MXenes and CO2: A pioneering journey towards sustainable electrochemical reduction DOI

Maham Tariq,

Zeshan Ali Sandhu,

Afifa Tariq

и другие.

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 96, С. 1281 - 1298

Опубликована: Ноя. 30, 2024

Язык: Английский

Electrochemical Oxidation of Small Molecules for Energy‐Saving Hydrogen Production DOI
Hainan Sun, Xiaomin Xu, Liangshuang Fei

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер 14(30)

Опубликована: Май 27, 2024

Abstract Electrochemical water splitting is a promising technique for the production of high‐purity hydrogen. Substituting slow anodic oxygen evolution reaction with an oxidation that thermodynamically more favorable enables energy‐efficient Moreover, this approach facilitates degradation environmental pollutants and synthesis value‐added chemicals through rational selection small molecules as substrates. Strategies small‐molecule electrocatalyst design are critical to electrocatalytic performance, focus on achieving high current density, selectivity, Faradaic efficiency, operational durability. This perspective discusses key factors required further advancement, including technoeconomic analysis, new reactor system design, meeting requirements industrial applications, bridging gap between fundamental research practical product detection separation. aims advance development hybrid electrolysis applications.

Язык: Английский

Процитировано

43

Interfacial coordination bonds accelerate charge separation for unprecedented hydrogen evolution over S-scheme heterojunction DOI
Chunxue Li, Hao Lü,

Guixiang Ding

и другие.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2024, Номер 65, С. 174 - 184

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

21

Polyoxometalate chemistry of {M[P4Mo6]2}: From structure assembly to functional application DOI

Hao‐Xue Bi,

Meng-Si Guo,

Jing Du

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 518, С. 216092 - 216092

Опубликована: Июль 26, 2024

Язык: Английский

Процитировано

16

Array of Manganese-Based Bimetallic Metal–Organic-Framework Nanozymes with Enhanced Oxidase-like Catalytic Activity Can Simultaneously Identify and Measure Antioxidants DOI

Oldouz Heidary,

Hossein Ashrafi, Morteza Akhond

и другие.

Analytical Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Фев. 26, 2025

Developing sensitive and highly active nanozymes for antioxidant analysis is of the utmost significance in medical diagnosis health monitoring due to their essential roles as free reactive oxygen species scavengers. Here, six metal-organic frameworks (MOFs)-based are developed a dual-mode absorbance/image colorimetric sensor array simultaneous discrimination determination various antioxidants with comparable structural or chemical properties. The catalysts exhibit wide range potent oxidase-like catalytic activities, verified by kinetic parameters, presence dispersed transition metallic bimetallic redox nodes. These efficiently catalyze oxidation colorless 3,3',5,5'-tetramethylbenzidine (TMB) blue TMBox, resulting noticeable absorption RGB color changes at 650 nm. Various demonstrate different reducing capabilities leading generation fingerprint-like spectral patterns. pattern recognition chemometrics methods including principal component (PCA) linear discriminant (LDA) represent well-separated clustering ascorbic acid, dopamine, uric cysteine, glutathione, thiocyanate, tannic gallic acid. assay provides detection (0.1-75 μM) limits low 30 nM. successfully discriminated concentrations, mixtures, interferences. Furthermore, sensor's applicability biologically relevant was validated urine plasma samples. Overall, MOF-based nanozyme offers promising platform discriminating determining potential applications.

Язык: Английский

Процитировано

1

Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction DOI Creative Commons
Chao Li,

Hong Yan,

Hanlu Yang

и другие.

Science China Materials, Год журнала: 2024, Номер 68(1), С. 21 - 38

Опубликована: Ноя. 8, 2024

Abstract The conversion of carbon dioxide (CO 2 ) to the reduced chemical compounds offers substantial environmental benefits through minimizing emission greenhouse gas and fostering sustainable practices. Recently, unique properties metal-organic frameworks (MOFs) make them attractive candidates for electrocatalytic CO reduction reaction RR), providing many opportunities develop efficient, selective, environmentally processes mitigating emissions utilizing as a valuable raw material synthesis fuels chemicals. Here, recent advances in MOFs efficient catalysts RR are summarized. detailed characteristics, mechanisms, practical approaches improving efficiency, selectivity, durability under realistic conditions also clarified. Furthermore, outlooks on prospects MOF-based electrocatalysts provided.

Язык: Английский

Процитировано

8

A review on catalyst convergence: Unleashing the potential of MXenes for CO2 electrochemical reduction into high-value liquid product DOI Creative Commons

Samia,

Muhammad Hasnain Jameel,

Musfira Arain

и другие.

Nano Materials Science, Год журнала: 2024, Номер unknown

Опубликована: Июль 1, 2024

The electrochemical reduction reaction of carbon dioxide (CO2-ERR) holds tremendous potential as a key approach for achieving neutrality by harnessing renewable resources. However, the current state CO2-ERR encounters challenges in terms efficiency and selectivity. Overcoming these obstacles requires development robust electrocatalyst capable enhancing process improving selectivity towards desired products. In recent years, 2D materials have garnered significant attention efficient catalysts. Among them, MXene stands out high interest due to unique multilayered structure presence surface functional moieties. material offers electrical conductivity, versatile chemistry, tunable interface designs. This comprehensive review explores utilization MXene-based catalysts into valuable It covers fundamental aspects conversion, including CO2 adsorption on Ti3C2Tx, mechanism (Mo2CS2) single-atom catalysts, applications, synthesis methods production, future prospects. Additionally, highlights significance modern artificial intelligence techniques, particularly machine learning, screening activating CO2, making it pioneering scientific endeavor.

Язык: Английский

Процитировано

7

Electrochemical Conversion of CO2 Using Metal-Organic Frameworks-Based Materials: A Review on Recent Progresses and Outlooks DOI

R. Abd-El Aziz,

Suha Abad,

Sagheer A. Onaizi

и другие.

Chemosphere, Год журнала: 2024, Номер 365, С. 143312 - 143312

Опубликована: Сен. 10, 2024

Язык: Английский

Процитировано

7

Advances in methanol synthesis via MOF-based catalysts: A comprehensive review and critical analysis DOI

Ali Khatib Juma,

Zulkifli Merican Aljunid Merican, Abdurrashid Haruna

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114266 - 114266

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Design of electrocatalysts and electrodes for CO2 electroreduction to formic acid and formate DOI
Dinh Son Tran,

Nhu‐Nang Vu,

Houssam-Eddine Nemamcha

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 524, С. 216322 - 216322

Опубликована: Ноя. 12, 2024

Язык: Английский

Процитировано

6

Synergistic effect of CexOy and Zn ion within the ZIF-zni framework for enhanced electrocatalytic reduction of CO2 DOI
Mustapha Umar, Ismail Abdulazeez, Abdulkadir Tanimu

и другие.

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(3), С. 112899 - 112899

Опубликована: Апрель 25, 2024

Язык: Английский

Процитировано

4