MXenes and CO2: A pioneering journey towards sustainable electrochemical reduction DOI

Maham Tariq,

Zeshan Ali Sandhu,

Afifa Tariq

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 96, P. 1281 - 1298

Published: Nov. 30, 2024

Language: Английский

Electrochemical Oxidation of Small Molecules for Energy‐Saving Hydrogen Production DOI
Hainan Sun, Xiaomin Xu, Liangshuang Fei

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(30)

Published: May 27, 2024

Abstract Electrochemical water splitting is a promising technique for the production of high‐purity hydrogen. Substituting slow anodic oxygen evolution reaction with an oxidation that thermodynamically more favorable enables energy‐efficient Moreover, this approach facilitates degradation environmental pollutants and synthesis value‐added chemicals through rational selection small molecules as substrates. Strategies small‐molecule electrocatalyst design are critical to electrocatalytic performance, focus on achieving high current density, selectivity, Faradaic efficiency, operational durability. This perspective discusses key factors required further advancement, including technoeconomic analysis, new reactor system design, meeting requirements industrial applications, bridging gap between fundamental research practical product detection separation. aims advance development hybrid electrolysis applications.

Language: Английский

Citations

41
Interfacial coordination bonds accelerate charge separation for unprecedented hydrogen evolution over S-scheme heterojunction DOI
Chunxue Li, Hao Lü,

Guixiang Ding

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 65, P. 174 - 184

Published: Oct. 1, 2024

Language: Английский

Citations

18
Polyoxometalate chemistry of {M[P4Mo6]2}: From structure assembly to functional application DOI

Hao‐Xue Bi,

Meng-Si Guo,

Jing Du

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216092 - 216092

Published: July 26, 2024

Language: Английский

Citations

10
A review on catalyst convergence: Unleashing the potential of MXenes for CO2 electrochemical reduction into high-value liquid product DOI Creative Commons

Samia,

Muhammad Hasnain Jameel,

Musfira Arain

et al.

Nano Materials Science, Journal Year: 2024, Volume and Issue: unknown

Published: July 1, 2024

The electrochemical reduction reaction of carbon dioxide (CO2-ERR) holds tremendous potential as a key approach for achieving neutrality by harnessing renewable resources. However, the current state CO2-ERR encounters challenges in terms efficiency and selectivity. Overcoming these obstacles requires development robust electrocatalyst capable enhancing process improving selectivity towards desired products. In recent years, 2D materials have garnered significant attention efficient catalysts. Among them, MXene stands out high interest due to unique multilayered structure presence surface functional moieties. material offers electrical conductivity, versatile chemistry, tunable interface designs. This comprehensive review explores utilization MXene-based catalysts into valuable It covers fundamental aspects conversion, including CO2 adsorption on Ti3C2Tx, mechanism (Mo2CS2) single-atom catalysts, applications, synthesis methods production, future prospects. Additionally, highlights significance modern artificial intelligence techniques, particularly machine learning, screening activating CO2, making it pioneering scientific endeavor.

Language: Английский

Citations

7
Electrochemical Conversion of CO2 Using Metal-Organic Frameworks-Based Materials: A Review on Recent Progresses and Outlooks DOI

R. Abd-El Aziz,

Suha Abad,

Sagheer A. Onaizi

et al.

Chemosphere, Journal Year: 2024, Volume and Issue: 365, P. 143312 - 143312

Published: Sept. 10, 2024

Language: Английский

Citations

7
Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction DOI Creative Commons
Chao Li,

Hong Yan,

Hanlu Yang

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: 68(1), P. 21 - 38

Published: Nov. 8, 2024

Abstract The conversion of carbon dioxide (CO 2 ) to the reduced chemical compounds offers substantial environmental benefits through minimizing emission greenhouse gas and fostering sustainable practices. Recently, unique properties metal-organic frameworks (MOFs) make them attractive candidates for electrocatalytic CO reduction reaction RR), providing many opportunities develop efficient, selective, environmentally processes mitigating emissions utilizing as a valuable raw material synthesis fuels chemicals. Here, recent advances in MOFs efficient catalysts RR are summarized. detailed characteristics, mechanisms, practical approaches improving efficiency, selectivity, durability under realistic conditions also clarified. Furthermore, outlooks on prospects MOF-based electrocatalysts provided.

Language: Английский

Citations

7
Synergistic effect of CexOy and Zn ion within the ZIF-zni framework for enhanced electrocatalytic reduction of CO2 DOI
Mustapha Umar, Ismail Abdulazeez, Abdulkadir Tanimu

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112899 - 112899

Published: April 25, 2024

Language: Английский

Citations

4
Design of electrocatalysts and electrodes for CO2 electroreduction to formic acid and formate DOI
Dinh Son Tran,

Nhu‐Nang Vu,

Houssam-Eddine Nemamcha

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 524, P. 216322 - 216322

Published: Nov. 12, 2024

Language: Английский

Citations

4
Self-supporting nickel single atom catalyst derived from nickel metal organic framework for efficient electrocatalysis of CO2 DOI
Jiale Sun, Haihui Zhou,

Junwei Xu

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 178780 - 178780

Published: Jan. 1, 2025

Language: Английский

Citations

0
Array of Manganese-Based Bimetallic Metal–Organic-Framework Nanozymes with Enhanced Oxidase-like Catalytic Activity Can Simultaneously Identify and Measure Antioxidants DOI

Oldouz Heidary,

Hossein Ashrafi, Morteza Akhond

et al.

Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 26, 2025

Developing sensitive and highly active nanozymes for antioxidant analysis is of the utmost significance in medical diagnosis health monitoring due to their essential roles as free reactive oxygen species scavengers. Here, six metal-organic frameworks (MOFs)-based are developed a dual-mode absorbance/image colorimetric sensor array simultaneous discrimination determination various antioxidants with comparable structural or chemical properties. The catalysts exhibit wide range potent oxidase-like catalytic activities, verified by kinetic parameters, presence dispersed transition metallic bimetallic redox nodes. These efficiently catalyze oxidation colorless 3,3',5,5'-tetramethylbenzidine (TMB) blue TMBox, resulting noticeable absorption RGB color changes at 650 nm. Various demonstrate different reducing capabilities leading generation fingerprint-like spectral patterns. pattern recognition chemometrics methods including principal component (PCA) linear discriminant (LDA) represent well-separated clustering ascorbic acid, dopamine, uric cysteine, glutathione, thiocyanate, tannic gallic acid. assay provides detection (0.1-75 μM) limits low 30 nM. successfully discriminated concentrations, mixtures, interferences. Furthermore, sensor's applicability biologically relevant was validated urine plasma samples. Overall, MOF-based nanozyme offers promising platform discriminating determining potential applications.

Language: Английский

Citations

0