Ni(II)-MOF based hypersensitive dual-function luminescent sensor towards 3-nitrotyrosine biomarker and 6-Propyl-2-thiouracil antithyroid drug in Urine

Journal of Materials Chemistry B, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Luminescent NiMOF demonstrated remarkable capabilities in efficient, sensitive and intelligent detection of 3-NT biomarker 6-PTU thyroid drug urine through luminescence quenching effects.

Язык: Английский

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Nitrogen-Rich Barium–Organic Framework for Capture and Cocatalysts Free Chemical Fixation of CO₂ via Cyclic Carbonates and Oxazolidinones

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Янв. 17, 2025

The carbon dioxide (CO2) capture and utilization strategy has emerged as an innovative multifaceted approach to counteract emissions. In this study, a highly porous muffin polyhedral barium (Ba) ̵ organic framework (BaTATB; H3TATB = 4,4',4″-s-triazine-2,4,6-triyl-tribenzoic acid) was synthesized solvothermally. three-dimensional honeycomb pore architectures were densely populated with Lewis acidic Ba(II) metal sites basic nitrogen-rich triazines. BaTATB demonstrated selective CO2 adsorption high heat of adsorption. Its abundance (Ba clusters) (triazine) makes ideal catalyst for the cycloaddition epoxides in two- three-component reactions. Furthermore, is exceptional recyclable aromatic amines, enabling high-yield synthesis cyclic carbonates oxazolidinone at 1 bar under moderate, solvent-free, cocatalyst-free conditions. Additionally, recycled nine seven consecutive cycles carbonate no substantial decrease catalytic activity. Using density functional theory, we rational design metal-organic frameworks that exhibit excellent conversion.

Язык: Английский

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Eu(III) encapsulation strategy to construct intelligent ratiometric luminescent sensor for efficient detection of phenylglyoxylic acid biomarker in bodily fluids

Microchemical Journal, Год журнала: 2024, Номер 207, С. 112127 - 112127

Опубликована: Ноя. 7, 2024

Язык: Английский

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NH2-Functionalized InIIIDyIII−Organic Frameworks for Efficient Catalytic Performance on Chemical Fixation of CO2 and Knoevenagel Condensation

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141361 - 141361

Опубликована: Янв. 1, 2025

Язык: Английский

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Reconfiguration of Electrostatic Interactions within an Ultramicroporous Metal–Organic Framework Enables CO₂ Separation

ACS Materials Letters, Год журнала: 2025, Номер unknown, С. 1242 - 1249

Опубликована: Март 4, 2025

Язык: Английский

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One-Step Eco-Friendly and Ultrasonic Fabrication of Bimetallic Co/Ni-MOF for Improved Efficiency in Overall Water Splitting

Journal of Molecular Structure, Год журнала: 2025, Номер 1329, С. 141379 - 141379

Опубликована: Янв. 9, 2025

Язык: Английский

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Crystal Transformation Synthesis of a Three-Dimensional Dual-Fold Building Block Derived from Metal–Organic Framework for Tetracycline Detection

ACS Omega, Год журнала: 2025, Номер unknown

Опубликована: Янв. 11, 2025

Metal-organic framework (MOF)-based sensors, which have garnered considerable focus for their potential to enhance environmental monitoring and improve water quality by accurately consistently identifying antibiotic compounds in water, gained interest. With the help of pH value, an unusual instance single-crystal-to-single-crystal (SCSC) transition from three-dimensional (3D) Zn-framework {[Zn2(mbix)2(2,5-bda)2]·H2O} n (1) 3D 2-fold {[Zn4(mbix)4(2,5-bda)4]·H2O} (2) has been observed under mild conditions. This transformation necessitates replication structure 1 while simultaneously modifying angle between planes imidazole benzene rings. It is noteworthy that detection capabilities 2 tetracyclines (TC) surpass those other analytes water. Furthermore, sensing results are close consistency with S-V model when TC concentrations fall within range 0-0.08 mM. Additionally, limit (LOD) sensor toward estimated be 0.59 nM. The stronger quenching impact seen can linked a more significant overlap energy transfer process. aforementioned proposition presents viable strategy systematic fabrication economically luminescent thereby enabling efficient cost-effective modifications properties.

Язык: Английский

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Rational design of amino-functionalized pillar-layered Co6O6 cluster MOF for gas purification in the MTO process

Separation and Purification Technology, Год журнала: 2025, Номер 361, С. 131644 - 131644

Опубликована: Янв. 15, 2025

Язык: Английский

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One new MOF with hierarchical pores achieving efficient one-step purifying C2H2, recycling CH4 and eliminating CO2 in C2H2 production

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159641 - 159641

Опубликована: Янв. 1, 2025

Язык: Английский

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Fluorescent Polymer Nanoparticles for Targeted Drug Delivery and Synergistic Osteosarcoma Therapy

Journal of the Indian Chemical Society, Год журнала: 2025, Номер unknown, С. 101660 - 101660

Опубликована: Март 1, 2025

Язык: Английский

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