Mn-based catalysts derived from the non-thermal treatment of Mn-MIL-100 to enhance its water-resistance for toluene oxidation: Mechanism study

Chemical Engineering Journal, Год журнала: 2024, Номер 485, С. 149776 - 149776

Опубликована: Фев. 18, 2024

Язык: Английский

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Progress of catalytic oxidation of VOCs by manganese-based catalysts

Fuel, Год журнала: 2024, Номер 366, С. 131305 - 131305

Опубликована: Март 11, 2024

Язык: Английский

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Nickel foam based monolithic catalyst supporting transition metal oxides for toluene combustion: Experimental and theoretical study of interfacial synergistic oxidation and water resistance

Chemical Engineering Journal, Год журнала: 2024, Номер 483, С. 149176 - 149176

Опубликована: Янв. 29, 2024

Язык: Английский

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Regulating surface properties of Co3O4@MnO2 catalysts through Co3O4-MnO2 interfacial effects for efficient toluene catalytic oxidation

Separation and Purification Technology, Год журнала: 2024, Номер 352, С. 128221 - 128221

Опубликована: Май 31, 2024

Язык: Английский

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Recent Advances of the Effect of H₂O on VOC Oxidation over Catalysts: Influencing Factors, Inhibition/Promotion Mechanisms, and Water Resistance Strategies

Environmental Science & Technology, Год журнала: 2025, Номер 59(2), С. 1034 - 1059

Опубликована: Янв. 6, 2025

Water vapor is a significant component in real volatile organic compounds (VOCs) exhaust gas and has considerable impact on the catalytic performance of catalysts for VOC oxidation. Important progress been made reaction mechanisms H2O water resistance strategies oxidation recent years. Despite advancements technology, most still exhibit low activity under humid conditions, presenting challenge reducing adverse effects To develop water-resistant catalysts, understanding mechanistic role implementing effective water-resistance with influencing factors are imperative. This Perspective systematically summarizes related research oxidation, drawing from over 390 papers published between 2013 2024. Five main proposed to clarify their H2O. inhibition/promotion introduced, elucidating various VOCs. Additionally, different kinds discussed, including fabrication hydrophobic materials, design specific structures morphologies, introduction additional elements catalyst modification. Finally, scientific challenges opportunities enhancing efficient practical applications purification highlighted.

Язык: Английский

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In-situ fabrication of MOF-derived MnO-C modified graphite felt for electro-activation of peroxymonosulfate toward degradation of tetracycline: Performance, mechanism and degradation pathway

Separation and Purification Technology, Год журнала: 2024, Номер 342, С. 126766 - 126766

Опубликована: Март 1, 2024

Язык: Английский

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Lead-free perovskite Cs3Bi2Br9 quantum dots (QDs)/ultra-thin W18O49 nanobelts S-scheme heterojunction toward optimized photocatalytic CO2 reduction coupled with toluene oxidation

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159635 - 159635

Опубликована: Янв. 1, 2025

Язык: Английский

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Local Electron Environment Regulation of Spinel CoMn₂O₄ Induced Effective Reactant Adsorption and Transformation of Lattice Oxygen for Toluene Oxidation

Environmental Science & Technology, Год журнала: 2023, Номер 57(51), С. 21888 - 21897

Опубликована: Дек. 11, 2023

In contrast to numerous studies on oxygen species, the interaction of volatile organic compounds (VOCs) with oxides is also critical catalytic reaction but has hardly been considered. Herein, we develop a highly efficient Pt atom doped spinel CoMn2O4 (Pt-CoMn) for oxidation toluene at low temperature, and conversion rate increased by 18.3 times (129.7 versus 7.1 × 10–11 mol/(m2·s)) 160 °C compared that CoMn2O4. Detailed characterizations density functional theory calculations reveal local electron environment Co sites changed after doping, formed electron-deficient in turn strengthen toluene. Adsorbed will react lattice Pt-CoMn CoMn catalysts convert into benzoate intermediates, consumption closely related activation gaseous oxygen. Significantly, abundant bulk defects help open channel spinel, which acts as an pump promote transformation surface lower temperatures, thus accelerating intermediates CO2 enhancing low-temperature combustion developed here emphasizes regulation VOCs adsorption strength processes adjusting environment, provide new guidance design oxide oxidation.

Язык: Английский

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Regulating asymmetric oxygen vacancies in copper-ceria catalysts for achievement of excellent toluene catalytic oxidation

Separation and Purification Technology, Год журнала: 2023, Номер 334, С. 126035 - 126035

Опубликована: Дек. 14, 2023

Язык: Английский

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Recent advances in the catalytic oxidation of toluene on Mn-based catalysts

Catalysis Reviews, Год журнала: 2024, Номер unknown, С. 1 - 71

Опубликована: Фев. 12, 2024

Toluene, which is one of the typical volatile organic compounds (VOCs), can pose a serious threat to environment and human health. Catalytic oxidation technology regarded as highly efficient method for removal toluene. This article reviews recent advances catalytic toluene on Mn-based catalysts. The reaction mechanism has been summarized first. Then structure performance different catalysts have systematically described discussed. In particular, defect engineering fabricate active introduced. Finally, current scientific issues perspectives in future research are put forward. Hopefully, this comprehensive review shed light design more promote their practical application.

Язык: Английский

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