A Zero‐Gap Gas Phase Photoelectrolyzer for CO₂ Reduction with Porous Carbon Supported Photocathodes

ChemSusChem, Journal Year: 2024, Volume and Issue: 17(16)

Published: April 30, 2024

A modified Metal-Organic Framework UiO-66-NH

Language: Английский

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A Carbon Dioxide Refinery: The Core of a Sustainable Carbon-based Circular Economy

Highlights of Sustainability, Journal Year: 2024, Volume and Issue: 3(2), P. 205 - 239

Published: May 9, 2024

The atmospheric carbon dioxide (CO2) accumulation (2–2.5 ppmv/year) is the result of enormous gap between its emissions (37 Gton/year) and capture, storage, utilization (<500 Mton/year). Climate has been dramatically affected due to failure natural sinks, in working effectively. To address this Gton-scale gap, numerous uses applications are needed particularly, those consuming vast volumes compound and/or rendering longevous products or long lifecycle services. Thus, (CU) can be seen as step close cycle. Among CU, R&D on CO2 chemical conversion proposed a variety processes, with different degrees developmental maturity. These process technologies could efficiently effectively integrated into refineries upgrade emitted CO2. A technology pipeline consisting database these processes market status should defined based published scientific results patents. Then, an innovative top-down methodology eco-design configurations that refinery, warrant sustainable cycle (in terms energy, environment, economy) change ways producing fuels, chemicals, materials. Additionally, used identify research development gaps needs, for orienting science investments measures. Hopefully, will implemented circular C-based economy underpin decarbonized industry.

Language: Английский

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Behavior, mechanisms, and applications of low-concentration CO₂ in energy media

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review discusses the behavior of low-concentration carbon dioxide (LCC) in multiphase flows and interfaces, covering diffusion, adsorption, catalytic mechanisms, applications CO 2 capture, storage, conversion, challenges, prospect.

Language: Английский

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Electrocatalysis: Prospects and Role to Enable an E‐Chemistry Future

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Electrocatalysis is a crucial technology that will enable future low‐carbon chemical production and energy beyond fossil fuels. Notwithstanding the intense growing research in area, potentialities of field are largely unexplored. We provide case examples discuss emerging possibilities have still not been investigated enough but necessary to exploit this potential e‐chemistry. Starting from defining trends setting scene, as well clarifying difference between electrochemistry electrocatalysis, some elements vision foster innovation discussed. The aim stimulate discussion reflection rather than review state‐of‐the‐art. Aspects discussed regard i) passing electro photoelectrocatalytic approaches, ii) making chemicals air, iii) exploitation both anodic cathodic reactions, tandem/paired electrocatalytic iv) for selective oxidation mediated synthesis. Priorities strategies an e‐chemistry Intensifying these directions extending still‐too‐limited current including modelling design, effort accelerate realisation distributed

Language: Английский

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Advancing CO₂ Conversion with Cu‐LDHs: A Review of Computational and Experimental Studies

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Abstract Layered Double Hydroxides (LDHs) are versatile materials with tuneable properties. They show promising electro‐ and photo‐catalytic activity in the activation conversion of CO 2 . Their unique properties make LDHs pivotal emerging sustainable strategies for mitigating effect emissions. However, intricate structure‐property relationship inherent to challenges their rational design. In this review, we provide a comprehensive overview both experimental computational studies about photo‐ electro‐catalytic , mainly focusing on Cu‐based systems due superior performance producing C products. We present background framework, describing essentials tools, designed support experimentalists theoreticians development tailored LDH efficient valorisation. Finally, discuss future potential advancements, emphasizing importance new synergistic experimental‐computational studies.

Language: Английский

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Recent advances in the measurement of thermochemical, electrochemical and photochemical efficiency of CO2 conversion to value-added products - its challenges and future directions

Deleted Journal, Journal Year: 2025, Volume and Issue: unknown, P. 100049 - 100049

Published: April 1, 2025

Language: Английский

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Recent Progress and Future Perspectives of Ionic Liquid-Based Carbon Dioxide Capture and Conversion

Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 1, 2024

Language: Английский

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Addressing the Complexity of Bridging Thermal and Reactive Catalysis. The Role of Strong Localised Electrical Fields

Topics in Catalysis, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 3, 2025

Language: Английский

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Development of catalysts and reactor designs for CO₂ electroreduction towards C₂₊ products

Energy Materials, Journal Year: 2025, Volume and Issue: 5(5)

Published: Feb. 25, 2025

Recent research on the electrocatalytic CO2 reduction reaction (eCO2RR) has garnered significant attention given its capability to address environmental issues associated with emissions while harnessing clean energy produce high-value-added products. Compared C1 products, C2+ products provide greater densities and are highly sought after as chemical feedstocks. However, formation of C-C bond is challenging due competition H-H C-H bonds. Therefore, elevate selectivity yield fuels, it essential develop more advanced electrocatalysts optimize design electrochemical cell configurations. Of materials investigated for CO2RR, Cu-based stand out their wide availability, affordability, compatibility. Moreover, catalysts exhibit promising capabilities in adsorption activation, facilitating compounds via coupling. This review examines recent both cells electroreduction compounds, introducing core principles eCO2RR pathways involved generating A key focus categorization catalyst designs, including defect engineering, surface modification, nanostructure tandem catalysis. By analyzing studies catalysts, we aim elucidate mechanisms behind enhanced compounds. Additionally, various types electrolytic discussed. Lastly, prospects limitations utilizing highlighted future research.

Language: Английский

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Perspectives and Emerging Trends in Plasma Catalysis: Facing the Challenge of Chemical Production Electrification

ChemCatChem, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 23, 2025

Abstract Electrification of chemical production requires the development innovative solutions, with plasma catalysis being among them. This perspective summarizes many years studies and discussions made in frame ERC Synergy project SCOPE dedicated to above aspects. However, it does not aim overview results but rather use them combination literature indications outline emerging trends present gaps pass from a research area key technology develop sustainable associated changes required modalities production. The thus aims offer vision future for its role facing societal challenges.

Language: Английский

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