Inorganic Chemistry,
Год журнала:
2023,
Номер
62(3), С. 1240 - 1249
Опубликована: Янв. 11, 2023
Photocatalytic
reduction
of
CO2
to
value-added
chemicals
is
known
be
a
promising
approach
for
conversion.
The
design
and
preparation
ideal
photocatalysts
conversion
are
pivotal
significance
the
sustainable
development
whole
society.
In
this
work,
we
integrated
two
functional
organic
linkers
prepare
novel
metal
framework
(MOF)
photocatalyst
{[Co(9,10-bis(4-pyridyl)anthracene)0.5(bpda)]·4DMF}
(Co-MOF).
existence
anthryl
amino
groups
leads
wide
range
visible
light
absorption
efficient
separation
photogenerated
electrons.
To
extend
lifetime
electrons
in
photocatalytic
system,
modified
Co-MOF
particles
onto
g-C3N4.
As
expected,
Co-MOF/g-C3N4
composites
exhibited
an
ultrahigh
selectivity
(more
than
97%)
process,
highest
CO
production
rate
(1824
μmol/g/h)
was
7.1
27.2
times
Co-MOFs
g-C3N4,
respectively.
What's
more,
also
discussed
reaction
mechanism
reduction,
work
paves
pathway
designing
with
performance.
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(18), С. 9378 - 9418
Опубликована: Янв. 1, 2024
Organic
transformation
by
light-driven
catalysis,
especially,
photocatalysis
and
photothermal
denoted
as
photo(thermal)
is
an
efficient,
green,
economical
route
to
produce
value-added
compounds.
In
recent
years,
owing
their
diverse
structure
types,
tunable
pore
sizes,
abundant
active
sites,
metal-organic
framework
(MOF)-based
catalysis
has
attracted
broad
interest
in
organic
transformations.
this
review,
we
provide
a
comprehensive
systematic
overview
of
MOF-based
for
First,
the
general
mechanisms,
unique
advantages,
strategies
improve
performance
MOFs
are
discussed.
Then,
outstanding
examples
transformations
over
introduced
according
reaction
type.
addition,
several
representative
advanced
characterization
techniques
used
revealing
charge
kinetics
intermediates
presented.
Finally,
prospects
challenges
field
proposed.
This
review
aims
inspire
rational
design
development
materials
with
improved
catalysis.
