Photoredox/nickel dual-catalyzed deaminative cross-electrophile for allenylic alkylation with non-activated alkyl katritzky salts
Organic Chemistry Frontiers,
Год журнала:
2024,
Номер
11(20), С. 5685 - 5694
Опубликована: Янв. 1, 2024
The
first
allenylic
alkylation
with
non-activated
aliphatic
amine
derivatives,
Katritzky
salts,
has
been
developed
via
photoredox/nickel
dual-catalyzed
reductive
deaminative
cross-electrophile
coupling.
Язык: Английский
Photoreductive 1,4-Dicarbofunctionalization of 1,3-Enynes with Organoiodides and Cyanoarenes via Halogen-Atom Transfer
Liangfeng Yang,
Liang Zeng,
Yilin Liu
и другие.
Organic Letters,
Год журнала:
2024,
Номер
26(36), С. 7661 - 7666
Опубликована: Авг. 28, 2024
A
photoreductive
halogen-atom
transfer
(XAT)
strategy
for
1,4-dicarbofunctionalization
of
1,3-enynes
with
organoiodides
and
cyanoarenes
is
disclosed,
enabling
access
to
functionalized
allenes
in
a
highly
regio-,
chemo-,
stereoselective
manner.
Upon
the
photoredox
catalysis
activation
Et
Язык: Английский