Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 105751 - 105751
Опубликована: Янв. 1, 2025
Язык: Английский
Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 105751 - 105751
Опубликована: Янв. 1, 2025
Язык: Английский
Chemosphere, Год журнала: 2024, Номер 351, С. 141255 - 141255
Опубликована: Янв. 18, 2024
Язык: Английский
Процитировано
52Chemical Engineering Journal, Год журнала: 2024, Номер 481, С. 148789 - 148789
Опубликована: Янв. 18, 2024
Язык: Английский
Процитировано
32Chemical Engineering Journal, Год журнала: 2024, Номер 483, С. 149194 - 149194
Опубликована: Янв. 29, 2024
Язык: Английский
Процитировано
21Environmental Science & Technology Letters, Год журнала: 2024, Номер 11(4), С. 370 - 375
Опубликована: Март 14, 2024
Limited by the detection techniques, reactive species involved in catalytic water purification processes are difficult to be clarified. Spin-trapping electron paramagnetic resonance (EPR) analysis is recognized as a reliable tool for radical identification, which 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) usually used trapper. However, it questioned that of adducts DMPO definitively indicates generation radicals. In this work, transformation caused transition metal oxides monitored EPR, and abundant spin signals observed. MnO2, Mn2O3, NiO could oxidize into DMPOX through direct oxygen transfer. Besides, dissolved ions transform misleading DMPO–OH DMPO–R. The findings e.g., interactions between different quenching behavior pathways, would help with identifications both engineered systems natural environments.
Язык: Английский
Процитировано
21Water Research, Год журнала: 2024, Номер 253, С. 121259 - 121259
Опубликована: Фев. 5, 2024
Язык: Английский
Процитировано
19Chemosphere, Год журнала: 2024, Номер 354, С. 141582 - 141582
Опубликована: Март 8, 2024
Язык: Английский
Процитировано
16Chemical Engineering Journal, Год журнала: 2023, Номер 474, С. 145600 - 145600
Опубликована: Авг. 26, 2023
Язык: Английский
Процитировано
31Environmental Pollution, Год журнала: 2023, Номер 339, С. 122753 - 122753
Опубликована: Окт. 16, 2023
Язык: Английский
Процитировано
26Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(5), С. 113369 - 113369
Опубликована: Июнь 19, 2024
Язык: Английский
Процитировано
14Environmental Science & Technology, Год журнала: 2024, Номер 58(42), С. 18496 - 18507
Опубликована: Окт. 9, 2024
Advanced oxidation processes (AOPs) are rapidly evolving but still lack well-established protocols for reliably identifying oxidative reactive species (ORSs). This Perspective presents both the radical and nonradical ORSs that have been identified or proposed, along with extensive controversies surrounding mechanisms. Conventional identification tools, such as quenchers, probes, spin trappers, might be inadequate analytical demands of systems in which multiple coexist, often yielding misleading results. Therefore, challenges these complex, short-lived, transient must fully acknowledged. Refining methods is necessary, supported by rigorous experiments innovative paradigms, particularly through kinetic analysis based on situ spectroscopic techniques multiple-probe strategies. To demystify complex ORSs, future efforts should made to develop advanced tools strategies enhance mechanism understanding. In addition, integrating real-world conditions into experimental designs will establish a reliable framework fundamental studies, providing more accurate insights effectively guiding design AOPs.
Язык: Английский
Процитировано
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