new
synergistic
experimental‐computational
studies.
Recent
research
on
the
electrocatalytic
CO2
reduction
reaction
(eCO2RR)
has
garnered
significant
attention
given
its
capability
to
address
environmental
issues
associated
with
emissions
while
harnessing
clean
energy
produce
high-value-added
products.
Compared
C1
products,
C2+
products
provide
greater
densities
and
are
highly
sought
after
as
chemical
feedstocks.
However,
formation
of
C-C
bond
is
challenging
due
competition
H-H
C-H
bonds.
Therefore,
elevate
selectivity
yield
fuels,
it
essential
develop
more
advanced
electrocatalysts
optimize
design
electrochemical
cell
configurations.
Of
materials
investigated
for
CO2RR,
Cu-based
stand
out
their
wide
availability,
affordability,
compatibility.
Moreover,
catalysts
exhibit
promising
capabilities
in
adsorption
activation,
facilitating
compounds
via
coupling.
This
review
examines
recent
both
cells
electroreduction
compounds,
introducing
core
principles
eCO2RR
pathways
involved
generating
A
key
focus
categorization
catalyst
designs,
including
defect
engineering,
surface
modification,
nanostructure
tandem
catalysis.
By
analyzing
studies
catalysts,
we
aim
elucidate
mechanisms
behind
enhanced
compounds.
Additionally,
various
types
electrolytic
discussed.
Lastly,
prospects
limitations
utilizing
highlighted
future
research.
Abstract
Electrification
of
chemical
production
requires
the
development
innovative
solutions,
with
plasma
catalysis
being
among
them.
This
perspective
summarizes
many
years
studies
and
discussions
made
in
frame
ERC
Synergy
project
SCOPE
dedicated
to
above
aspects.
However,
it
does
not
aim
overview
results
but
rather
use
them
combination
literature
indications
outline
emerging
trends
present
gaps
pass
from
a
research
area
key
technology
develop
sustainable
associated
changes
required
modalities
production.
The
thus
aims
offer
vision
future
for
its
role
facing
societal
challenges.