In
current
research,
achieving
carbon
neutrality
has
become
a
primary
focus
through
the
utilization
of
various
conversion
technologies
that
transform
dioxide
(CO
2
)
into
valuable
chemicals
or
fuels.
Covalent
organic
frameworks
(COFs),
as
emerging
crystalline
polymers,
offer
distinct
advantages
in
CO
compared
to
other
materials.
These
include
controllable
nanoscale
pores,
predefined
functional
units,
editable
framework
structures,
and
rich
conjugated
systems.
The
unique
characteristics
COFs
make
them
highly
promising
electrocatalysts
for
conversion.
This
review
provides
comprehensive
overview
pioneering
works
recent
research
on
COF‐based
materials
electrochemical
reduction
reaction.
offers
analysis
design
principles
reactive
sites,
skeleton
pore
functionalities,
3D
frameworks,
morphologies,
composite
COFs,
aiming
enhance
electrocatalysis.
Finally,
this
presents
some
recommendations
material
design,
reaction
mechanisms,
theoretical
computations
understanding
mechanisms
further
facilitate
high‐performance
electrocatalysts.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(15), С. 6307 - 6416
Опубликована: Янв. 1, 2022
This
review
highlights
the
recent
advances
of
metalated
covalent
organic
frameworks,
including
synthetic
strategies
and
applications,
discusses
current
challenges
future
directions.
Energy & Environmental Science,
Год журнала:
2023,
Номер
16(7), С. 2759 - 2803
Опубликована: Янв. 1, 2023
The
catalytic
transformation
of
CO
2
into
valuable
fuels/chemicals
is
a
promising
and
economically
profitable
process
because
it
offers
an
alternative
toward
fossil
feedstocks
the
benefit
transforming
cycling
on
scale-up.
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
10(13), С. 6835 - 6871
Опубликована: Янв. 1, 2022
A
comprehensive
review
about
the
recent
advances
of
single-atom
catalysts
for
photocatalytic
and
photoelectrochemical
water
splitting
is
presented
by
highlighting
distinctive
roles,
unique
fabrication
methods
specific
design
strategies.
Bioactive Materials,
Год журнала:
2022,
Номер
21, С. 358 - 380
Опубликована: Сен. 14, 2022
Nanomedicines
for
drug
delivery
and
imaging-guided
cancer
therapy
is
a
rapidly
growing
research
area.
The
unique
properties
of
nanomedicines
have
massive
potential
in
solving
longstanding
challenges
existing
drugs,
such
as
poor
localization
at
the
tumor
site,
high
doses
toxicity,
recurrence,
immune
response.
However,
inadequate
biocompatibility
restricts
their
clinical
translation.
Therefore,
advanced
nanomaterials
with
enhanced
therapeutic
efficiency
are
highly
desired
to
fast-track
translation
nanomedicines.
Intrinsic
nanoscale
covalent
organic
frameworks
(nCOFs),
suitable
size,
modular
pore
geometry
porosity,
straightforward
post-synthetic
modification
via
simple
transformations,
make
them
incredibly
attractive
future
ability
COFs
disintegrate
slightly
acidic
microenvironment
also
gives
competitive
advantage
targeted
delivery.
This
review
summarizes
recently
published
applications
delivery,
photo-immuno
therapy,
sonodynamic
photothermal
chemotherapy,
pyroptosis,
combination
therapy.
Herein
we
mainly
focused
on
modifications
enhance
biocompatibility,
efficacy
will
provide
fundamental
knowledge
designing
biocompatible
nCOFs-based
help
rapid
development
carriers
theranostics.
