Photoredox/nickel dual-catalyzed deaminative cross-electrophile for allenylic alkylation with non-activated alkyl katritzky salts
Zhao‐Zhao Zhou,
No information about this author
Xiaofeng Zhai,
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Ke-Jian Xia
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et al.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(20), P. 5685 - 5694
Published: Jan. 1, 2024
The
first
allenylic
alkylation
with
non-activated
aliphatic
amine
derivatives,
Katritzky
salts,
has
been
developed
via
photoredox/nickel
dual-catalyzed
reductive
deaminative
cross-electrophile
coupling.
Language: Английский
Photoreductive 1,4-Dicarbofunctionalization of 1,3-Enynes with Organoiodides and Cyanoarenes via Halogen-Atom Transfer
Liangfeng Yang,
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Liang Zeng,
No information about this author
Yilin Liu
No information about this author
et al.
Organic Letters,
Journal Year:
2024,
Volume and Issue:
26(36), P. 7661 - 7666
Published: Aug. 28, 2024
A
photoreductive
halogen-atom
transfer
(XAT)
strategy
for
1,4-dicarbofunctionalization
of
1,3-enynes
with
organoiodides
and
cyanoarenes
is
disclosed,
enabling
access
to
functionalized
allenes
in
a
highly
regio-,
chemo-,
stereoselective
manner.
Upon
the
photoredox
catalysis
activation
Et
Language: Английский