Breaking new grounds: metal salts based-deep eutectic solvents and their applications- a comprehensive review

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(5), P. 2421 - 2453

Published: Jan. 1, 2024

Metal salt-based deep eutectic solvents (MSDESs) have recently developed a torrent of leading-edge applications in endless areas chemistry.

Language: Английский

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In silico COSMO-RS screening and experimental validation of metal chloride functionalized ionic liquids as dual-functional catalysts and solvents for H2S conversion to elemental sulfur

Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127002 - 127002

Published: Jan. 1, 2025

Language: Английский

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The multiple enhancements of deep eutectic solvent on cellulase significantly improve the saccharification efficiency of lignocellulosic biomass

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151439 - 151439

Published: April 18, 2024

Language: Английский

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Perspectives for the use of deep eutectic solvents in the preparation of electrochemical sensors and biosensors

Current Opinion in Electrochemistry, Journal Year: 2024, Volume and Issue: 45, P. 101465 - 101465

Published: Feb. 24, 2024

This review concerns deep eutectic solvents (DES) and how they can be exploited in the preparation of new improved electrochemical sensing platforms. Some relevant properties DES are described, with a brief description range applications recent advances concerning coatings materials prepared DES. Their use modified-electrode sensors biosensors publications is then addressed, particularly regarding electroactive redox polymer-modified electrodes, together nanomaterials, including employing ternary to increase sensitivity. Future perspectives indicated.

Language: Английский

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Sensing applications of graphitic carbon nitride (g-C3N4) for sensing SO2 and SO3 – A DFT study

Physica B Condensed Matter, Journal Year: 2024, Volume and Issue: 676, P. 415661 - 415661

Published: Jan. 2, 2024

Language: Английский

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Significance of anchoring group design on light harvesting efficiency of dye-sensitized solar cells and non-linear optical response

Journal of Molecular Structure, Journal Year: 2023, Volume and Issue: 1294, P. 136435 - 136435

Published: Aug. 16, 2023

Language: Английский

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Study on Cu(II) extraction process optimization and mechanism from acidic leaching solution using the deep eutectic solvent P507/Menthol

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 396, P. 123968 - 123968

Published: Jan. 7, 2024

Language: Английский

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Computational insights into deep eutectic solvent design: Modeling interactions and thermodynamic feasibility using choline chloride & glycerol

Chemical Engineering Journal Advances, Journal Year: 2023, Volume and Issue: 16, P. 100564 - 100564

Published: Sept. 29, 2023

To address climate change and environmental concerns, the chemical process industries are increasingly adopting green technology exploring eco-friendly waste management practices. Deep Eutectic Solvents (DES) have emerged as promising solvents with diverse applications in separation processes, catalysis, drug design, a lot more. However, ideal way for modeling ionic interactions within hydrogen-bond acceptor (HBA) during DES synthesis remains uncertain, theoretical insight on formation mechanism of energetically stable DESs from choline chloride (CHL) urea (URE) is yet to be explored. In this study, we investigate different approaches (no bond, generic or single bond) molecules thermodynamic feasibility forming an using through calculations (PM3, HF, DFT). Our findings indicate that choice approach does not significantly affect outcomes across calculation levels. The H-X pathway emerges most viable route CHL: GLC synthesis, offering strong binding energy high exothermicity. This provides robust solution synthesizing potential various industries. Researchers can consider alternative levels when DFT becomes cost-prohibitive optimize computational costs. study contributes valuable insights into design promoting environmentally sustainable cost-effective processes.

Language: Английский

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Efficient and clean treatment of indium-bearing zinc ferrite: A new approach using a water-regulated deep eutectic solvent

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 347, P. 127576 - 127576

Published: April 18, 2024

Language: Английский

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Deep Eutectic Solvent extraction and biological activity of polysaccharides from Tenebrio molitor

Heliyon, Journal Year: 2025, Volume and Issue: 11(2), P. e41790 - e41790

Published: Jan. 1, 2025

This study aimed to extract polysaccharides from Tenebrio molitor using ultrasound-assisted deep eutectic solvent (DESs) and evaluate their structural features, as well antimicrobial, antioxidant, α-amylase inhibitory activities. Various DESs were tested for extraction, the process was optimized response surface methodology (RSM). A preliminary analysis of conducted infrared spectrum. The characterized by measuring pH, viscosity, conductivity, refractive index, density. optimal extraction agent parameters determined. Significant differences in conductivity observed among DESs, whereas index density not significant. Choline chloride-lactic acid identified agent. a DES molar ratio 1:2.1, water content 27 %, an temperature 70 °C, time 44 min, resulting yield 18.62 %. extracted exhibited strong effects against Salmonella, along with antioxidant activity demonstrated that can be efficiently showcasing significant biological activities, including antibacterial, properties. These findings highlight potential applications valuable resources.

Language: Английский

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