Coordination-driven innovations in low-energy catalytic processes: Advancing sustainability in chemical production

Coordination Chemistry Reviews, Год журнала: 2024, Номер 514, С. 215900 - 215900

Опубликована: Май 8, 2024

Catalysis stands as a cornerstone in chemical synthesis, pivotal advancing sustainable manufacturing pathways. The evolution from energy-intensive to catalytic processes has marked transformative shift, notably exemplified by low-energy methods. These processes, operating under milder conditions and emphasizing selectivity recyclability, represent the forefront of chemistry. This review navigates through an array reactions, highlighting their diverse applications culminating exploration recent strides within processes. For example, explores uses such enzyme mimicking, biodiesel production, carbon dioxide capture, organic synthesis. Additionally, it covers enzymatic catalysis photocatalysis for transformations, energy applications, water treatment. Notably, emphasizes capabilities single-atom (SAC) diatomic catalysts (DACs), recognizing exceptional performance catalyzing reactions at minimal activation energies while maintaining high efficiency mild conditions. By elucidating modulation electronic structure offering microelectronic perspective, aims elucidate mechanisms underlying activity SAC DACs. Emphasizing interplay between coordination chemistry principles efficacy, elucidates indispensable role complexes fortifying sustainability these spotlighting fusion with catalysis, this underscore collective influence shaping landscape production.

Язык: Английский

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A Janus dual-atom catalyst for electrocatalytic oxygen reduction and evolution

Nature Synthesis, Год журнала: 2024, Номер 3(7), С. 878 - 890

Опубликована: Июнь 3, 2024

Язык: Английский

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Optimization strategies of high-entropy alloys for electrocatalytic applications

Chemical Science, Год журнала: 2023, Номер 14(45), С. 12850 - 12868

Опубликована: Янв. 1, 2023

This review summarizes the synthesis methods, characterization research progress and regulation strategies of HAEs in field electrocatalytic HER, HOR, OER, ORR, CO 2 RR, NRR AOR, providing deep understanding for future applications.

Язык: Английский

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Ru/Ir‐Based Electrocatalysts for Oxygen Evolution Reaction in Acidic Conditions: From Mechanisms, Optimizations to Challenges

Advanced Science, Год журнала: 2024, Номер 11(21)

Опубликована: Март 19, 2024

Abstract The generation of green hydrogen by water splitting is identified as a key strategic energy technology, and proton exchange membrane electrolysis (PEMWE) one the desirable technologies for converting renewable sources into hydrogen. However, harsh anode environment PEMWE oxygen evolution reaction (OER) involving four‐electron transfer result in large overpotential, which limits overall efficiency production, thus efficient electrocatalysts are needed to overcome high overpotential slow kinetic process. In recent years, noble metal‐based (e.g., Ru/Ir‐based metal/oxide electrocatalysts) have received much attention due their unique catalytic properties, already become dominant acidic OER process applied commercial devices. these still face thorny problem conflicting performance cost. this review, first, metal briefly classified according forms existence, mechanisms outlined. Then, focus on summarizing improvement strategies with respect activity stability over years. Finally, challenges development prospects discussed.

Язык: Английский

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Structural engineering of atomic catalysts for electrocatalysis

Chemical Science, Год журнала: 2024, Номер 15(14), С. 5082 - 5112

Опубликована: Янв. 1, 2024

This review systematically introduces how to regulate the electronic structure and geometric configuration of atomic catalysts achieve high-efficiency electrocatalysis performances by analyzing detailed electrocatalytic applications mechanisms.

Язык: Английский

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Structural regulation of covalent organic frameworks for advanced electrocatalysis

Nano Energy, Год журнала: 2023, Номер 120, С. 109155 - 109155

Опубликована: Дек. 2, 2023

Язык: Английский

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Advances and challenges in the electrochemical reduction of carbon dioxide

Chemical Science, Год журнала: 2024, Номер 15(21), С. 7870 - 7907

Опубликована: Янв. 1, 2024

This review highlights the structure–activity relationship of ECO 2 RR, provides a detailed summary advanced materials by analyzing electrocatalytic applications and reaction mechanisms, discusses challenges in both devices.

Язык: Английский

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Dual and Triple Atom Electrocatalysts for Energy Conversion (CO₂RR, NRR, ORR, OER, and HER): Synthesis, Characterization, and Activity Evaluation

ACS Catalysis, Год журнала: 2024, Номер 14(2), С. 1121 - 1145

Опубликована: Янв. 8, 2024

Dual and triple atom catalysts (DACs TACs) are an emerging field of heterogeneous catalysis research. They share properties with single (SACs), such as maximizing dispersion metals the ability to circumvent traditional scaling relations that limit extended surfaces. DACs TACs additionally provide adjacent sites necessary for certain reaction mechanisms add tunability electronic structure binding energies. are, however, inherently difficult selectively synthesize characterize. Characterization activity evaluation prone misinterpretation, adding confusion already complex field. In this review, we investigate current progress important electrochemical reactions in energy conversion storage. We further discuss future synthesis methods focus on common pitfalls characterization evaluation.

Язык: Английский

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Electrochemistry of 2D-materials for the remediation of environmental pollutants and alternative energy storage/conversion materials and devices, a comprehensive review

Sustainable materials and technologies, Год журнала: 2024, Номер 40, С. e00963 - e00963

Опубликована: Май 8, 2024

Язык: Английский

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Cutting-edge advancements in MXene-derived materials: Revolutionary electrocatalysts for hydrogen evolution and high-performance energy storage

Coordination Chemistry Reviews, Год журнала: 2024, Номер 506, С. 215722 - 215722

Опубликована: Фев. 16, 2024

Язык: Английский

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