A stable zirconium based metal-organic framework for specific recognition of representative polychlorinated dibenzo-p-dioxin molecules DOI Creative Commons
Bin Wang, Peilong Wang, Lin‐Hua Xie

и другие.

Nature Communications, Год журнала: 2019, Номер 10(1)

Опубликована: Авг. 27, 2019

Abstract Polychlorinated dibenzo- p -dioxins (PCDDs), as a class of persistent and highly toxic organic pollutants, have been posing great threat to human health the environment. The sensing these compounds is important but challenging. Here, we report stable zirconium-based metal-organic framework (MOF), Zr 6 O 4 (OH) 8 (HCOO) 2 (CPTTA) (BUT-17) with one-dimensional hexagonal channels phenyl-rich pore surfaces for recognition two representative PCDDs, 2,3-dichlorodibenzo- -dioxin (BCDD) 2,3,7,8-tetrachlorodibenzo- (TCDD), based on fluorescence quenching. BUT-17 exhibits high ability detection limits low 27 57 part per billion toward BCDD TCDD, respectively, very selective well without interference similar compounds. demonstrated by single-crystal structure its guest-loaded phase, in which fluorescence-quenched complexes form between adsorbed molecules MOF host through π-π stacking hydrogen bonding interactions.

Язык: Английский

Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications DOI
Guorui Cai, Yan Peng, Liangliang Zhang

и другие.

Chemical Reviews, Год журнала: 2021, Номер 121(20), С. 12278 - 12326

Опубликована: Июль 19, 2021

Metal-organic frameworks (MOFs) have been widely recognized as one of the most fascinating classes materials from science and engineering perspectives, benefiting their high porosity well-defined tailored structures components at atomic level. Although intrinsic micropores endow size-selective capability surface area, etc., narrow pores limit applications toward diffusion-control large-size species involved processes. In recent years, construction hierarchically porous MOFs (HP-MOFs), MOF-based composites, derivatives has captured widespread interest to extend conventional materials. this Review, advances in design, synthesis, functional are summarized. Their structural characters various applications, including catalysis, gas storage separation, air filtration, sewage treatment, sensing energy storage, demonstrated with typical reports. The comparison HP-MOFs traditional (e.g., zeolite, silica, carbons, metal oxides, polymers), subsisting challenges, well future directions research field, also indicated.

Язык: Английский

Процитировано

1104
Metal–Organic Frameworks for Biomedical Applications DOI
Jie Yang, Ying‐Wei Yang

Small, Год журнала: 2020, Номер 16(10)

Опубликована: Фев. 6, 2020

Metal-organic frameworks (MOFs) are an interesting and useful class of coordination polymers, constructed from metal ion/cluster nodes functional organic ligands through bonds, have attracted extensive research interest during the past decades. Due to unique features diverse compositions, facile synthesis, easy surface functionalization, high areas, adjustable porosity, tunable biocompatibility, MOFs been widely used in hydrogen/methane storage, catalysis, biological imaging sensing, drug delivery, desalination, gas separation, magnetic electronic devices, nonlinear optics, water vapor capture, etc. Notably, with rapid development synthetic methods functionalization strategies, smart MOF-based nanocomposites advanced bio-related properties designed fabricated meet growing demands MOF materials for biomedical applications. This work outlines synthesis recent advances fields, including cargo (drugs, nucleic acids, proteins, dyes) delivery cancer therapy, bioimaging, antimicrobial, biosensing, biocatalysis. The prospects challenges field also discussed.

Язык: Английский

Процитировано

810
Porous metal-organic frameworks for gas storage and separation: Status and challenges DOI
Hao Li, Libo Li, Rui‐Biao Lin

и другие.

EnergyChem, Год журнала: 2019, Номер 1(1), С. 100006 - 100006

Опубликована: Июнь 27, 2019

Язык: Английский

Процитировано

768
Metal–Organic Framework-Based Enzyme Biocomposites DOI
Weibin Liang, Peter Wied, Francesco Carraro

и другие.

Chemical Reviews, Год журнала: 2021, Номер 121(3), С. 1077 - 1129

Опубликована: Янв. 13, 2021

Because of their efficiency, selectivity, and environmental sustainability, there are significant opportunities for enzymes in chemical synthesis biotechnology. However, as the three-dimensional active structure is predominantly maintained by weaker noncovalent interactions, thermal, pH, stressors can modify or eliminate activity. Metal–organic frameworks (MOFs), which extended porous network materials assembled a bottom-up building block approach from metal-based nodes organic linkers, be used to afford protection enzymes. The self-assembled structures MOFs encase an enzyme process called encapsulation when MOF synthesized presence biomolecule. Alternatively, infiltrated into mesoporous surface bound via covalent processes. Integration this way affords allows maintain activity challenge conditions (e.g., denaturing agents, elevated temperature, non-native solvents). In addition forming simple enzyme/MOF biocomposites, other introduced composites improve recovery facilitate advanced applications sensing fuel cell technology. This review canvasses encapsulation, pore infiltration, adsorption summarizes strategies form multicomponent composites. Also, given that biocomposites straddle chemistry enzymology, provides assessment characterization methodologies MOF-immobilized identifies some key parameters development field.

Язык: Английский

Процитировано

551
A historical overview of the activation and porosity of metal–organic frameworks DOI
Xuan Zhang, Zhijie Chen, Xinyao Liu

и другие.

Chemical Society Reviews, Год журнала: 2020, Номер 49(20), С. 7406 - 7427

Опубликована: Янв. 1, 2020

Since the first reports of metal-organic frameworks (MOFs), this unique class crystalline, porous materials has garnered increasing attention in a wide variety applications such as gas storage and separation, catalysis, enzyme immobilization, drug delivery, water capture, sensing. A fundamental feature MOFs is their porosity which provides space on micro- meso-scale for confining exposing functionalities. Therefore, designing with high developing suitable activation methods preserving accessing pore have been common theme MOF research. Reticular chemistry allows facile design from highly tunable metal nodes organic linkers order to realize different structures, topologies, With hope shedding light future research endeavors porosity, it worthwhile examine development MOFs, an emphasis how properly access space. In review, we will provide overview historic evolution followed by synopsis strategies preserve permanent MOFs.

Язык: Английский

Процитировано

536
Metal-Organic Framework Composites for Catalysis DOI Creative Commons
Liyu Chen, Qiang Xü

Matter, Год журнала: 2019, Номер 1(1), С. 57 - 89

Опубликована: Июль 1, 2019

Язык: Английский

Процитировано

412
Acid-Resistant Mesoporous Metal–Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release DOI
Yijing Chen, Peng Li, Justin A. Modica

и другие.

Journal of the American Chemical Society, Год журнала: 2018, Номер 140(17), С. 5678 - 5681

Опубликована: Апрель 11, 2018

Diabetes affects millions of people worldwide and the number diagnoses continues to climb annually. Though several effective medications therapeutic methods have been developed treat type 1 (T1DM) 2 (T2DM) diabetes mellitus, direct insulin injection remains only treatment for resistant (IR) patients. Here, we immobilize in a crystalline mesoporous metal-organic framework (MOF), NU-1000, obtain high loading ∼40 wt % 30 min. The acid-stable MOF capsules are found effectively prevent from degrading presence stomach acid digestive enzyme, pepsin. Furthermore, encapsulated can be released NU-1000 under simulated physiological conditions.

Язык: Английский

Процитировано

400
Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs DOI Creative Commons
Zhijie Chen, Sylvia L. Hanna, Louis R. Redfern

и другие.

Coordination Chemistry Reviews, Год журнала: 2019, Номер 386, С. 32 - 49

Опубликована: Фев. 10, 2019

Язык: Английский

Процитировано

393
Metal-organic frameworks as novel matrices for efficient enzyme immobilization: An update review DOI
Shan Liang,

Xiaoling Wu,

Jun Xiong

и другие.

Coordination Chemistry Reviews, Год журнала: 2019, Номер 406, С. 213149 - 213149

Опубликована: Дек. 20, 2019

Язык: Английский

Процитировано

378
Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal–Organic Frameworks DOI
Rui‐Biao Lin, Hui Wu, Libo Li

и другие.

Journal of the American Chemical Society, Год журнала: 2018, Номер 140(40), С. 12940 - 12946

Опубликована: Сен. 14, 2018

The separation of ethane from its analogous ethylene is great importance in the petrochemical industry, but very challenging and energy intensive. Adsorptive using C2H6-selective porous materials can directly produce high-purity C2H4 a single operation suffers poor selectivity. Here, we report an approach to boost C2H6 over C2H4, involving control pore structures two isoreticular ultramicroporous metal–organic framework (MOF) with weakly polar surface for strengthened binding affinity toward C2H4. Under ambient conditions, prototypical compound shows small uptake difference selectivity C2H6/C2H4, whereas smaller-pore analogue exhibits quite large ratio 237% (60.0/25.3 cm3 cm–3), remarkably increasing C2H6/C2H4 Neutron powder diffraction studies clearly reveal that latter material self-adaptive sorption behavior C2H6, which enables it continuously maintain close van der Waals contacts molecules optimized structure, thus preferentially binds Gas isotherms, crystallographic analyses, molecular modeling, calculation, breakthrough experiment comprehensively demonstrate this unique MOF as efficient adsorbent purification.

Язык: Английский

Процитировано

373