Advanced Functional Materials,
Год журнала:
2022,
Номер
32(45)
Опубликована: Авг. 20, 2022
Abstract
Great
efforts
have
been
made
toward
the
separation
of
CO
2
from
flue
gas
and
biogas
to
mitigate
environmental
pollution
demand
for
renewable
fuels,
respectively.
Nonthermal‐based
separations,
such
as
adsorption‐based
or
membrane‐separation
technology
employing
porous
materials,
are
considered
be
more
promising
than
traditional
cryogenic
absorption‐based
systems.
Due
several
advantages
metal–organic
frameworks
(MOFs)
over
other
conventional
reports
on
by
MOFs
burgeoning
(423
adsorption
56
membrane‐based
separations
until
June
2021)
urgent
summarization.
This
review
presents
a
bird's
eye
view
while
organizing
developed
strategies
considering
performance
parameters,
trade‐off
between
sorption
capacity
selectivity
in
systems
permeability
versus
In
addition,
mechanisms
involving
at
molecular
level
presented.
A
critical
discussion
section
offers
crucial
insights
into
these
materials
industrial
deployment
viewpoints.
Finally,
future
recommendations
further
developments
MOF
separators
thus
solving
both
challenging
universal
problems
global
warming
energy
scarcity
simultaneously.
Chemical Reviews,
Год журнала:
2022,
Номер
122(9), С. 9078 - 9144
Опубликована: Март 28, 2022
In
the
past
two
decades,
metal-organic
frameworks
(MOFs)
or
porous
coordination
polymers
(PCPs)
assembled
from
metal
ions
clusters
and
organic
linkers
via
metal-ligand
bonds
have
captivated
significant
scientific
interest
on
account
of
their
high
crystallinity,
exceptional
porosity,
tunable
pore
size,
modularity,
diverse
functionality.
The
opportunity
to
achieve
functional
materials
by
design
with
promising
properties,
unattainable
for
solid-state
in
general,
distinguishes
MOFs
other
classes
materials,
particular,
traditional
such
as
activated
carbon,
silica,
zeolites,
thereby
leading
complementary
properties.
Scientists
conducted
intense
research
production
chiral
MOF
(CMOF)
specific
applications
including
but
not
limited
recognition,
separation,
catalysis
since
discovery
first
CMOF
(i.e.,
d-
l-POST-1).
At
present,
CMOFs
become
interdisciplinary
between
chirality
chemistry,
material
which
involve
many
subjects
physics,
optics,
medicine,
pharmacology,
biology,
crystal
engineering,
environmental
science,
etc.
this
review,
we
will
systematically
summarize
recent
progress
regarding
strategies,
synthetic
approaches,
cutting-edge
applications.
highlight
successful
implementation
asymmetric
catalysis,
enantioselective
sensing.
We
envision
that
review
provide
readers
a
good
understanding
chemistry
and,
more
importantly,
facilitate
endeavors
rational
multifunctional
industrial
implementation.
Journal of the American Chemical Society,
Год журнала:
2022,
Номер
144(24), С. 10663 - 10687
Опубликована: Июнь 8, 2022
Hydrogen-bonded
organic
frameworks
(HOFs),
self-assembled
from
strategically
pre-designed
molecular
tectons
with
complementary
hydrogen-bonding
patterns,
are
rapidly
evolving
into
a
novel
and
important
class
of
porous
materials.
In
addition
to
their
common
features
shared
other
functionalized
materials
constructed
modular
building
blocks,
the
intrinsically
flexible
reversible
H-bonding
connections
endow
HOFs
straightforward
purification
procedures,
high
crystallinity,
solution
processability,
recyclability.
These
unique
advantages
have
attracted
considerable
attention
across
broad
range
fields,
including
gas
adsorption
separation,
catalysis,
chemical
sensing,
electrical
optical
However,
relatively
weak
interactions
within
can
potentially
limit
stability
potential
use
in
further
applications.
To
that
end,
this
Perspective
highlights
recent
advances
development
chemically
thermally
robust
HOF
systematically
discusses
relevant
design
rules
synthesis
strategies
access
highly
stable
HOFs.
ACS Omega,
Год журнала:
2022,
Номер
7(49), С. 44507 - 44531
Опубликована: Дек. 2, 2022
Metal
ions
or
clusters
that
have
been
bonded
with
organic
linkers
to
create
one-
more-dimensional
structures
are
referred
as
metal–organic
frameworks
(MOFs).
Reticular
synthesis
also
forms
MOFs
properly
designated
components
can
result
in
crystals
high
porosities
and
great
chemical
thermal
stability.
Due
the
wider
surface
area,
huge
pore
size,
crystalline
nature,
tunability,
numerous
shown
be
potential
candidates
various
fields
like
gas
storage
delivery,
energy
storage,
catalysis,
chemical/biosensing.
This
study
provides
a
quick
overview
of
current
MOF
techniques
order
familiarize
newcomers
sciences
field
fast-growing
research.
Beginning
classification
nomenclature
MOFs,
approaches
demonstrated.
We
emphasize
applications
such
drug
rechargeable
batteries,
supercapacitors,
separation
membranes.
Lastly,
future
scope
is
discussed
along
prospective
opportunities
for
application
nano-MOFs,
which
will
help
promote
their
uses
multidisciplinary
Angewandte Chemie International Edition,
Год журнала:
2021,
Номер
60(45), С. 23946 - 23974
Опубликована: Март 30, 2021
At
its
core,
reticular
chemistry
has
translated
the
precision
and
expertise
of
organic
inorganic
synthesis
to
solid
state.
While
initial
excitement
over
metal-organic
frameworks
(MOFs)
covalent
(COFs)
was
undoubtedly
fueled
by
their
unprecedented
porosity
surface
areas,
most
profound
scientific
innovation
field
been
elaboration
design
strategies
for
extended
crystalline
solids
through
strong
directional
bonds.
In
this
contribution
we
highlight
different
classes
materials
that
have
developed,
how
these
can
be
functionalized,
complexity
introduced
into
backbones.
Finally,
show
structural
control
is
being
from
molecular
scale
crystal
morphology
shape
on
nanoscale,
all
way
shaping
bulk
scale.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(3), С. 1045 - 1097
Опубликована: Янв. 1, 2022
This
review
illustrates
molecular-scale
confinement,
containment,
isolation,
and
related
concepts
to
present
MOF-centric
catalysts
realize
desired
chemical
transformations.
Chemical Society Reviews,
Год журнала:
2021,
Номер
50(11), С. 6349 - 6368
Опубликована: Янв. 1, 2021
Since
the
transition
of
energy
platforms,
proton-conductive
metal–organic
frameworks
(MOFs)
exhibiting
high
performance
have
been
extensively
investigated
with
rational
strategies
for
their
potential
application
in
solid-state
electrolytes.
Advanced Energy Materials,
Год журнала:
2021,
Номер
11(39)
Опубликована: Сен. 1, 2021
Abstract
Proton
conductivity
is
the
paramount
property
of
proton‐conducting
materials
that
are
playing
significant
roles
in
diverse
electrochemical
devices
with
applications
proton
exchange
membranes
(PEMs)
for
fuel
cells
(PEMFCs).
Considering
scarcity
fossil
fuels,
development
clean
and
green
renewable
energy
resources
in‐demand
across
globe.
Toward
this
direction,
solid‐state
conductors
interest.
The
higher
structural
tunability,
lower
density,
good
crystallinity,
accessible
well‐defined
pores,
excellent
thermal
chemical
stability
covalent‐organic
frameworks
(COFs)
make
them
versatile
platforms
as
both
under
hydrous
anhydrous
conditions.
Taking
advantage
such
superior
properties,
reports
on
COFs
have
been
increasing
swiftly
since
2014,
which
demands
a
summarization
comprehensive
discussion
“at
glance”
visualization
further
development.
In
review,
showcased
newer
class
material.
A
presented
by
organizing
strategies
taken
to
develop
COFs.
Establishment
structure–function
relationships
implementation
discussed
well.
Moreover,
challenges
future
prospects
elaborately
critically
analyzed.
