Breaking new grounds: metal salts based-deep eutectic solvents and their applications- a comprehensive review

Green Chemistry, Год журнала: 2024, Номер 26(5), С. 2421 - 2453

Опубликована: Янв. 1, 2024

Metal salt-based deep eutectic solvents (MSDESs) have recently developed a torrent of leading-edge applications in endless areas chemistry.

Язык: Английский

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In silico COSMO-RS screening and experimental validation of metal chloride functionalized ionic liquids as dual-functional catalysts and solvents for H2S conversion to elemental sulfur

Journal of Molecular Liquids, Год журнала: 2025, Номер unknown, С. 127002 - 127002

Опубликована: Янв. 1, 2025

Язык: Английский

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The multiple enhancements of deep eutectic solvent on cellulase significantly improve the saccharification efficiency of lignocellulosic biomass

Chemical Engineering Journal, Год журнала: 2024, Номер 489, С. 151439 - 151439

Опубликована: Апрель 18, 2024

Язык: Английский

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Perspectives for the use of deep eutectic solvents in the preparation of electrochemical sensors and biosensors

Current Opinion in Electrochemistry, Год журнала: 2024, Номер 45, С. 101465 - 101465

Опубликована: Фев. 24, 2024

This review concerns deep eutectic solvents (DES) and how they can be exploited in the preparation of new improved electrochemical sensing platforms. Some relevant properties DES are described, with a brief description range applications recent advances concerning coatings materials prepared DES. Their use modified-electrode sensors biosensors publications is then addressed, particularly regarding electroactive redox polymer-modified electrodes, together nanomaterials, including employing ternary to increase sensitivity. Future perspectives indicated.

Язык: Английский

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Sensing applications of graphitic carbon nitride (g-C3N4) for sensing SO2 and SO3 – A DFT study

Physica B Condensed Matter, Год журнала: 2024, Номер 676, С. 415661 - 415661

Опубликована: Янв. 2, 2024

Язык: Английский

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Significance of anchoring group design on light harvesting efficiency of dye-sensitized solar cells and non-linear optical response

Journal of Molecular Structure, Год журнала: 2023, Номер 1294, С. 136435 - 136435

Опубликована: Авг. 16, 2023

Язык: Английский

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Study on Cu(II) extraction process optimization and mechanism from acidic leaching solution using the deep eutectic solvent P507/Menthol

Journal of Molecular Liquids, Год журнала: 2024, Номер 396, С. 123968 - 123968

Опубликована: Янв. 7, 2024

Язык: Английский

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Computational insights into deep eutectic solvent design: Modeling interactions and thermodynamic feasibility using choline chloride & glycerol

Chemical Engineering Journal Advances, Год журнала: 2023, Номер 16, С. 100564 - 100564

Опубликована: Сен. 29, 2023

To address climate change and environmental concerns, the chemical process industries are increasingly adopting green technology exploring eco-friendly waste management practices. Deep Eutectic Solvents (DES) have emerged as promising solvents with diverse applications in separation processes, catalysis, drug design, a lot more. However, ideal way for modeling ionic interactions within hydrogen-bond acceptor (HBA) during DES synthesis remains uncertain, theoretical insight on formation mechanism of energetically stable DESs from choline chloride (CHL) urea (URE) is yet to be explored. In this study, we investigate different approaches (no bond, generic or single bond) molecules thermodynamic feasibility forming an using through calculations (PM3, HF, DFT). Our findings indicate that choice approach does not significantly affect outcomes across calculation levels. The H-X pathway emerges most viable route CHL: GLC synthesis, offering strong binding energy high exothermicity. This provides robust solution synthesizing potential various industries. Researchers can consider alternative levels when DFT becomes cost-prohibitive optimize computational costs. study contributes valuable insights into design promoting environmentally sustainable cost-effective processes.

Язык: Английский

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Efficient and clean treatment of indium-bearing zinc ferrite: A new approach using a water-regulated deep eutectic solvent

Separation and Purification Technology, Год журнала: 2024, Номер 347, С. 127576 - 127576

Опубликована: Апрель 18, 2024

Язык: Английский

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Deep Eutectic Solvent extraction and biological activity of polysaccharides from Tenebrio molitor

Heliyon, Год журнала: 2025, Номер 11(2), С. e41790 - e41790

Опубликована: Янв. 1, 2025

This study aimed to extract polysaccharides from Tenebrio molitor using ultrasound-assisted deep eutectic solvent (DESs) and evaluate their structural features, as well antimicrobial, antioxidant, α-amylase inhibitory activities. Various DESs were tested for extraction, the process was optimized response surface methodology (RSM). A preliminary analysis of conducted infrared spectrum. The characterized by measuring pH, viscosity, conductivity, refractive index, density. optimal extraction agent parameters determined. Significant differences in conductivity observed among DESs, whereas index density not significant. Choline chloride-lactic acid identified agent. a DES molar ratio 1:2.1, water content 27 %, an temperature 70 °C, time 44 min, resulting yield 18.62 %. extracted exhibited strong effects against Salmonella, along with antioxidant activity demonstrated that can be efficiently showcasing significant biological activities, including antibacterial, properties. These findings highlight potential applications valuable resources.

Язык: Английский

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